Evaluation of hydrogeochemical processes and groundwater quality for suitability of drinking and irrigation purposes: a case study in the Aosta Valley region,Italy

The present study aims to discuss the hydrogeochemical processes in the Aosta Valley region and assess the quality of its groundwater for suitability of drinking and irrigation purposes. One hundred twenty-two samples were collected from the Aosta Valley region in the years 2007 and 2008 (61 per year), and analysed for pH, electrical conductivity, total dissolved solids (TDS), total hardness, major cations and anions. The pH of the samples in both years indicated a near-neutral to alkaline nature of the groundwater. The cation and anion chemistry showed the general ionic abundance as: Ca²⁺ > Mg²⁺ > Na⁺ > K⁺ and HCO₃ ^?>SO₄ ^2?>Cl^?>NO₃ ^?>F^? in both years. Ca²⁺-Mg²⁺-HCO₃ ^? and Ca²⁺-Mg²⁺-Cl^?-SO₄ ^2? were the dominant hydrogeochemical facies. The computed saturation indices demonstrated that the groundwater was supersaturated with respect to dolomite and calcite in both years. The groundwater chemistry of the study area was mainly controlled by the dissolution of carbonate, sulphate and silicate minerals, as well as ion exchange processes. A comparison of the groundwater quality in relation to drinking water standards showed that most of the water samples were suitable for drinking and domestic uses. The computed water quality index (WQI) values of the study area groundwater ranged from 24 to 84 in the year 2007 and from 22 to 82 in the year 2008, and all the location fell under the Excellent to Good category. Quality assessment for irrigation uses revealed that the groundwater was good to permissible quality for irrigation; however, locally higher salinity, residual sodium carbonate (RSC) and magnesium hazard (MH) restricted its suitability for irrigation at a few sites. These results will be useful in implementing future measures in groundwater resource management at regional and national level.     

Variations of trace gases over the Bay of Bengal during the summer monsoon

In situ measurements of near-surface ozone (\(\hbox {O}_{3})\), carbon monoxide (CO), and methane (\(\hbox {CH}_{4})\) were carried out over the Bay of Bengal (BoB) as a part of the Continental Tropical Convergence Zone (CTCZ) campaign during the summer monsoon season of 2009. \(\hbox {O}_{3}\), CO and \(\hbox {CH}_{4}\) mixing ratios varied in the ranges of 8–54 ppbv, 50–200 ppbv and 1.57–2.15 ppmv, respectively during 16 July–17 August 2009. The spatial distribution of mean tropospheric \(\hbox {O}_{3}\) from satellite retrievals is found to be similar to that in surface \(\hbox {O}_{3}\) observations, with higher levels over coastal and northern BoB as compared to central BoB. The comparison of in situ measurements with the Monitoring Atmospheric Composition & Climate (MACC) global reanalysis shows that MACC simulations reproduce the observations with small mean biases of 1.6 ppbv, –2.6 ppbv and 0.07 ppmv for \(\hbox {O}_{3}\), CO and \(\hbox {CH}_{4}\), respectively. The analysis of diurnal variation of \(\hbox {O}_{3}\) based on observations and the simulations from Weather Research and Forecasting coupled with Chemistry (WRF-Chem) at a stationary point over the BoB did not show a net photochemical build up during daytime. Satellite retrievals show limitations in capturing \(\hbox {CH}_{4}\) variations as measured by in situ sample analysis highlighting the need of more shipborne in situ measurements of trace gases over this region during monsoon.     

Software for interactively visualizing solar vector magnetograms of udaipur solar observatory

The Solar Vector Magnetograph (SVM) at Udaipur Solar Observatory saw its first light in April 2005. The retrieval of vector fields from the imaging spectro-polarimetric observational data requires a substantial amount of computer post-processing. The GUI-based data reduction and analysis software have been developed to make the data processing pipeline user-friendly and less time-consuming. In this paper we describe these software packages.     

Is tidal forcing critical to trigger large Sumatra earthquakes?

Complexity in the earthquake mechanism is manifested in different forms such as fractal distribution, clustering of seismicity, etc., and characterized as critical phenomenon. Occurrences of earthquakes generally represent the state of metastable equilibrium. The Andaman–Sumatra subduction zone is one of the most seismically active corridors (possibly in metastable state) in the world. Recently, the region faced three major earthquakes of magnitude more than 8.5 (M ~ 9.1 on December 26, 2004; M ~ 8.6 on March 28, 2005; M ~ 8.6 on April 11, 2012). Researchers have suggested multiple causes of earthquake generation in this region including the one with possible correlation of tidal stresses with earthquake occurrences. The latter issue, however, has been hotly debated in view of the fact that a small stress generated due to tidal forcing cannot cause such a bigger magnitude earthquake. We study here the impact of tidal forcing on critically generated earthquake phenomena. We examined the statistical behavior of recurrence time interval of earthquakes using the available data for period of about 40 years from 1973 to 2013. We constrain the simple empirical toy model using the concept of catastrophe theory to evaluate the impact of small tidal forcing on the critical state of earthquakes occurrences. In addition to the major role of Helmholtz free energy during the plate motion, our analysis suggests that the stability and critical behavior of the earthquake in Sumatra region could be associated with tidal forcing, however, only for triggering of some of the “Catastrophic–Chaotic” earthquake phenomenon.     

Soil characterization based on land cover heterogeneity over a tropical landscape: an integrated approach using earth observation data-sets

Soil is a vital part of the natural environment and is always responding to changes in environmental factors, along with the influences of anthropogenic factors and land use changes. The long-term change in soil properties will result in change in soil health and fertility, and hence the soil productivity. Hence, the main aim of this paper focuses on the analysis of land use/land cover (LULC) change pattern in spatial and temporal perspective and to present its impact on soil properties in the Merawu catchment over the period of 18?years. Post classification change detection was performed to quantify the decadal changes in historical LULC over the periods of 1991, 2001 and 2009. The pixel to pixel comparison method was used to detect the LULC of the area. The key LULC types were selected for investigation of soil properties. Soil samples were analysed in situ to measure the physicochemical soil properties. The results of this study show remarkable changes in LULC in the period of 18?years. The effect of land cover change on soil properties, soil compaction and soil strength was found to be significant at a level of <0.05.     

Density variation effect on multi-ions with kinetic Alfven wave around cusp region—a kinetic approach

The kinetic Alfven waves in the presence of homogeneous magnetic field plasma with multi-ions effect are investigated. The dispersion relation and normalised damping rate are derived for low-\(\beta\) plasma using kinetic theory. The effect of density variation of \(\text{H}^{+}\), \(\text{He}^{+}\) and \(\text{O}^{+}\) ions is observed on frequency and damping rate of the wave. The variation of frequency (\(\omega\)) and normalised damping rate (\(\gamma / \varOmega_{H^{ +}} \)) of the wave are studied with respect to \(k_{ \bot} \rho_{j}\), where \(k_{ \bot} \) is the perpendicular wave number, \(\rho_{j}\) is the ion gyroradius and \(j \) denotes \(\text{H}^{+}\), \(\text{He}^{+}\) and \(\text{O}^{+}\) ions. The variation with \(k_{ \bot} \rho_{j}\) is considered over wide range. The parameters appropriate to cusp region are used for the explanation of results. It is found that with hydrogen and helium ions gyration, the frequency of wave is influenced by the density variation of \(\text{H}^{+}\) and \(\text{He}^{+}\) ions but remains insensitive to the change in density of \(\text{O}^{+}\) ions. For oxygen ion gyration, the frequency of wave varies over a short range only for \(\text{O}^{+}\) ion density variation. The wave shows damping at lower altitude due to variation in density of lighter \(\text{H}^{+}\) and \(\text{He}^{+}\) ions whereas at higher altitude only heavy \(\text{O}^{+}\) ions contribute in wave damping. The damping of wave may be due to landau damping or energy transfer from wave to particles. The present study signifies that the both lighter and heavier ions dominate differently to change the characteristics of kinetic Alfven wave and density variation is also an important parameter to understand wave phenomena in cusp region.     

Influence of Relative Density on Static Soil–Structure Frictional Resistance of Dry and Saturated Sand

Soil–structure frictional resistance is required while designing foundation systems and retaining walls. Although much more attention has been paid in recent years regarding soil–structure interaction for dynamic loading, highly conservative values of the static frictional resistance between soil and structure are used in design. Not much emphasis has been given lately to evaluate static frictional resistance between soil and structure. In this study, a well graded sand, as per USCS classification system, was prepared in the laboratory at different relative densities and moisture contents i.e. dry and saturated, and frictional resistances of those soils were measured. Those soil samples were also sheared against wood, concrete, and steel blocks and corresponding soil–structure frictional resistances were measured. Moreover, similar experiments were performed for saturated and loose poorly graded sand (SP), silty sand (SM) and poorly graded sand with silt (SP–SM). The study result shows that the difference between frictional resistance of soil and skin friction depends on the type of soil, relative density and the moisture content. Interestingly, shear envelopes for soil–soil and soil–structure shearing resistance exhibited curvature. The traditionally adopted soil–structure frictional resistance values adopted by various geotechnical manuals were found to be highly conservative.