Facies analysis of Pleistocene limestones from Neil West Coast Formation,Neil Island,Ritchie’s archipelago of South Andaman,India

Petrographic thin section analysis of the samples collected from the type section of Neil West Coast Formation, situated in the west coast of Neil Island yielded moderately preserved coralline red algae, benthic and planktic foraminifers, coral fragments, echinoid spines and gastropod shells. The coralline red algae are represented by both non-geniculate and geniculate forms. The non-geniculate forms belong to melobesids, lithophylloids and mastophoroides. The geniculate forms are represented by species of Amphiroa, Corallina, and Jania. However, the diversity and abundance of coralline algal forms are less in comparison to the benthic foraminifers those are represented by Amphistegina, Neorotalia, Ammonia, Elphidium, Operculina, Assilina, Amphisorus and texularids. Planktic foraminifers like Globigerinoides and other biogenic components viz., gastropod shells, echinoid spines and coral fragments are also common. A foraminiferal-algal grainstone facies has been recognized as observed in the field as well as in thin section analysis. The overall assemblage of the biogenic components and facies analysis indicate intertidal to near shore environment of deposition with high energy condition and increased hydrodynamic activity.     

Numerical modelling of groundwater flow to understand the impacts of pumping on arsenic migration in the aquifer of North Bengal Plain

In this paper, numerical simulations of regional-scale groundwater flow of North Bengal Plain have been carried out with special emphasis on the arsenic (As)-rich alluvium filled gap between the Rajmahal hills on the west and the Garo hills on the east. The proposed concern of this modelling arose from development that has led to large water table declines in the urban area of English Bazar block, Malda district, West Bengal and possible transport of As in the near future from the adjacent As-polluted aquifer. Groundwater occurs under unconfined condition in a thick zone of saturation within the Quaternary alluvial sediments. Modelling indicates that current pumping has significantly changed the groundwater flowpaths from pre-development condition. At the present pumping rate, the pumping wells of the urban area may remain uncontaminated till the next 25 yrs, considering only pure advection of water but some water from the As-polluted zone may enter wells by 50 yrs. But geochemical and other processes such as adsorption, precipitation, redox reaction and microbial activity may significantly retard the predicted rate by advective transport. In the rural areas, majority of the water pumped from the aquifer is for irrigation, which is continuously re-applied on the surface. The near-vertical nature of the flowpaths indicates that, where As is present or released at shallow depths, it will continue to occur in pumping wells. Modelling also indicates that placing all the pumping wells at depths below 100 m may not provide As-free water permanently.     

Prediction of slope stability using multiple linear regression (MLR) and artificial neural network (ANN)

The stability problem of natural slopes, filled slopes, and cut slopes are commonly encountered in Civil Engineering Projects. Predicting the slope stability is an everyday task for geotechnical engineers. In this paper, a study has been done to predict the factor of safety (FOS) of the slopes using multiple linear regression (MLR) and artificial neural network (ANN). A total of 200 cases with different geometric and shear strength parameters were analyzed by using the well-known slope stability methods like Fellenius method, Bishop’s method, Janbu method, and Morgenstern and Price method. The FOS values obtained by these slope stability methods were used to develop the prediction models using MLR and ANN. Further, a few case studies have been done along the Jorabat-Shillong Expressway (NH-40) in India, using the finite element method (FEM). The output values of FEM were compared with the developed prediction models to find the best prediction model and the results were discussed.     

The Geochemical Effects of Microbial Humic Substances Reduction

As part of a study on microbial redox alteration of humic substances we investigated the potential effect of this metabolism on the fate of heavy metals and hydrocarbons as a result of conformational alteration of the humic molecular structure due to microbial reduction. Our studies indicate that the microbial reduction of humic acids (HA) results in significant morphological and geochemical alterations. X‐ray microscopy analysis indicate that the conformational structure of the humic colloids is altered as a result of the redox change. In the reduced state, the HA appeared as small dense particles, on reoxidation, large loose aggregates were formed. In addition, spectrofluorometric studies indicated that the binding capacity of the HA for naphthalene was decreased by 10% when the HA was reduced. Similarly, the reduced HA yielded higher surface tension values at all concentrations tested which is indicative of a more hydrophilic and less hydrophobic solute. On reoxidation, the surface tension values reverted back to values similar to those obtained for the untreated oxidized HA. These data indicate that the hydrophobicity of the HA is altered on biological reduction of the HA and that this alteration is reversible. In contrast the reduced HA demonstrated a 15% higher affinity for heavy metals such as divalent cobalt than the oxidized HA. In addition to increasing the binding capacity of HA for heavy metals, the reduction of the HA also decreased the bioavailability and toxicity of bound heavy metals such as chromium. When incubated in the presence of Cr(III) and HA, cells of Escherichia coli grew much more rapidly in the presence of the reduced HA suggesting that the higher metal binding capacity of the reduced humic substances resulted in a removal of the Cr(III) from solution and hence reduced its bioavailability and toxicity. These studies demonstrate that HA redox state and reduction of humic acids by microorganisms can have a significant effect on the molecular morphology and binding constants of HA for heavy metals and hydrocarbons and also directly affects the bioavailability of these compounds in the environment.     

Methane flux dynamics in relation to methanogenic and methanotrophic populations in the soil of Indian Sundarban mangroves

The dynamics of methane (CH₄) flux in relation to populations of methanogenic and methanotrophic bacteria was studied under the different biophysical conditions of the Indian Sundarban mangrove ecosystem. Soil depth profile analysis (up to 60 cm) in the lower littoral zone (LLZ) revealed that a methanogenic population of 6.45 ± 0.19 × 10⁴ cells/g dry weight (dry wt) of soil accounted for a CH₄ production rate of 6.23 ± 3.53 × 10³ µmol m^?2 day^?1, whereas in the surface soil, a methanogenic population of 3.34 ± 0.37 × 10⁴ cells/g dry wt of soil accounted for a CH₄ production rate of 31.6 ± 0.57 µmol m^?2 day^?1. The CH₄ oxidation rate at 60 cm depth in the LLZ was 24.42 ± 1.28 µmol m^?2 day^?1, with an average methanotrophic population of 1.33 ± 0.43 × 10⁴ cells/g dry wt of soil, whereas in the surface soil, the oxidation rate and average population were 3.38 ± 1.43 × 10³ µmol m^?2 day^?1 and 12.80 ± 2.54 × 10⁴ cells/g dry wt of soil, respectively. A similar soil profile in terms of CH₄ dynamics and the populations of methanogenic and methanotrophic bacteria was found in the mid‐littoral and upper littoral zones of the studied area. The results demonstrate that most of the produced CH₄ (approximately 60%) was oxidized by methanotrophic bacteria present in the soil, thus revealing their principal role in regulating the CH₄ flux from this unique ecosystem.