Rhenium in rivers and estuaries of India: Sources,transport and behaviour

The concentration of dissolved and particulate Re have been measured in the Narmada, Tapi and the Mandovi estuaries in the Arabian Sea and the Hooghly estuary in the Bay of Bengal. Re concentration in water and particulate matter of these estuaries is highly variable. Re in river waters analysed varies from 1 to 41 pmol/kg, the lowest in the Mandovi and the highest in the Mahi river. Re concentrations in the rivers analysed except in the Mandovi river are higher than the average global riverine Re concentration of 2.1 pmol/kg. Based on this study and the available data, the contemporary global annual flux of dissolved riverine Re is estimated to be ~ 350 × 10³ mol with an average concentration of ~ 9.2 pmol/kg, much higher than the earlier estimates. Residence time of Re in the oceans based on this estimate is 175,000 years, ~ 4 times lower compared to earlier estimates. Re behaves conservatively in all the estuaries studied. Re concentrations of seawater in the Bay of Bengal and in the Arabian Sea, estimated from the data of the Hooghly and the Mandovi estuaries respectively are ~ 40 pmol/kg, similar to the open ocean Re values of the Arabian Sea measured in this study and the values reported for in other oceanic regions. However, the dissolved Re in the Gulf of Cambay is 2 to 5 times higher, consistent with the high Re measured in the Mahi estuary and in the coastal waters of the Gulf of Cambay. The source of high Re in the Gulf of Cambay seems to be anthropogenic, measurements of Re in rivers and industrial waste waters draining into the Gulf supply amount to ~ 2300 mol of Re annually. This anthropogenic supply coupled with high residence time of water in the Gulf contribute to its high Re. Re concentration in suspended sediments of the Narmada estuary varies from 1 to 2 pmol/g, and does not show any discernible trend with salinity.The contemporary global riverine Re supply to the oceans estimated in this study is ~ 2–4 times higher compared to its removal in the reducing (anoxic/suboxic) sediments, indicating non-steady state of Re in the ocean. High dissolved riverine Re flux coupled with high Re content in the Gulf of Cambay highlights the need of a detailed study of Re in the various global rivers and in oceans including coastal regions and semi enclosed basins of the world to understand its behaviour in various reservoirs and to constrain the residence time of Re in the ocean.     

A global assessment of the impact of climate change on water scarcity

This paper presents a global scale assessment of the impact of climate change on water scarcity. Patterns of climate change from 21 Global Climate Models (GCMs) under four SRES scenarios are applied to a global hydrological model to estimate water resources across 1339 watersheds. The Water Crowding Index (WCI) and the Water Stress Index (WSI) are used to calculate exposure to increases and decreases in global water scarcity due to climate change. 1.6 (WCI) and 2.4 (WSI) billion people are estimated to be currently living within watersheds exposed to water scarcity. Using the WCI, by 2050 under the A1B scenario, 0.5 to 3.1 billion people are exposed to an increase in water scarcity due to climate change (range across 21 GCMs). This represents a higher upper-estimate than previous assessments because scenarios are constructed from a wider range of GCMs. A substantial proportion of the uncertainty in the global-scale effect of climate change on water scarcity is due to uncertainty in the estimates for South Asia and East Asia. Sensitivity to the WCI and WSI thresholds that define water scarcity can be comparable to the sensitivity to climate change pattern. More of the world will see an increase in exposure to water scarcity than a decrease due to climate change but this is not consistent across all climate change patterns. Additionally, investigation of the effects of a set of prescribed global mean temperature change scenarios show rapid increases in water scarcity due to climate change across many regions of the globe, up to 2 °C, followed by stabilisation to 4 °C.     

Assessment of groundwater potential zone using remote sensing,GIS and multi criteria decision analysis techniques

The sustainable development and management of groundwater resource needs quantitative assessment, based on scientific principle and recent techniques. In the present study, groundwater potential zone is being determined using remote sensing, Geographical Information System (GIS) and Multi-Criteria Decision Analysis (MCDA) techniques using various thematic layers viz. geomorphology, geology, drainage density, slope, rainfall, soil texture, groundwater depth, soil depth, lineament and land use/ land cover. The Analytic Hierarchy Approach (AHP) is used to determine the weights of various themes for identifying the groundwater potential zone based on weights assignment and normalization with respect to the relative contribution of the different themes to groundwater occurrence. Finally, obtained groundwater potential zones were classified into five categories, viz. low, medium, medium-high, high and very high potential zone. The result depicts the groundwater potential zone in the study area and found to be helpful in better development and management planning of groundwater resource.     

Stratigraphy and correlation of Mesoproterozoic rocks associated with Mohar cauldron,Shivpuri district,Madhya Pradesh

A circular structure, termed as cauldron of volcanic origin, was located near Mohar village in Shivpuri district (M.P.) in the year 2000. Subsequently, the same structure was called as Dhala structure of impact origin. There may be debate over the origin and evolution of this circular structure, but it is characterized by a unique lithological set-up within the Bundelkhand craton. The circular structure is defined by annular disposition of igneous and sedimentary rocks. This includes a set of felsic volcanic rocks and associated breccias named as Mohar Formation, exposed in the outer rim of the circular structure. The inner part of the circular structure has sedimentary sequence, termed as Dhala Formation.The field relations indicate that the Mohar and Dhala foarmations are younger than Bundelkhand granitoid complex but older than Kaimur Group. This period in Indian stratigraphy corresponds to Semri Group which consists of Porcellanite Formation, the rocks of which have formed due to deposition of volcanic ash.The geochronological data and field relations between different litho-units indicate that the Mohar volcanism which generated large volume of volcanic ash was a possible source for the formation of Porcellanite Formation. The deposition of sedimentary sequence in main Vindhyan basin was continued, whereas the volcanic activity in Mohar area continued till H ≈ 1.0 Ga. Since, acid volcanic activity has been reported in different parts of the world at H ≈ 1.0 Ga., it is possible that the Mohar acid volcanic activity is not an isolated event; instead it may be a part of global volcanic activities around H ≈ 1.0 Ga.     

Dump slope stability analysis – A case study

In opencast mining operation, the stability of waste materials stands at high priority from the safety and economic perspective. Poor management of overburden (OB) dump results the instability of slope in an opencast mine. The present paper deals with the stability analysis of dump material of an opencast coal mine at Talcher coal field, Angul district, Odisha, by means of different geotechnical parameters and mineralogical composition affecting the dump slope. The prolonged rainfall in the mining area causes dump failure and loss of valuable life and property. A recent dump failure that occurred in 2013 at Basundhara mines of Mahanadi Coalfields Limited (MCL), Odisha, took 14 lives, and created problems for the mining industry. Most of the dump failure that occurs in the study area are mainly due to increase in pore water pressure as a result of rainfall infiltration. The stability of the waste dump was investigated using the limit equilibrium analysis to suggest an economical, sustainable and safe disposal of the dump in the study area.     

Dynamicity of the Himalayan landslide — A tectono-geotechnical appraisal of the 13<Superscript>th</Superscript> mile landslide,Sikkim

Understanding the causes of slope development with movement initiation of land sliding requires knowledge on dynamicity, displacement, strain concentration and factor of safety. The 13^th mile landslide on Gangtok-Nathula road of the Sikkim Himalaya has seriously affected the Indo-China trade route. To quantify the spatial movement pattern, strain analysis and identification of zones of safety were attempted which indicates that differential movement activity of the landslide zone is co-relatable with differential strain pattern with an overall imprint of the Himalaya collision tectonics.     

Shallow lithosphere-asthenosphere boundary beneath Cambay Rift Zone of India: Inferred presence of carbonated partial melt

A vast area between Phalodi in Jodhpur and Pokaran in Jaisalmer district of western Rajasthan, is occupied distinctly by rocky, shallow gravelly surfaces and occasional hills. These surfaces exhibit quartz and quartzite pebbles, angular, sub-angular and few rounded sandstone gravels, have slightly convex outline and can be best described as desert pavements. Such land features assume significance because of their extent and variability under a dominantly dry aeolian environment. Morphology and distributional pattern of such formations indicate that sediments are either of in situ origin or may have been transported to a short distance. The present study is based on field level assessment of such surfaces in the above two desert districts. Over much of the area, the profile shows a surficial concentration of gravels followed by thick sand and silt mixed with gravels and then the parent material. There are also occasional rock outcrops of very low relief exhibiting vertical, horizontal and conchoidal pattern of fractures over these surfaces near Pokaran and north of Jaisalmer which indicate disintegration of rocks under extreme diurnal fluctuation of temperature. Such manifestations in the morphology indicate impact of both thermal as well as aeolian processes. In the east of Jaisalmer town near Basanpir and Bhojka, the pavement surfaces are found covered with abundant sub-rounded to rounded pebbles and cobbles. This type of condition would indicate a profound action by fluvial activities followed by wind sorting. Our study found significant spatial variability in the distribution of pavement surfaces, which carried imprints of climatic fluctuations and environment of deposition during Holocene.     

Discrimination of explosions and earthquakes: An example based on spectra and source parameters of the 11<Superscript>th</Superscript> May 1998 Pokhran explosion and the 9<Superscript>th</Superscript> April 2009 earthquake

We compare the P-, S- and Lg- spectra of the 11^th May, 1998 Pokhran underground nuclear explosion (NE) with those of an earthquake (EQ) of comparable magnitude that occurred in its vicinity (~100 km west) on 9^th April, 2009, utilizing the waveforms recorded by a Global Seismograph Network station at Nilore (NIL), Pakistan. The contiguous occurrence of these events and the similarity of the travel paths provided a good opportunity to discriminate the nature of the sources. Our results suggest that the Pn/Lg and Pn/Sn amplitude ratios of the explosion and earthquake waveforms exhibit distinct differences in the higher frequency window. Further, since the P-phases have high signal to noise ratio compared to their S counterparts, we utilize their spectra to derive the source parameters of the NE and EQ sources. Our results show that the seismic moment, corner frequency and source dimension of the explosion are ~1.58X10¹⁷ Nm, 1.18 Hz and ~0.793 km respectively. The moment magnitude (M_W) and surface wave magnitude (M_S) for the nuclear explosion are estimated to be ~5.4 and ~3.57 respectively. The values of M_W (5.3) and M_S (4.3) obtained by us for the earthquake are consistent with the estimates in the Harvard catalog and earlier published results. The estimate of M_W for the nuclear explosion was hitherto not available. Lastly, we estimate the yield of the NE to be ~50 kt from the surface wave magnitude and discuss the various limitations related to its estimation.