A Late Tournaisian synmetamorphic folding and thrusting event in the eastern Variscan foreland: 40Ar/39Ar evidence from the phyllites of the Wolsztyn–Leszno High,western Poland

A Variscan foreland in western Poland comprises two NW-trending basement highs, which are concealed under Carboniferous through Triassic strata of the Fore-Sudetic Monocline (FSM). Both highs consist of multiply deformed quartz-sericite - albite - chlorite phyllites of unknown protolith age. ⁴⁰Ar/³⁹Ar laser probe dating of white micas in up to 0.5-mm-thick mica layers, which form the S₂ axial-plane foliation in phyllites of the Wolsztyn-Leszno High, yielded an age of 340.1DŽ.6 Ma for the lower greenschists facies metamorphism and probably also for the F₂ folding. This deformation was associated and followed by thrusting, which brought about the basement highs. The latter delivered clasts to overlying late Viséan-early Namurian flysch basin that was mainly sourced from the Saxothuringian Sudetes in which most of the deformation occurred between 345-335 Ma. The FSM basement may represent an independent terrane, referred to as the Wielkopolska terrane, belonging to the Armorican Terrane Assemblage.     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Supergranule and Mesogranule Evolution

The MDI instrument on the SOHO satellite obtained a nearly continuous 45.5-hr run in high-resolution mode on 17–18 January 1997, collecting continuum, Dopplergram, and magnetogram images once per minute. This is one of the longest data sets yet obtained in this mode and shows significant evolution of the supergranulation pattern. After allowing for solar rotation within the fixed field of view, an area spanning 17° in latitude and 11° in longitude was extracted that covers the same area of the solar surface for the entire run. From the de-rotated continuum images, we computed flow maps of photospheric motions using local correlation techniques (LCT). Horizontal divergence maps constructed from the flow maps show local maxima of the size of mesogranules (5–10). We interpret these as mesogranules although the LCT flow map resolution (4.8 FWHM) may not completely resolve smaller mesogranules. Movies made from the divergence maps clearly show the outward convection (advection) of these mesogranules within each supergranule, and narrow boundaries of negative divergence outlining the supergranules. Several new supergranules are observed forming. These appear as areas of strong divergence that pop up between pre-existing supergranules and grow, pushing their neighbors apart. Others seem to perish between growing neighbors. We also computed the vertical component of vorticity from the flow maps. Movies of this vorticity do not show any obvious patterns.     

Products and Mechanism of the Gas Phase Reaction of Ozone with β-Pinene

Gas phase ozonolysis of -pinene was performedin a 570 l static reactor at 730 Torr and 296 K insynthetic air and the products were analysed by acombination of gas phase FTIR spectroscopy, HPLC andIC analyses of gas phase and aerosol samples,respectively. The reaction mechanism was investigatedby adding HCHO, HCOOH and H₂O as Criegeeintermediate scavenger and cyclohexane as OH radicalscavenger. Main identified products (yields inparentheses) in the presence of cyclohexane as OHradical scavenger were HCHO (0.65 ± 0.04),nopinone (0.16 ± 0.04), 3-hydroxy-nopinone (0.15± 0.05), CO₂ (0.20 ± 0.04), CO (0.030± 0.002), HCOOH (0.020 ± 0.002), the secondaryozonide of -pinene (0.16 ± 0.05), andcis-pinic acid (0.02 ± 0.01). The decompositionof the primary ozonide was found to yieldpredominantly the excited C₉-Criegee intermediateand HCHO (0.84 ± 0.04) and to a minor extent theexcited CH₂OO intermediate and nopinone (0.16± 0.04). Roughly 40% of the excitedC₉-Criegee intermediate becomes stabilised andcould be shown to react with HCHO, HCOOH and H₂O. The atmospherically important reaction of thestabilised C₉-Criegee intermediate with H₂Owas found to result in a nopinone increase of (0.35± 0.05) and in the formation of H₂O₂(0.24 ± 0.03). Based on the observed products,the unimolecular decomposition/isomerisationchannels of the C₉-Criegee intermediate arediscussed in terms of the hydroperoxide and esterchannels. Subsequent reactions of the nopinonylradical, formed in the hydroperoxide channel, lead tomajor products like 3-hydroxy-nopinone but also tominor products like cis-pinic acid. A mechanismfor the formation of this dicarboxylic acid isproposed and its possible role in aerosol formationprocesses discussed.     

Mathematical expressions used in amino acid racemisation geochronology—A review

A variety of mathematical expressions that describe changes over time (t) in the extent of amino acid racemisation (AAR, expressed as the ratio of d- to l-amino acid isomers or epimers) have been used in Quaternary geochronology. The integrated rate equation was first used to estimate fossil age from D/L but its geochronological utility is disadvantaged by uncertainties regarding the conformity of AAR in fossil protein to apparent reversible first-order kinetics for the entire reaction history. ‘Non-linear’ models have subsequently been used to relate D/L to t. The logarithmic equation successfully applied to Atlantic Coastal Plain research has not achieved widespread application, perhaps due to the regional calibration required if sensitivity to temperature is to be modelled, or the difficulties encountered when extending the model to include fossils with D/L<0.1. Success producing a linear correlation between D/L transformed with a power function and t has seen this approach emerge as one of the most commonly applied in AAR geochronology in recent years. Like parabola curve fitting, which has been applied to trends in D/L versus t in a variety of fossils and geographic settings, power transformations may not be suitable for geochronological modelling during the latter stages of amino acid diagenesis. Several studies have demonstrated the utility of simple and contingent linear equations for relating D/L to t. Future research should aim to reduce reliance on independent calibration and explore the geochronological benefits of AAR in pools other than the total hydrolysable amino acids.     

Brest sea level record: a time series construction back to the early eighteenth century

The completeness and the accuracy of the Brest sea level time series dating from 1807 make it suitable for long-term sea level trend studies. New data sets were recently discovered in the form of handwritten tabulations, including several decades of the eighteenth century. Sea level observations have been made in Brest since 1679. This paper presents the historical data sets which have been assembled so far. These data sets span approximately 300 years and together constitute the longest, near-continuous set of sea level information in France. However, an important question arises: Can we relate the past and the present-day records? We partially provide an answer to this question by analysing the documents of several historical libraries with the tidal data using a ‘data archaeology’ approach advocated by Woodworth (Geophys Res Lett 26:1589–1592, 1999b). A second question arises concerning the accuracy of such records. Careful editing was undertaken by examining the residuals between tidal predictions and observations. It proved useful to remove the worst effects of timing errors, in particular the sundial correction to be applied prior to August 1, 1714. A refined correction based on sundial literature [Savoie, La gnomique, Editions Les Belles Lettres, Paris, 2001] is proposed, which eliminates the systematic offsets seen in the discrepancies in timing of the sea level measurements. The tidal analysis has also shown that shallow-water tidal harmonics at Brest causes a systematic difference of 0.023 m between mean sea level (MSL) and mean tide level (MTL). Thus, MTL should not be mixed with the time series of MSL because of this systematic offset. The study of the trends in MTL and MSL however indicates that MTL can be used as a proxy for MSL. Three linear trend periods are distinguished in the Brest MTL time series over the period 1807–2004. Our results support the recent findings of Holgate and Woodworth (Geophys Res Lett) of an enhanced coastal sea level rise during the last decade compared to the global estimations of about 1.8 mm/year over longer periods (Douglas, J Geophys Res 96:6981–6992, 1991). The onset of the relatively large global sea level trends observed in the twentieth century is an important question in the science of climate change. Our findings point out to an ‘inflexion point’ at around 1890, which is remarkably close to that in 1880 found in the Liverpool record by Woodworth (Geophys Res Lett 26:1589–1592, 1999b).     

What Happened in the Trans-North China Orogen in the Period 2560-1850 Ma？

The Trans-North China Orogen （TNCO） was a Paleoproterozic continent-continent collisional belt along which the Eastern and Western Blocks amalgamated to form a coherent North China Craton （NCC）. Recent geological, structural, geochemical and isotopic data show that the orogen was a continental margin or Japan-type arc along the western margin of the Eastern Block, which was separated from the Western Block by an old ocean, with eastward-directed subduction of the oceanic lithosphere beneath the western margin of the Eastern Block. At 2550-2520 Ma, the deep subduction caused partial melting of the medium-lower crust, producing copious granitoid magma that was intruded into the upper levels of the crust to form granitoid plutons in the low- to medium-grade granite-greeustone terranes. At 2530-2520 Ma, subduction of the oceanic lithosphere caused partial melting of the mantle wedge, which led to underplating of mafic magma in the lower crust and widespread mafic and minor felsic volcanism in the arc, forming part of the greenstone assemblages. Extension driven by widespread mafic to felsic volcanism led to the development of back-arc and/or intra-arc basins in the orogen. At 2520-2475 Ma, the subduction caused further partial melting of the lower crust to form large amounts of tonalitic-trondhjemitic-granodioritic （TTG） magmatism. At this time following further extension of back-arc basins, episodic granitoid magmatism occurred, resulting in the emplacement of 2360 Ma, -2250 Ma 2110-21760 Ma and -2050 Ma granites in the orogen. Contemporary volcano-sedimentary rocks developed in the back-arc or intra-are basins. At 2150-1920 Ma, the orogen underwent several extensional events, possibly due to subduction of an oceanic ridge, leading to emplacement of mafic dykes that were subsequently metamorphosed to amphibolites and medium- to high-pressure mafic granulites. At 1880-1820 Ma, the ocean between the Eastern and Western Blocks was completely consumed by subduction, and the dosing of the ocean led to the continent-arc-continent collision, which caused large-scale thrusting and isoclinal folds and transported some of the rocks into the lower crustal levels or upper mantle to form granulites or eclogites. Peak metamorphism was followed by exhumation/uplift, resulting in widespread development of asymmetric folds and symplectic textures in the rocks.     

Some economics of ‘dangerous’ climate change: Reflections on the Stern Review

The Stern Review on the Economics of Climate Change concluded that there can be “no doubt” the economic risks of business-as-usual (BAU) climate change are “very severe” [Stern, 2006. The Economics of Climate Change. HM Treasury, London, p. 188]. The total cost of climate change was estimated to be equivalent to a one-off, permanent 5–20% loss in global mean per-capita consumption today. And the marginal damage cost of a tonne of carbon emitted today was estimated to be around $312 [p. 344]. Both of these estimates are higher than most reported in the previous literature. Subsequently, a number of critiques have appeared, arguing that discounting is the principal explanation for this discrepancy. Discounting is important, but in this paper we emphasise that how one approaches the economics of risk and uncertainty, and how one attempts to model the very closely related issue of low-probability/high-damage scenarios (which we connect to the recent discussion of ‘dangerous’ climate change), can matter just as much. We demonstrate these arguments empirically, using the same models applied in the Stern Review. Together, the issues of risk and uncertainty on the one hand, and ‘dangerous’ climate change on the other, raise very strongly questions about the limits of a welfare-economic approach, where the loss of natural capital might be irreversible and impossible to compensate. Thus we also critically reflect on the state-of-the-art in integrated assessment modelling. There will always be an imperative to carry out integrated assessment modelling, bringing together scientific ‘fact’ and value judgement systematically. But we agree with those cautioning against a literal interpretation of current estimates. Ironically, the Stern Review is one of those voices. A fixation with cost-benefit analysis misses the point that arguments for stabilisation should, and are, built on broader foundations.     

A Pb-Ra-Th-U study of Klyuchevskoy and Bezymianny volcanoes, Kamchatka

Lavas from Klyuchevskoy and Bezymianny volcanoes, Kamchatka, appear to show a link between the extent of partial melting in their mantle source region and the subsequent degree of fractionation suffered by the magmas during passage through the crust. This fractionation may have occurred on timescales significantly less than 1000 years if observed ²²⁶Ra excesses largely reflect variable residual porosity in the source melting region. Unlike most arc lavas, those with the highest MgO contents and Ba/Th ratios have the lowest ²²⁶Ra excess. Forward models suggest that those portions of the source which had undergone the greatest addition of U by fluids from the subducting plate also underwent the greatest extents of partial melting at the highest residual porosity. At Kluchevskoy, a change from eruption of high-MgO to high-Al₂O₃ basaltic andesites around 1945 is reflected in an increase in size of ²²⁶Ra excess which seems to require a simultaneous decrease in residual porosity and suggests a rapid changes in the melting regime. The eruption of andesites at Bezyminanny, simultaneous with the eruption of basaltic andesites at Klyuchevskoy, further suggests that different degree melts produced at differing residual porosity can be formed and extracted from the melt region at the same time. Thus, the melting processes beneath Klyuchevskoy and Bezyminanny are demonstrably complex. They have clearly been influenced by both fluid addition from the subducting plate and extension and decompression beneath the Central Kamchatka Depression. Finally, the ²¹⁰Pb data are, with one or two exceptions, in equilibrium with ²²⁶Ra, suggesting that there was restricted relative magma-gas movement in this highly productive magmatic system.     

Paleoceanographic evolution of the SW Svalbard margin (76°N) since 20,000 C yr BP

Two cores from the southwestern shelf and slope of Storfjorden, Svalbard, taken at 389 m and 1485 m water depth have been analyzed for benthic and planktic foraminifera, oxygen isotopes, and ice-rafted debris. The results show that over the last 20,000 yr, Atlantic water has been continuously present on the southwestern Svalbard shelf. However, from 15,000 to 10,000 ¹⁴C yr BP, comprising the Heinrich event H1 interval, the Bølling-Allerød interstades and the Younger Dryas stade, it flowed as a subsurface water mass below a layer of polar surface water. In the benthic environment, the shift to interglacial conditions occurred at 10,000 ¹⁴C yr BP. Due to the presence of a thin upper layer of polar water, surface conditions remained cold until ca. 9000 ¹⁴C yr BP, when the warm Atlantic water finally appeared at the surface. Neither extensive sea ice cover nor large inputs of meltwater stopped the inflow of Atlantic water. Its warm core was merely submerged below the cold polar surface water.