中国红土的研究与地基承载力的评价

通过广泛的工作，着重研究了不同成因类型红土的物质组成和结构特征，决定红土工程地质性质的主要因素是游离氧化铁、由于不同种类、不同形态游离氧化物的大量存在使红土在高含水率和高孔隙比情况下具有较高的强度，因此红土的地基承载力标准值不能与一般粘性土等同时待，还介绍了如何提高地基承载和和确定标准值的方法。     

微型活性碳柱富集比色法测定金

本文探讨了用微型活性碳柱富集痕量金的方法。研究了富集金和TMK—Au—Twee 85显色反应的条件,用本法测定了地质试样中痕量金,其测定限为2 ppbAu,本法操作简便、快速,灵敏度高,结果较为满意。     

Petrogenesis of the Early Cretaceous Laojunshan monzogranite at the southern margin of the North China Craton: Constrains on the transition of the tectonic regime

<正>1 Introduction Voluminous Mesozoic magmatic rocks containing abundant Au-Mo polymetallic mineralization resources are developed in the Xiaoqinling-Xiong’ershan district of the southern margin of the North China Craton(NCC).     

西藏改则洞错地区白垩纪火山岩锆石U-Pb年代学、Hf同位素组成及对班公-怒江洋俯冲闭合的制约

班公湖—怒江缝合带是青藏高原内一条重要的缝合带,其俯冲极性和闭合时限一直存在着争议,这无疑限制了我们对青藏高原演化历史的认识。本文对仲岗安山玄武岩和一套新发现的晚白垩世安山岩进行研究,获得了其锆石U-Pb年龄分别为123.75±0.92 Ma和74.23±0.76 Ma。仲岗安山玄武岩锆石的ε_(Hf)(t)值为-7.3~+4.4,具有岛弧玄武岩特征,指示班公湖—怒江洋盆在该地区仍然继续向北俯冲;晚白垩世安山岩锆石的ε_(Hf)(t)值为+3.1~+11.1,其可能是亏损地幔混熔了部分的陆壳物质而形成的,且不整合在蛇绿岩之上。结合区域资料本文认为班公湖—怒江洋盆在改则地区的闭合时限在100~75 Ma之间。     

Petrography and Geochemistry of Peridotite Xenoliths from Hannuoba and Significance for Lithospheric Mantle Evolution

Mantle-derived xenoliths and xenocrysts in Pale-ozoic diamondiferous ki mberlites in Mengyin (Shan-dong Province) and Fuxian (Liaoning Province) showthe presence of a cold,thick lithospheric mantle be-neath the North China craton ( NCC) in the MiddleOrdovician ( Griffin et al ., 1998 ; Menzies et al .,1993 ;Fan and Menzies ,1992) . However ,studies onmantle peridotites captured in the Tertiary to Neo-gene basalts of the NCC have revealed the existenceof a thin, hot and fertile lithosph…     

The formation of porphyry copper deposits

Copper is a moderately incompatible chalcophile element. Its behavior is strongly controlled by sulfides. The speciation of sulfur is controlled by oxygen fugacity. Therefore, porphyry Cu deposits are usually oxidized (with oxygen fugacities > ΔFMQ +2) (Mungall 2002; Sun et al. 2015). The problem is that while most of the magmas at convergent margins are highly oxidized, porphyry Cu deposits are very rare, suggesting that high oxygen fugacity alone is not sufficient. Partial melting of mantle peridotite even at very high oxygen fugacities forms arc magmas with initial Cu contents too low to form porphyry Cu deposits directly (Lee et al. 2012; Wilkinson 2013). Here we show that partial melting of subducted young oceanic slabs at high oxygen fugacity (>ΔFMQ +2) may form magmas with initial Cu contents up to >500 ppm, favorable for porphyry mineralization. Pre-enrichment of Cu through sulfide saturation and accumulation is not necessarily beneficial to porphyry Cu mineralization. In contrast, re-melting of porphyritic hydrothermal sulfide associated with iron oxides may have major contributions to porphyry deposits. Thick overriding continental crust reduces the “leakage” of hydrothermal fluids, thereby promoting porphyry mineralization. Nevertheless, it is also more difficult for ore forming fluids to penetrate the thick continental crust to reach the depths of 2–4 km where porphyry deposits form.     

铝硅酸盐矿物和玻璃中Al的配位与局部结构

利用同步辐射的AlK边X射线吸收近进结构（XANES）谱研究了刚玉和铝硅酸盐矿物（蓝晶石,红柱石,夕线石和钠长石）中Al的配位与局部结构,证明该方法可以作为新的结构探针研究结构未知体系中Al的配位与局部结构。例如,Al的K边XANES谱证明在室温压条件,钠长石玻璃中的Al保持为四面体配位（AlIV）,局部结构与钠长石晶体中的Al相似;尽管硬玉晶体中的Al为八面体配位,但硬玉玻璃中的Al变为四面体配位（AlIV）。而在相同的高温压条件（4．4GPa,1575C）下制备的硬玉-钠长石玻璃系列中,压力引起四面体配位的Al变成五次（Alv）和六次配位（AlVl）,且五次和六次配位Al的比例随玻璃中硬玉含量的增加而增大。     

碧口岩群硅质岩成因及地质意义

碧口块状硫化物矿床直接赋矿主岩硅质岩地质特征及常量、微量、稀土元素组成表明,碧口岩群硅质岩为同火山岩喷流热水沉积成因。碧口岩群硅质岩常量元素富Fe、贫Si,为典型热水沉积成因;其微量元素、稀土元素特征均与现代大洋热水沉积物相似。热水硅质岩Eu异常与古流体温度存在密切关系,Eu／Eu特征显示筏子坝、铜矿坡为较高温度喷流产物,而大茅坪、黑窝子、铜矿梁、周家坡则为较低温度下的产物。     

辉南新生代玄武岩中捕虏体橄榄岩矿物化学与华北岩石圈地幔演化

内容提要：在对吉林辉南新生代玄武岩中捕虏体橄榄岩详细的岩相学和矿物主量元素研究基础上,重点分析了单斜辉石激光原位微量元素,并讨论了辉南陆下岩石圈地幔的性质及其在华北克拉通破坏过程中的意义。橄榄石、单斜辉石和尖晶石的Mg#和Cr#均表明该区陆下岩石圈地幔主体是饱满的,同时也存在少量过渡和难熔型地幔。单斜辉石REE配分形式包括LREE亏损、倒U字型REE和LREE富集等不同类型。这些橄榄岩是地幔经历不同程度的部分熔融作用(低于10%)和复杂地幔交代作用的产物。交代介质主体是硅酸盐熔体,但个别样品有碳酸岩熔体交代的残留。橄榄石Mg#和平衡温度无相关性,说明辉南陆下岩石圈地幔不存在明显的分层而是交叉的。这些地幔特征和华北东部其他地区新生代的主体地幔性质相似,是熔-岩反应、侵蚀作用和上涌软流圈物质冷却转变置换的综合结果。     

粉末冶金在探矿工程中的应用

介绍了粉末冶金技术及产品在探矿工程中的应用,回顾了硬质合金钻进的历史;讨论了粉末冶金技术在金刚石钻头制造中的应用,尤其是近几年的进展,综述了钎头用硬质合材料新发展－梯度硬质合金和铁镍代钴硬质合金。