Mineralization time and tectonic setting of the Zhengguang Au deposit in the Duobaoshan ore field,Heilongjiang Province,NE China

The Zhengguang deposit, a representative large gold deposit in the Duobaoshan ore field in NE China, is located in the northeast of the Central Asian Orogenic Belt (CAOB). Ore body emplacement was structurally controlled and occurs mainly at the contact zone between the strata of Duobaoshan Formation and an Ordovician diorite stock. The diorite rocks have a close genetic relationship with Au mineralization. Re–Os isotope dating of Au-bearing pyrite yields an isochron age of 506 ± 44 Ma (MSWD = 15). Based on present and previous dating results, it can be concluded that the Zhengguang deposit formed at ~480 Ma. The mineralization time of the Zhengguang deposit is nearly identical to those of the Duobaoshan and Tongshan deposits, indicating they are all derived from the same metallogenic system. The Duobaoshan-style porphyry Cu–Mo mineralization may exist at deeper levels at Zhengguang. The geochemical characteristics of the Zhengguang dioritic rocks presented in this paper are similar to those of bajaitic high-Mg andesite, and the magmas originated from a mantle wedge metasomatized by melts from a subducting oceanic slab at an active continental margin setting. The Ordovician magmatic–metallogenic events in the Duobaoshan ore field were caused by the westward subduction of an oceanic slab located between the Xing’an and Songliao blocks. It is worth pointing out that the Zhengguang deposit is the oldest known Phanerozoic Au deposit in NE China. Further studies of this deposit will improve understanding of the regularity of ore formation and aid mineralization forecast across the Duobaoshan region.     

新疆乌鲁木齐东部早二叠世枕状玄武岩火山岩系的发现及大地构造意义

新疆乌鲁木齐东部野生动物园附近的下二叠统下部发育了一套以枕状玄武岩为代表的火山岩系。该玄武岩在公路上发育有两层,上部一层较厚,可达7～8m,下部一层2～3m。岩枕近圆形、肾状、枕状、条带状或蠕虫状等,多呈顶突底凹。岩枕长轴平行排列,长轴基本顺层面分布;有的岩枕中含大量海百合茎、珊瑚及腕足等生物化石。在TAS图中大部分样品位于玄武粗安岩,而在K_2O-SiO_2图上主要落在低K拉斑玄武岩区间。MnOTiO_2-P_2O_5图解显示以岛弧为主,常量元素的特征总体上更接近岛弧玄武岩。在Hf/3-Th-Ta图解上也以岛弧为主;在Zr/4-2Nb-Y图解显示以火山弧为主,常量元素的特点总体上更接近岛弧玄武岩。微量元素原始地幔标准化蛛网图表明为同源岩浆产物,具高度相似的演化过程,多种微量元素判别图揭示岛弧-弧后盆地环境;稀土总量明显较低,在稀土元素球粒陨石标准化图解上,其稀土分布曲线一致性较好,呈轻稀土富集右倾型,Eu为负异常,揭示了乌东玄武岩岩浆有一定分异。稀土元素配分曲线与弧后盆地玄武岩(BABB)具有很好的一致性。U-Pb和谐年龄为283±8Ma,结合地层及古生物资料推测乌东玄武岩喷发的时间为早二叠世早期。乌东枕状玄武岩-灰岩之下有一套(磨拉石)底砾岩,初定为石炭-二叠系的界限。底砾岩之下为下石炭统的中厚层灰岩,具有明显的喀斯特化,为不整合接触,揭示在两者之间发生了造山作用。通过对新疆乌东早二叠世早期的枕状玄武岩的地质特征、地球化学特征、形成环境和时代的研究,表明乌东一带早二叠世主要为一个岛弧和弧后盆地环境,进一步揭示了北天山北缘石炭-二叠世碰撞闭合造山之后又发生了松弛扩张形成了弧后盆地,海水再度大规模入侵。最终的闭合碰撞造山的时间最早可能在晚二叠世。由于乌东枕状玄武岩在喷出地表后受到了生物化石和陆源碎屑的污染,再加上侵入过程中地壳的污染,使其具有非常复杂的地球化学特点和多解性。乌东玄武岩的研究对于了解博格达山、甚至天山中段在晚古生代的构造沉积演化及造山作用具有重要意义,同时对准噶尔盆地、吐哈盆地及三塘湖盆地油气资源的形成与分布具有重要意义。     

Metallogenic Mechanism and Tectonic Setting of Tungsten Mineralization in the Yangbishan Deposit in Northeastern China

The Yangbishan iron–tungsten deposit in the Shuangyashan area of Heilongjiang Province is located in the center of the Jiamusi Massif in northeastern China. The rare earth element and trace element compositions of the scheelite show that it formed in a reducing environment and inherited the rare earth element features of the ore-forming fluid. The geochemical characteristics of the gneissic granite associated with the tungsten mineralization show that the magma formed in this reducing environment and originated from the partial melting of metamorphosed shale that contained organic carbon and was enriched with tungsten. In addition, in situ Hf isotopic analysis of zircons from the gneissic granite indicates that they probably originated from the partial melting of a predominantly Paleo–Mesoproterozoic crustal source. According to LA-ICP-MS zircon dating, the Yangbishan orerelated gneissic granite has an Early Paleozoic crystallization age of 520.6 ± 2.8 Ma. This study, together with previous data, indicates that the massifs of northeastern China, including Erguna, Xing'an, Songliao, Jiamusi, and Khanka massifs, belonged to an orogenic belt that existed along the southern margin of the Siberian Craton during the late Pan-African period. The significant continental movements of this orogeny resulted in widespread magmatic activity in northeastern China from 530 Ma to 470 Ma under a tectonic setting that transitioned from compressional syn-collision to extensional postcollision.     

Constraints on sedimentary ages of the Chuanlinggou Formation in the Ming Tombs,Beijing, North China Craton: LA-ICP-MS and SHRIMP U–Pb dating of detrital zircons

Detrital zircons in five sedimentary samples, MC1 to MC5, from the bottom of the Chuanlinggou Formation in the Ming Tombs District, Beijing, were dated with the LA-ICP-MS and SHRIMP U–Pb methods. Age spectra of the five samples show a major peak at 2500 Ma and a secondary peak at 2000 Ma, suggesting their provenances were mainly from the crystalline basement of the North China Craton and the Trans-North China Orogen. The youngest zircon has an age of 1673 ± 44 Ma, indicating that the Chuanlinggou Formation was deposited after this age. From sample MC4 to MC5, lithology changed from a clastic rock (fine-grained sandstone) to a carbonate rock (fine-grained dolomite), suggesting that the depositional basin became progressively deeper. The age spectrum of sample MC5 shows a major peak at 2500 Ma and a secondary peak at 2000 Ma. Sample MC4, which is stratigraphically lower than sample MC5, only had one peak at 2500 Ma. We conclude that there was a transgressive event when sediments represented by MC5 was deposited, and seawater carried ca. 2000 Ma clastic materials to the basin where the Chuanlinggou Formation was deposited, leading to the addition of ca. 2000 Ma detritus. Our research indicates that the source area for the sediments became more extensive with time. We conclude that the Chuanlinggou Formation in the Ming Tombs District was deposited in a low-energy mud flat sedimentary environment in the inter-supra tidal zone because it is mainly composed of silty mudstone and fine-grained sandstone with relatively simple sedimentary structures.     

新疆三塘湖盆地上石炭统近源凝灰岩致密油藏形成条件

三塘湖盆地上石炭统烃源岩是火山喷发环境下形成的,烃源岩往往与厚度不等的凝灰岩交互出现,但凝灰岩致密储层的厚度和物性差异较大,源储关系较复杂,因而近源凝灰岩致密油藏的形成需要特定的条件。为了认识三塘湖盆地上石炭统近源凝灰岩致密油藏的形成条件,以典型致密油藏M36为例,综合运用岩心、薄片、测录井、地球化学测试等资料,对成藏要素进行解剖,建立上石炭统凝灰岩致密储层及烃源岩有效性的评价标准,并总结出近源致密油藏成藏模式。结果表明,储层孔隙度大于5%、对应渗透率大于0.07×10-3μm2的凝灰岩可以作为有效储层;烃源岩有机碳含量在4.0%以上,对应生烃潜量大于10%,且Ro大于0.8%的高炭泥岩、暗色泥岩为优质烃源岩;较好的储层、优质的烃源岩和互层型源储配置关系是近源凝灰岩致密油藏的形成条件。     

辽宁凌源四合当地区九佛堂组珍稀化石层划分及意义

辽宁省凌源市四合当地区九佛堂组含有丰富的中生代热河生物群化石,尤其是珍稀化石.通过剖面测制、化石采集以及实地调查等手段,将九佛堂组划分为3个段,确定了化石层的分布及重要化石的产出层位,同时命名了3个化石层：一段的韩家沟层、二段的卅二道湾层、三段的四合当层,加深了辽西九佛堂组化石层的研究程度.     

Investigation of gas content of organic-rich shale:A case study from Lower Permian shale in southern North China Basin,central China

Measuring gas content is an essential step in estimating the commerciality of gas reserves. In this study,eight shale core samples from the Mouye-1 well were measured using a homemade patented gas desorption apparatus to determine their gas contents. Due to the air contamination that is introduced into the desorption canister, a mathematical method was devised to correct the gas quantity and quality.Compared to the chemical compositions of desorbed gas, the chemical compositions of residual gas are somewhat different. In residual gas, carbon dioxide and nitrogen record a slight increase, and propane is first observed. This phenomenon may be related to the exposure time during the transportation of shale samples from the drilling site to the laboratory, as well as the differences in the mass, size and adsorptivity of different gas molecules. In addition to a series of conventional methods, including the USBM direct method and the Amoco Curve Fit(ACF) method, which were used here for lost gas content estimation, a Modified Curve Fit(MCF) method, based on the 'bidisperse' diffusion model, was established to estimate lost gas content. By fitting the ACF and MCF models to gas desorption data, we determined that the MCF method could reasonably describe the gas desorption data over the entire time period, whereas the ACF method failed. The failure of the ACF method to describe the gas desorption process may be related to its restrictive assumption of a single pore size within shale samples. In comparison to the indirect method, this study demonstrates that none of the three methods studied in this investigation(USBM, ACF and MCF) could individually estimate the lost gas contents of all shale samples and that the proportion of free gas relative to total gas has a significant effect on the estimation accuracy of the selected method. When the ratio of free gas to total gas is lower than 45%, the USBM method is the best for estimating the lost gas content, whereas when the ratio ranges from 45% to 75% or is more than 75%, the ACF and MCF methods, are the best options respectively.     

Mechanical behavior and micro-structure of cement kiln dust-stabilized expensive soil

In this study, the effects of cement kiln dust (CKD) on the swelling properties, strength properties, and microstructures of CKD-stabilized expansive soil were investigated. Samples were prepared and stabilized with different CKD content ratios, ranging from 0 to 18% by dry mass. The results obtained show that the maximum swelling pressures decrease exponentially with increases in CKD content. Both the cohesion and unconfined compressive strength (UCS) increase at ratios below 10% CKD and then decrease slightly, above that ratio. CKD can also improve the strength of saturated, expansive soil. There is no visible change of UCS for soil without CKD when cured, while the UCS of a sample with 10% CKD content after curing for 90 days is higher than that after curing for only 1 day. This indicates that CKD can improve the long-term strength of expansive soil. Finally, microstructure analysis reveals that the addition of CKD reduces the montmorillonite content of expansive soil and decreases its swelling properties. The addition of CKD also changes the pore volume distribution, both the size and amount of macro-pores and micro-pores decrease with increase in CKD content. For saturated samples, the size of macro-pores is obviously reduced, while that of micro-pores is slightly increased for both treated and untreated soils. Hydration and saturation processes make the soil structure become dispersive which results in a lower strength, and adding CKD can restrain this process. The suggested optimal CKD content is between 10 and 14% and with a curing time of more than 27 days.     

Geochemistry of organic matter and elements of black shale during weathering in Northern Guizhou,Southwestern China: Their mobilization and inter-connection

Different from previous studies on effect of weathering upon geochemical variation along a single weathered profile, this paper provides a new methodology validated by comparing a weathered outcrop samples and their stratigraphic counterpart un-weathered core samples in a nearby shallow borehole. This outcrop and borehole penetrated the Ordovician-Silurian Wufeng–Longmaxi shales, located in the same anticline structure in the northern part of Guizhou Province, Southern China. The mineral composition, major, trace and rare earth elements (REEs) composition and Rock-Eval parameters of outcrop and core samples were analyzed and compared. Organic matter (OM) was observed in the microscope and extracted for elements analysis. The results show that short-term weathering still has significant influence on OM, mineral and elemental composition of black shales. The elements composition shows the outcrop profile was moderately weathered. The REEs compositions do not alter much during weathering process and the REEs composition and their relative ratios still are valid for rock origin determination. The OM, mainly composed by graptolite and bitumen, even entering the highly-over thermal maturity, is still sensitive to the weathering with a systematic loss 30–50% of TOC along the outcrop profile, which suggests that the OM consumption is predominantly controlled by weathering duration and the distance from the weathering surface. In turn, OM has significant influence on the trace elements transportation behavior during weathering. Some trace elements associated with the OM such as V, Cr, Th, U, Ni and Co, change significantly in their absolute concentration during weathering, but their relative ratios do not necessarily change too much and might be still reliable proxies for paleo-environmental determination. The mobility of shale minerals during weathering is in the following order: plagioclase?>?potassium feldspar and dolomite >pyrite and OM. Short-term weathering can also result in considerable transportation of elements and significant variation of minerals content in black shale, which may pose potentially high environmental and engineering risk in the regions rich in black shale.