Phytoplankton,protozooplankton and nutrient dynamics in the Bornholm Basin (Baltic Sea) in 2002–2003 during the German GLOBEC Project

From March 2002 to until April 2003 we investigated the seasonal nutrient and phytoplankton dynamics in the central Bornholm Basin (Baltic Sea) within the framework of the German GLOBEC Project. We choose a nested approach consisting of vertical fluorescence profiles, phytoplankton counts and nutrient analyses. The Fluoroprobe (MultiProbe, BBE Moldaenke) is capable of distinguishing four algal groups (Cryptophyceae, Cyanophyceae, Chlorophyceae, Bacillariophyceae + Dinophyceae). Winter nutrient concentrations were about 5 μM NO₃ and 0.5 μM PO₄ in the central Basin. The spring phytoplankton bloom was dominated by the diatom Skeletonema sp. and reached a maximum of about 270 μg C/l before the onset of the seasonal stratification. Protozooplankton was dominated by the Mesodinium rubrum (a phototrophic ciliate = Myrionecta rubra) and reached a maximum biomass of about 200–300 μg C/l about 2 weeks after the demise of the diatom spring bloom. During summer, the water column was stratified and a subsurface maximum developed near the thermocline consisting of Bacillariophyceae, Cryptophycea and other phototrophic flagellates. Phytoplankton and protozooplankton biomass was generally low. Nutrient concentrations point towards a nitrogen limitation during this period. The stratification period ended during September and surface nutrient concentrations increased again. Protozooplankton reached a second maximum during September. With the Fluoroprobe small scale structures in the plankton community could be detected like a subsurface Cryptophyceae maximum near the thermocline that however, could not be confirmed by cell counts. The chlorophyll a estimate of the Fluoroprobe was in good agreement with the phytoplankton biomass estimated from counts. We conclude that only by combining modern sensing technology with microscopy, the small-scale dynamics and taxonomic spectrum of the plankton can be fully captured.     

An Inter-Laboratory Assessment of the Thorium Isotopic Composition of Synthetic and Rock Reference Materials

We present a concerted international effort to cross-calibrate five synthetic Th isotope reference materials (UCSC Th "A", OU Th "U", WUN, IRMM-35 and IRMM-36), and six rock reference materials (UCSC TML, Icelandic ATHO, USGS BCR-2, USGS W-2, USGS BHVO-2, LV18) using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). We then compare our new values with a compilation of literature mass spectrometric data for these reference materials and derive recommended "consensus"²³⁰Th/²³²Th values for each. We also present isotope dilution U and Th concentration data for four rock reference materials (UCSC TML, Icelandic ATHO, USGS BCR-2, USGS W-2).     

ESP: a tool to estimate scale parameter for multiresolution image segmentation of remotely sensed data

The spatial resolution of imaging sensors has increased dramatically in recent years, and so too have the challenges associated with extracting meaningful information from their data products. Object-based image analysis (OBIA) is gaining rapid popularity in remote sensing science as a means of bridging very high spatial resolution (VHSR) imagery and GIS. Multiscalar image segmentation is a fundamental step in OBIA, yet there is currently no tool available to objectively guide the selection of appropriate scales for segmentation. We present a technique for estimating the scale parameter in image segmentation of remotely sensed data with Definiens Developer®. The degree of heterogeneity within an image-object is controlled by a subjective measure called the ‘scale parameter’, as implemented in the mentioned software. We propose a tool, called estimation of scale parameter (ESP), that builds on the idea of local variance (LV) of object heterogeneity within a scene. The ESP tool iteratively generates image-objects at multiple scale levels in a bottom-up approach and calculates the LV for each scale. Variation in heterogeneity is explored by evaluating LV plotted against the corresponding scale. The thresholds in rates of change of LV (ROC-LV) indicate the scale levels at which the image can be segmented in the most appropriate manner, relative to the data properties at the scene level. Our tests on different types of imagery indicated fast processing times and accurate results. The simple yet robust ESP tool enables fast and objective parametrization when performing image segmentation and holds great potential for OBIA applications.     

Combination of common-midpoint-refraction seismics with the generalized reciprocal method

A useful method for increasing the signal/noise ratio of refracted waves is Common-Midpoint (CMP)-refraction seismics. With this technique the shallow underground can be described in detail using all information (amplitude, frequency, phase characteristics) of the wavetrain following the first break (first-break phase). Thus, the layering can be determined and faults, weak zones, and clefts can be identified. This paper deals with the optimization of CMP-refraction seismics used in combination with the Generalized Reciprocal Method (GRM). Theoretical studies show a close relationship of both methods to the kinematics of wave propagation. Velocities and optimum offsets determined by the GRM can be used directly in the partial Radon transformation in CMP-refraction seismics. The integration of refracted waves leads to an increase in the signal/noise ratio but simultaneously the integration boundaries must be restricted to deal only with selective parts of the investigated refractor. The result of this process is an intercept-time section which can be converted directly to a depth section using standard refraction seismic techniques. Another possibility of depth conversion is the transformation of this intercept-time section to a `pseudo-zero-offset section', known from reflection seismics. Thus, zero-offset sections can be migrated using wave-equation techniques such as Kirchhoff migration.     

Anisotropic reflection coefficients for a weak-contrast interface

In this article the interaction of plane waves with a weak-contrast interface between two weakly anisotropic half-spaces is investigated. The anisotropy dealt with is of a general type. The stress–displacement vectors of the plane waves are calculated by perturbation theory. By assuming that the jump in elastic parameters and density across the interface is small, one can derive a simple expression for the R _qPqP coefficient. In cases in which the wave motion is restricted to a symmetry plane of an anisotropic medium, simple expressions for the R _qSVqSV and R _SHSH coefficients are also derived.     

Reconstruction of palaeohydrological conditions in a lagoon during the 2nd Zechstein cycle through simultaneous use of δD values of individual n-alkanes and δ<Superscript>18</Superscript>O and δ<Superscript>13</Superscript>C values of carbonates

For the first time ¹⁸O and ¹³C values from carbonates and D values of individual n-alkanes were used to reconstruct palaeohydrological conditions in a lagoon at the southern margin of the Central European Zechstein Basin (CEZB). A 12-m core covering the complete Ca2 interval and adjacent anhydrites (A1 and A2) was analyzed for ¹⁸O and ¹³C values of dolomitized carbonates and D values of individual n-alkanes. ¹⁸O_carb values (+2 to +5 vs. VPDB) were strongly influenced by evaporation and temporal freshwater input into the lagoon. The ¹³C_carb values (–1 to +4 vs. VPDB) were controlled mainly by changes in primary production. Both isotopic ratios show an inverse relationship throughout most of the core, contradicting diagenetic alteration, since ¹³C_carb values are not altered significantly during dolomitization. Assuming a temperature range of 35–40 °C in the lagoon, ¹⁸O_carb values of +2.5 to +8 (vs. VSMOW) for the lagoonal water can be reconstructed. The lagoon may have desiccated twice during the Ca2 interval, as indicated by very high ¹⁸O_carb and low ¹³C_carb values, coinciding with increasing amount of anhydrite in the analyzed sample. These events seem to reflect not just local but a regional intra-Ca2 cyclicity. Measured D values of the short-chain n-alkanes, namely n-C₁₆ and n-C₁₈ which are widely used as indicators for photosynthetic bacterial and algal input, reflect the isotopic composition of the lagoonal water. Assuming constant fractionation during incorporation of hydrogen into lipids of –160, an average D value of +70 (vs. VSMOW) can be reconstructed for the lagoonal water, accounting for very arid conditions. The long-chain n-alkanes n-C₂₇, n-C₂₈, n-C₂₉ and n-C₃₀, thought to be derived from the leaf waxes of terrestrial higher plants, were shown to be depleted in D relative to the short-chain alkanes, therefore indicating a different hydrogen source. Terrestrial plants in arid areas mainly use water supplied by precipitation. By using a smaller fractionation of –120 due to evaporation processes in the leaves, reconstructed values vary between –74 and –9 (vs. VSMOW). These values are not indicating extremely arid conditions, implying that the long-chain n-alkanes were transported trough wind and/or rivers into the lagoon at the Zechstein Sea coast. D_water values, reconstructed using the n-C₁₆ alkane and ¹⁸O _water values, independently reconstructed on the same sample using the temperature dependant fractionation for dolomites are good agreement and suggest high amounts of evaporation affecting the coastal lagoon. Altogether, our results indicate that hydrogen isotopic ratios of n-alkanes give information on their origin and are a useful proxy for palaeoclimatic reconstruction.     

Laboratory experiments on wave transmission by overtopping

Laboratory experiments with regular waves were used to investigate wave transmission by overtopping for a smooth, impermeable breakwater with a 1-in-4 slope.A resulting relationship between the transmission coefficient and a breakwater height above mean sea level normalized with a theoretical wave run-up height is reported in this paper.     

Changes in structural and functional diversity of nematode communities during a spring phytoplankton bloom in the southern North Sea

The response of nematode communities to the sedimentation of a spring phytoplankton bloom in a sandy, well-oxygenated sediment at a single station (station 330) in the Southern North Sea was investigated monthly from early March to July 1999. Both structural (nematode density, diversity, vertical distribution and community composition) and functional (feeding type distributions, number of species within feeding groups) characteristics showed considerable changes shortly after the arrival of fresh organic material at the sediment surface. The general increase in numerical densities and diversity was related to changes within the groups of selective deposit-feeding and epistrate-feeding nematodes. It is hypothesised that sedimentation and subsequent remineralisation of fresh organic matter during the spring phytoplankton bloom result in an increase of suitable food items (both living and dead). This, combined with the availability of oxygen, creates conditions in which many nematode species can co-exist.     

Trace elements in suspended matter from the anoxic hypersaline Tyro and Bannock Basins (eastern Mediterranean)

In the anoxic hypersaline Tyro and Bannock Basins of the eastern Mediterranean, extremely high concentrations of Co (0.015%), Cu (1.35%) and Zn (0.28%) were found in suspended matter collected at the sharp interface between seawater and the anoxic brine. The high particulate Co, Cu and Zn concentrations can be explained by the sharp increase in dissolved sulphide at these interfaces, and the resultant precipitation of metal sulphides. The particulate As, Sb and Mo concentrations also showed a sharp maximum at or close to the interface. However, the contributions of As, Sb and Mo contents in suspended matter to the total concentrations in the water column are small. Scanning electron microscopy-energy-dispersive X-ray analysis (SEM-EDAX) of suspended particulate matter from the Tyro Basin revealed spherical particles strongly enriched in Fe, Cu and Zn at the seawater-brine interface.     

Late Quaternary polycystine radiolarian datum events in the Sea of Okhotsk

Five radiolarian datum events have been recorded in the Late Quaternary sediment section from the Sea of Okhotsk, using age assignments based on oxygen-isotope stratigraphy: the last occurrence datum (LOD) of Stylacontarium acquilonium (at about 329 ka), the LOD of Spongodiscus sp. (at about 287 ka), the LOD of Amphimelissa setosa (at about 72 ka), the LOD of Lychnocanoma nipponica sakaii (at about 28 ka), and the L. nipponica sakaii acme event (at about 72 ka). The LODs of S. acquilonium, Spongodiscus sp. and A. setosa appear to be synchronous in comparison with those in the Subarctic North Pacific, but the LOD and the acme event of L. nipponica sakaii show an apparent diachroneity with the corresponding North Pacific events.