Emissions from Russian domestic civil aviation in 2000–2012 and integrated assessment of their impact on the climate system

Emissions from Russian domestic civil aviation for the period of 2000–2012 are assessed for the following gases: carbon dioxide, methane, nitrous oxide, carbon monoxide, nitrogen oxides, and sulfur dioxide. The integrated assessment of their impact on the climate system is performed using the values of the global warming potential. The CO₂ equivalent was used as a common measure of emissions. It is established that the modern impact of Russian civil aviation on the Earth climate is insignificant.     

Metacarbonate-terrigenous complex of the Derba block (East Sayan): petrogeochemical and isotope parameters,metamorphism, and time of formation

The Derba block is one of the largest Precambrian terranes of the Sayan-Yenisei accretionary belt in the southwestern margin of the Siberian Platform. It is composed of metamorphosed terrigenous-carbonate rocks of the Sayan Group, injected by granitoids. The geochemical features of gneiss-schist associations indicate the low maturity of their sedimentary protoliths corresponding in composition mainly to graywackes and terrigenous-carbonate rocks (marls). According to the results of U-Pb (LA-ICP-MS) dating of detrital zircons from gneisses and schists, the sedimentary protolith formed in the Vendian. Neoproterozoic subduction complexes were probably the major provenance for terrigenous material, and Early Precambrian rocks made a limited contribution. The Ar-Ar and U-Pb isotope data testify to nearly coeval and multistage events of metamorphism (up to the amphibolite facies) and granitoid magmatism (~ 510-500 and 480-465 Ma) in the Derba block. These processes were reflective of the Early Caledonian orogenic processes in the structures of the Central Asian Orogenic Belt. The similarity in the composition, time of sedimentation, and provenances of metaterrigenous-carbonate complexes of the Derba block (Sayan Group), West Sangilen block of the Tuva-Mongolian massif (Erzin and Moren complexes), and the Khamar-Daban terrane (Slyudyanka Group) suggests that these structures were a single Vendian continental margin with lateral variations in depositional environments and the sources of terrigenous material.     

Amplitude and period of the dynamo wave and prediction of the solar cycle

The relation of the solar cycle period and its amplitude is a complex problem as there is no direct correlation between these two quantities. Nevertheless, the period of the cycle is of important influence to the Earth's climate, which has been noted by many authors. The present authors make an attempt to analyse the solar indices data taking into account recent developments of the asymptotic theory of the solar dynamo. The use of the WKB method enables us to estimate the amplitude and the period of the cycle versus dynamo wave parameters in the framework of the nonlinear development of the one-dimensional Parker migratory dynamo. These estimates link the period T and the amplitude a with dynamo number D and thickness of the generation layer of the solar convective zone h. As previous authors, we have not revealed any considerable correlation between the above quantities calculated in the usual way. However, we have found some similar dependences with good confidence using running cycle periods. We have noticed statistically significant dependences between the Wolf numbers and the running period of the magnetic cycle, as well as between maximum sunspot number and duration of the phase of growth of each sunspot cycle. The latter one supports asymptotic estimates of the nonlinear dynamo wave suggested earlier. These dependences may be useful for understanding the mechanism of the solar dynamo wave and prediction of the average maximum amplitude of solar cycles. Besides that, we have noted that the maximum amplitude of the cycle and the temporal derivative of the monthly Wolf numbers at the very beginning of the phase of growth of the cycle have high correlation coefficient of order 0.95. The link between Wolf number data and their derivative taken with a time shift enabled us to predict the dynamics of the sunspot activity. For the current cycle 23 this yields Wolf numbers of order 107±7.     

Immiscibility of Fluoride–Calcium and Silicate Melts in Trachyrhyolitic Magma: Data on Acidic Volcanic Rocks from the Nyalga Basin,Central Mongolia

An Early Cretaceous (120 ± 5 Ma) trachyrhyolite lava sheet in the Nyalga basin, Central Mongolia, includes a domain (～0.5 km²) of unusual fluorite-enriched rocks with anomalously high concentrations of CaO (1.2–25.7 wt %) and F (0.6–15 wt %). The textures and structures of the rocks suggest that they were produced by two immiscible melts: fluoride–calcium (F–Ca) and trachyrhyolitic. Data on mineral-hosted inclusions and SEM EDS studies of the matrixes of the rocks indicate that a F–Ca melt occurred in the trachyrhyolitic magmas during its various evolutionary episodes, starting from the growth of minerals in a magmatic chamber and ending with eruptions on the surface. Elevated fluorine concentrations (up to 1.5–2 wt %) in local domains of the trachyrhyolitic melt may have resulted in the onset of its liquid immiscibility and the exsolution of a F–Ca liquid phase. This was associated with the redistribution of trace elements: REE, Y, Sr, and P were preferably concentrated in the F–Ca melt, while Zr, Hf, Ta, and Nb were mostly redistributed into the immiscible silicate liquid. The F–Ca melt contained oxygen and aqueous fluid and remained mobile until vitrification of the trachyrhyolitic magma. The oxygen-enriched F–Ca phase was transformed into fluorite at 570–780°? and a high oxygen fugacity Δlog fO₂ (0.9–1.7) relative to the NNO buffer. Ferrian ilmenite, monazite-group As-bearing minerals, and cerianite crystallized under oxidizing conditions, and the titanomagnetite was replaced by hematite. The Ca- and F-enriched rocks were affected by low-density (0.05–0.1 g/cm³) aqueous fluid, which was released from the crystallizing trachyrhyolitic melt, and this led to the partial removal of REE from the F–Ca phase. The chondrite-normalized REE and Y patterns of the fluidmodified rocks show positive Y anomalies and W-shaped minima from Gd to Ho. A composition of the F–Ca phase close to the original one is conserved in mineral-hosted inclusions and in relict isolations in the rocks matrix. It is so far unclear why fluorite did not crystallize from the F–Ca melt contained in the trachyrhyolitic magma. Conceivably, this was favored by high-temperature oxidizing conditions under which the melt accommodated oxygen and aqueous fluid. The possible origin of mobile oxygen-bearing fluorite–calcic melt at subsolidus temperature should be taken into account when magmatic rocks and ores are studied. Fluorite and accompanying ore mineralization might have been formed in certain instances not by hydrothermal–metasomatic processes but during the fluid–magmatic stage as a result of the transformation of F–Ca melt enriched in REE, Y, and other trace elements.     

Geochemistry of the Paleoproterozoic metaterrigenous rocks of the Biryusa Block,southwestern Siberian Craton

Major and trace element compositions of the Paleoproterozoic metaterrigenous rocks (Neroi Group) formed in a large sedimentation basin in the southwestern Siberian Craton (Biryusa Block) were determined to reconstruct the protoliths of metasediments, degree of their recycling, and maturity of source rocks. Primary rocks from the lower part of the sequence (Alkhadyr Formation) are represented by both petrogenic (“first cycle”) and recycled sediments of the graywacke to siltstone and aluminous pelite series. Protoliths of the micaceous and carbonaceous schists from the upper part of the sequence (Tumanshet Formation) correspond to silty pelites and pelites. As the micaceous schists of the Alkhadyr Formation, these rocks have K₂O/Al₂O₃ < 0.3 and elevated Th concentrations, indicating the contribution of recycling in the formation of the fine-grained rocks. Distribution of trace and rare earth elements (REE) in metaterrigenous rocks of the Neroi Group testifies to the predominance of felsic rocks in the source area, while the prominent Eu minimum indicates the presence of granitoids—the products of crustal melting. Rocks of the Alkhadyr Formation also show elevated contents of Cr, Co, Ni, Sc, and Fe, indicating the development of mafic rocks in the source area. Comparison of the trace element contents and their ratios in rocks of the Neroi Group with those in the Archean (3.5–2.5 Ga) and Paleoproterozoic (2.5–1.6 Ga) upper continental crust made it possible to establish that metasedimentary rocks of the Neroi Group were formed by the erosion of sufficiently mature (geochemically differentiated) protoliths, which are similar to the Paleoproterozic crust. Judging from the Sm-Nd isotope data, one of the components of source areas for the terrigenous rocks of the Neroi Group were Archean rocks similar to basement rocks of the Biryusa block with the Nd model ages within 2.8–2.6 Ga. The second component in the source area could be juvenile Paleoproterozoic crust (Nd model age ∼1.9 Ga), which was probably represented by the metavolcanic associations of grabens surrounding the Biryusa block. The minimum Nd model ages for metaterrigenous rocks of the Neroi Group define the lowermost sedimentation boundary at 1.9 Ga.     

Late Precambrian terrigenous rocks of the Anamakit–Muya zone of the Baikal–Muya belt: geochemistry and results of LA-ICP-MS dating of detrital zircons

A comparative geochemical characteristics of Late Precambrian sedimentary rocks (Ust’-Kelyana and Tuluya rock units) in the Anamakit–Muya zone of the Baikal–Muya belt is given, and the conditions of their sedimentation are considered. The first results of U–Pb (LA-ICP-MS) dating of detrital zircons and Sm–Nd isotope data on the Tuluya unit deposits are presented. Petrogeochemical study showed that the studied sediments are first-cycle rocks similar in composition to terrigenous island-arc sediments. The low contents of Th, Rb, Zr, Hf, and LREE and high contents of Co, Ni, Sc, V, Cr, and Fe₂O₃* in the sandstones of the Ust’-Kelyana unit evidence that these rocks are similar to oceanic-arc deposits. In contrast, the enrichment of the Tuluya unit rocks in Zr, LREE, Th, Rb, and Nb indicates their similarity to deposits of continental island arcs or active continental margin. Isotope-geochronological studies of the Tuluya rock unit showed the mixing of detrital material resulted from the erosion of Neoproterozoic island-arc igneous rock associations (625–700 Ma), like those in the Karalon–Mamakan zone (Yakor’ and Karalon Formations), and more ancient associations, like the Kelyana (812–824 Ma) and/or Dzhaltuk Groups. Judging from the minimum age of detrital zircon, the lower time bound of sedimentation corresponds to 0.6 Ga.     

Petrogeochemical features of metaterrigenous rocks of the Kan Block of the Eastern Sayan: Reconstructions of provenances and sedimentation conditions

Chemical and isotopic compositions of Proterozoic metaterrigenous rocks of the Kan Block (Central and Idar terranes) of the Eastern Sayan are studied. The results of the reconstruction of their provenances and sedimentation conditions are presented. The rocks under investigation correspond by their petrogeochemical composition to graywackes of island arcs. The combination of geochemical and isotope data shows that sediments of the Central terrane had a local provenance represented by Early Proterozoic subduction magmatic complexes, whereas sediments of the Idar terrane formed probably as the result of mixing of terrigenous material related to the destruction of rocks of Meso-Neoproterozoic oceanic and more ancient continental crust.     

Riphean fine-grained aluminosilicate clastic rocks in the Southern Urals, Uchur-Maya area, and the Yenisei Kryazh: Principal litho-geochemical characteristics

Analysis of the litho-geochemistry of fine-grained terrigenous rocks (metapelites, shales, and mudstones) of sedimentary megasequences in the Southern Urals, Uchur-Maya area, and the Yenisei Kryazh indicates that Riphean sequences in these regions are dominated by chlorite-hydromica rocks, with montmorillonite and potassic feldspar possibly occurring only in some of the lithostratigraphic units. According to the values of their hydrolysate modulus, most clay rocks from the three Riphean metamorphosed sedimentary sequences are normal or supersialites, with hydrosialites and hydrolysates playing subordinate roles. The most lithochemicaly mature rocks are Riphean clays in the Yenisei Kryazh (Yenisei Range). The median value of their CIA is 72, whereas this index is 70 for fine-grained aluminosilicate rocks from the Uchur-Maya area and 66 for fine-grained terrigenous rocks of the Riphean stratotype. Hence, at ancient water provenance areas from which aluminosilicate clastic material was transported in sedimentation basins in the southwestern (in modern coordinates) periphery of the Siberian Platform, the climate throughout the whole Riphean was predominantly humid. At the same time, the climate at the eastern part of the East European Platform was semiarid-semihumid. The K₂O/Al₂O₃ ratio, which is employed as an indicator of the presence of petro-and lithogenic aluminosilicate clastic component in Riphean sedimentary megasequences, shows various tendencies. According to their Sc, Cr, Ni, Th, and La concentrations and the Th/Sc ratio, the overwhelming majority of Riphean shales and mudstones notably differ from the average Archean mudstone and approach the average values for post-Archean shales. This suggests that mafic Archean rock in the provenance areas did not play any significant role in the origin of Riphean sedimentary megasequences. The Co/Hf and Ce/Cr ratios of the terrigenous rocks of the three Riphean megaseqeunces and their (Gd/Yb) _N and Eu/Eu* ratios place these rocks among those containing little (if any) erosion products of primitive Archean rocks. According to various geochemical data, the source of the great majority of fine-grained aluminosilicate clastic rocks in Riphean sediment megasequences in our study areas should have been mature sialic (felsic), with much lower contents of mafic and intermediate rocks as a source of the clastic material. The REE patterns of the Riphean shales and metapelites in the Bashkir Meganticlinorium, Uchur-Maya area, and Yenisei Kryazh show some features that can be regarded as resulting from the presence of mafic material in the ancient provenance areas. This is most clearly seen in the sedimentary sequences of the Uchur-Maya area, where the decrease in the (La/Yb) _N ratio up the sequence of the fine-grained terrigenous rocks from 15–16.5 to 5.8–7.1 suggests that mantle mafic volcanics were brought to the upper crust in the earliest Late Riphean in relation to rifting. Analysis of the Sm-Nd systematics of the Riphean fine-grained rocks reveals the predominance of model age values in the range of 2.5–1.7 Ga, which can be interpreted as evidence that the rocks were formed of predominantly Early Proterozoic source material. At the same time, with regard for the significant role of recycling in the genesis of the upper continental crust, it seems to be quite possible that the ancient provenance areas contained Archean complexes strongly recycled in the Early Proterozoic and sediments formed of their material. An additional likely source of material in the Riphean was mafic rocks, whose variable contribution is reflected in a decrease in the model age values. Higher Th and U concentrations in the Riphean rocks of the Yenisei Kryazh compared to those in PAAS indicate that the sources of their material were notably more mature than the sources of fine-grained aluminosilicate clastic material for the sedimentary megaseqeunces in the Southern Urals and Uchur-Maya area.