Determinations of particle size distributions in natural waters use of Zeiss Micro-Videomat image analyzer

Use of a Zeiss Micro-Videomat electronic image analyzer for routine measurements of size distributions of particles found in natural waters greater than 0.3 μm has been investigated. Staining of particles with a solution of Gentiana-violet eliminated the multiple-count problem which has frustrated earlier attempts to use image analyzers for quantitative phytoplankton work. Concentration of samples from the lake water column was successfully achieved with an impact centrifuge. Losses of inorganic particles indicate that the centrifuge method must be evaluated on an individual case basis. Precision and accuracy of the Zeiss Micro-Videomat using either sedimentation (Utermöhl) or centrifugation for sample concentration were satisfactory for particles larger than 1 μm. The system appears promising for routine surveillance of raw water quality at water treatment plants, and performance of unit processes used for particulate removal, as well as for specific investigations of ecological phenomena in natural waters.     

The evolved B[e] star HD 87643: observations and a radiation-driven disc wind model for B[e] stars

New high-resolution spectroscopic and medium-resolution spectropolarimetric data of the B[e] star HD 87643 are presented, complemented with optical broad- and narrow-band imaging. The spectrum of HD 87643 exhibits the hybrid characteristics well known to be representative of the group of B[e] stars; a fast wind with an expansion velocity in excess of 1000 km s⁻¹ is measured in the hydrogen and helium lines, while a slower component is traced by lower excitation lines and forbidden lines. Clues to the geometry of the rapidly expanding circumstellar shell are provided by the startling polarization changes across Hα. Comparison with published schematic calculations indicates that the polarizing material is located in a slowly rotating, expanding disc structure. A hydrodynamical model is then presented, the results of which are consistent with the original two-wind concept for B[e] stars, and which exhibits kinematic properties that may well explain the observed spectral features in HD 87643. The model calculations use as input a B star undergoing mass loss, surrounded by an optically thick disc. The resulting configuration consists of a fast polar wind from the star and a slowly expanding disc wind. The model also predicts that the stellar wind at intermediate latitudes is slower and denser than in the polar region.     

Fluid inclusions in charnockites from the Bjerkreim-Sokndal massif (Rogaland,southwestern Norway): fluid origin and in situ evolution

Fluid inclusions and mineral associations were studied in late-stage charnockitic granites from the Bjerkreim-Sokndal lopolith (Rogaland anorthosite province). Because the magmatic and tectonic evolutions of this complex appear to be relatively simple, these rocks are a suitable case for investigation of the origin and evolution of granulitic fluids. Fluid inclusions, primarily contained in quartz, can be divided into four types: carbonic (type I), N₂-bearing (type II), CO₂+H₂O (type III) and aqueous inclusions (type IV). For each type, the role of leakage and fluid mixing are discussed from microthermometric and Raman spectrometric data. The most striking features of CO₂-rich inclusions (the predominant fluid) is the presence of graphite in numerous, trail-bound inclusions (Ib) and its absence in a few isolated, very dense (d=1.16), pure CO₂ inclusions (Ia) and in the late carbonic inclusions (Ic). Fluid chronology and mineral assemblages suggest that carbonic Ia inclusions represent the first fluid (pure CO₂) trapped at or close to magmatic conditions (T=780–830° C, fO₂=10^-15 atm and P=7.4±1 kb), outside the graphite stability field. In contrast, type Ib inclusions enclosed graphite particles from a channelized fluid during retrograde rock evolution (P=3–4 kb and T=600° C). Decreases in T-fO₂ could explain a progressive evolution from a CO₂-rich fluid to an H₂O-rich fluid in a closed C–O–H system. However, graphite destabilization observed in type Ic inclusions implies some late introduction of external water during the last stage of retrogression. The main results of this study are the following: (1) a carbonic fluid was present in an early stage of rock evolution (probably in the charnockitic magma) and (2) this granulite occurrence offers good evidence of crossing the graphite stability field during post-magmatic evolution.     

Geomorphology and ancient settlements of the Southern Flank of MT. Cairo,lower Liri valley,Italy

The southern flank of Mt. Cairo in southern Lazio edges a valley which forms one of the major passageways from central to southern Italy. The mountainous landscape has affected the settlement pattern, as have historical events such as the Roman conquests and recent socio-economic evolution, which has led to industrialization of a traditional pastoral- agricultural setting. The slopes of calcareous Mt. Cairo are characterized by a cascade of normal faults which delimit landscape units such as the “uplands,” “steep slopes,” and the “mountain rise,” which contains well developed alluvial and colluvial fans. Along the lower mountain slopes, Bronze and Iron Age sites are consistently located higher than Roman ones. Archaeological remains and historical documents indicate that only after the Roman conquest was the agricultural potential of the flatter lower areas fully exploited. Roman villas were characteristically placed on the upper parts of the fans, where both access to different types of land and elevation above the mists of the valley were enjoyed. The Medieval period brought a trend back to higher sites and fortified villages. The uplands remained in use through the ages.     

Fertilization and pH effects on processes and mechanisms controlling dissolved inorganic phosphorus in soils

We used of a set of mechanistic adsorption models (1-pK TPM, ion exchange and Nica-Donnan) within the framework of the component additive (CA) approach in an attempt to determine the effect of repeated massive application of inorganic P fertilizer on the processes and mechanisms controlling the concentration of dissolved inorganic phosphorus (DIP) in soils. We studied the surface layer of a Luvisol with markedly different total concentrations of inorganic P as the result of different P fertilizer history (i.e. massive or no application for 40 years). Soil pH was made to vary from acid to alkaline. Soil solutions were extracted with water and CaCl₂ (0.01 M). The occurrence of montmorillonite led us to determine the binding properties of P and Ca ions for this clay mineral.Satisfactory results were obtained using generic values for model parameters and soil-specific ones, which were either determined directly by measurements or estimated from the literature. We showed that adsorption largely controlled the variations of DIP concentration and that, because of kinetic constrains, only little Ca-phosphates may be precipitated under alkaline conditions, particularly in the P fertilized treatment. The mineral-P pool initially present in both P treatments did not dissolve significantly during the course of the experiments. The adsorption of Ca ions onto soil minerals also promoted adsorption of P ions through electrostatic interactions. The intensity of the mechanism was high under neutral to alkaline conditions. Changes in DIP concentration as a function of these environmental variables can be related to changes in the contribution of the various soil minerals to P adsorption. The extra P adsorbed in the fertilized treatment compared with the control treatment was mainly adsorbed onto illite. This clay mineral was the major P-fixing constituent from neutral to alkaline pH conditions, because the repulsion interactions between deprotonated hydroxyl surface sites and P ions were sufficiently counterbalanced by Ca ions. The drastic increase of DIP observed at acid pH was due to the effect of the lower concentration of surface sites of Fe oxides and kaolinite.In addition to confirming the validity of our approach to model DIP concentrations in soils, the present investigation showed that adsorption was the predominant geochemical process even in the P fertilized soil, and that Ca ions can have an important promoting effect on P adsorption. However the influence of the dissolution of the mineral-P pool under field conditions remained questionable.     

A speleothem record of Holocene climate variability from southwestern Mexico

A paleoclimate reconstruction for the Holocene based upon variations of δ¹⁸O in a U-Th dated stalagmite from southwestern Mexico is presented. Our results indicate that the arrival of moisture to the area has been strongly linked to the input of glacial meltwaters into the North Atlantic throughout the Holocene. The record also suggests a complex interplay between Caribbean and Pacific moisture sources, modulated by the North Atlantic SST and the position of the ITCZ, where Pacific moisture becomes increasingly more influential through ENSO since ~ 4.3 ka. The interruption of stalagmite growth during the largest climatic anomalies of the Holocene (10.3 and 8.2 ka) is evidenced by the presence of hiatuses, which suggest a severe disruption in the arrival of moisture to the area. The δ¹⁸O record presented here has important implications for understanding the evolution of the North American Monsoon and climate in southwestern Mexico, as it represents one of the most detailed archives of climate variability for the area spanning most of the Holocene.     

Spatial patterns of soil δC reveal grassland-to-woodland successional processes

Many grasslands and savannas around the world have experienced woody plant encroachment in recent history. In the Rio Grande Plains of southern Texas, subtropical woodlands dominated by C₃ trees and shrubs have become significant components of landscapes once dominated almost exclusively by C₄ grasslands. In this study, spatial variation of soil δ¹³C to was used to investigate patterns of transformation. Previous research has shown that grassland-to-shrubland transitions are initiated when discrete, multi-species shrub clusters organized around a honey mesquite (Prosopis glandulosa) tree nucleus established in grassland. It is inferred from space-for-time substitution and modeling studies that as new shrub clusters are initiated and existing clusters enlarge, coalescence will occur, leading to the formation of groves; and that groves will eventually merge to form woodlands. The hypothesis that present-day mesquite groves represent areas where individual discrete shrub clusters have proliferated and coalesced was evaluated by comparing patterns of soil δ¹³C within isolated shrub clusters (n = 6) to those in nearby groves (n = 3). Mean soil δ¹³C within discrete clusters was lowest in the center (−23.3‰), increased exponentially toward the dripline (−20.1‰), and stabilized at a relatively high value approximately 15 cm beyond the dripline (−18.9‰). The spatial structure of soil δ¹³C in groves was consistent with that which would be expected to occur if present-day grove communities were a collection of what once were individual discrete clusters that had fused. As such, it provides direct evidence in support of conceptual and mathematical models derived from indirect assessments. However, spatial patterns of soil δ¹³C suggest that groves are not simply a collection of clusters with respect to primary production and SOC turnover. This study illustrates how soil δ¹³C values can be used to reconstruct successional processes accompanying vegetation compositional change, and its consequences for ecosystem function.     

Incorporating Groundwater-Surface Water Interaction into River Management Models

Accurate representation of groundwater-surface water interactions is critical to modeling low river flows in the semi-arid southwestern United States. Although a number of groundwater-surface water models exist, they are seldom integrated with river operation/management models. A link between the object-oriented river and reservoir operations model, RiverWare, and the groundwater model, MODFLOW, was developed to incorporate groundwater-surface water interaction processes, such as river seepage/gains, riparian evapotranspiration, and irrigation return flows, into a rule-based water allocations model. An explicit approach is used in which the two models run in tandem, exchanging data once in each computational time step. Because the MODFLOW grid is typically at a finer resolution than RiverWare objects, the linked model employs spatial interpolation and summation for compatible communication of exchanged variables. The performance of the linked model is illustrated through two applications in the Middle Rio Grande Basin in New Mexico where overappropriation impacts endangered species habitats. In one application, the linked model results are compared with historical data; the other illustrates use of the linked model for determining management strategies needed to attain an in-stream flow target. The flows predicted by the linked model at gauge locations are reasonably accurate except during a few very low flow periods when discrepancies may be attributable to stream gaging uncertainties or inaccurate documentation of diversions. The linked model accounted for complex diversions, releases, groundwater pumpage, irrigation return flows, and seepage between the groundwater system and canals/drains to achieve a schedule of releases that satisfied the in-stream target flow.