微型活性碳柱富集比色法测定金

本文探讨了用微型活性碳柱富集痕量金的方法。研究了富集金和TMK—Au—Twee 85显色反应的条件,用本法测定了地质试样中痕量金,其测定限为2 ppbAu,本法操作简便、快速,灵敏度高,结果较为满意。     

The formation of porphyry copper deposits

Copper is a moderately incompatible chalcophile element. Its behavior is strongly controlled by sulfides. The speciation of sulfur is controlled by oxygen fugacity. Therefore, porphyry Cu deposits are usually oxidized (with oxygen fugacities > ΔFMQ +2) (Mungall 2002; Sun et al. 2015). The problem is that while most of the magmas at convergent margins are highly oxidized, porphyry Cu deposits are very rare, suggesting that high oxygen fugacity alone is not sufficient. Partial melting of mantle peridotite even at very high oxygen fugacities forms arc magmas with initial Cu contents too low to form porphyry Cu deposits directly (Lee et al. 2012; Wilkinson 2013). Here we show that partial melting of subducted young oceanic slabs at high oxygen fugacity (>ΔFMQ +2) may form magmas with initial Cu contents up to >500 ppm, favorable for porphyry mineralization. Pre-enrichment of Cu through sulfide saturation and accumulation is not necessarily beneficial to porphyry Cu mineralization. In contrast, re-melting of porphyritic hydrothermal sulfide associated with iron oxides may have major contributions to porphyry deposits. Thick overriding continental crust reduces the “leakage” of hydrothermal fluids, thereby promoting porphyry mineralization. Nevertheless, it is also more difficult for ore forming fluids to penetrate the thick continental crust to reach the depths of 2–4 km where porphyry deposits form.     

调整的生态足迹方法在辽宁省的应用研究

应用调整的生态足迹方法,对辽宁省1996—2003年的生态足迹进行了计算与分析,从纵向比较并分析了辽宁省近年来在发展过程中所受到的环境压力.结果表明:辽宁省1996—2003年生态超载指数都大于2,有的年份甚至接近于3,这说明辽宁省当前的生物资源的生产和能源的消费的能力远超过其生态承载能力,即生态资源处于高强度利用状态,生态环境有潜在恶化的趋势.辽宁省1996—2003年生态效率稳步上升,从1996年的2 569元·hm^-2上升到2003年的4 101元·hm^-2,提高了0.6倍,年平均增长率为7.5%.但与其它工业化国家相比还有很大的差距,这说明辽宁省在提高生态效率方面还有更大的潜力.     

孟加拉湾晚第四纪的碳酸盐溶解旋回

孟加拉湾由于陆源物质大量输入产生稀释效应,使碳酸盐含量表现为冰期时减小、间冰期时增大的“大西洋型”旋回。通过对该区四支活塞岩芯的有孔虫溶解指数、浮游有孔虫沉积通量、CaCO₃ 沉积通量和 >16 0 μm粗组分沉积通量的分析发现,研究区碳酸盐溶解作用强烈,表现出冰期减弱而间冰期增强的总趋势,且溶解作用滞后于浮游有孔虫壳的氧同位素旋回,尤以氧同位素 4、5期的高溶解度情况与印度洋和太平洋氧同位素 5期晚期至 4期为CaCO₃溶解高峰一致。因此,孟加拉湾地区的CaCO₃ 旋回是大西洋型稀释作用与太平洋型溶解作用两者叠加的产物.     

三维地质图制作方法——以1∶50万海南岛地质图为例

将Global Mapper、ArcGIS、MapGIS三款GIS软件有效结合起来,以海南岛为例进行基于DEM的三维晕渲地质图的制作方法研究。首先将SRTM数据和矢量地理数据在不同地图参数下进行自动配准,然后实现地质要素与DEM模型的精准匹配,最后根据DEM对第四系地质界线进行微调,实现了1∶50万海南岛三维地质图的制作。同时总结了不同椭球体与坐标系统下的数据转换、DEM空白区数据填补、晕渲地质图生产的方法。三维地质图制作所采用的DEM数据完全满足1∶50万三维地质图的制图要求;与传统地质图相比,其立体感和可读性明显增强,图件信息量显著增大,图面呈现清晰的三维地质结构,很好地提高了制图精度。该方法为我国三维地质图的制作提供了一个新的方法和思路,并为其他三维图件制作提供了参考借鉴。     

山东刚玉巨晶中包裹体研究Ⅱ：氯化物与地幔液相的物质组成

利用电子探针,扫描电镜在山东碱性玄武岩中产出的刚玉巨晶中发现了许多氯化物包裹体,这些氯化物可能以石盐为主,它的发现表明在较浅深度的地幔液相中也存在较多的氯。     

The 30–60-day Intraseasonal Oscillations over the Subtropical Western North Pacific during the Summer of 1998简

The features of 30-60-day convection oscillations over the subtropical western North Pacific （WNP） were investigated, along with the degree of tropical-subtropical linkage between the oscillations over the WNP during summer 1998. It was found that 30-60-day oscillations were extremely strong in that summer over both the subtropical and tro]~ical WNP, providing a unique opportunity to study the behavior of subtropical oscillations and their relationship to tropical oscillations. Further analyses indicated that 30-60-day oscillations propagate westwards over the subtropical WNP and reach eastern China. In addition, 30-60-day oscillations in the subtropics are affected by those over the South China Sea （SCS） and tropical WNP through two mechanisms： （1） direct propagation from the tropics into the subtropics; and （2） a seesaw pattern between the tropics and subtropics, with the latter being predominant.     

Model for Methane Emission from Rice Fields and Its Application in Southern China

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气象场经验正交函数不同展开方案收敛性问题的探讨

本文从理论上证明EOFs(经验正交函数)用于气象场时,三种不同计算方案特征值的相互关系.指出利用原始场积和矩阵展开的特征值λ_j等于用协方差阵展开的特征值λ_j~*加上平均场方差引起的特征值λ_j.进而论证了收敛速度差舁的原因.最后又以实例表明,不同展开方案的典型场意义及其与时间权重系数的对应关系.     

中国东部降水的随机动力预测初步研究

利用一个具有门限的非线性随机动力气候模式,对中国东部江淮流域的降水进行了预报试验。结果表明：模式能对大范围环流降水作出较为准确的形势预报。还比较了海气耦合模式与外强迫模式的预报效果,表明耦合模式的预报效果略好于外强迫模式。