Analysis of the non-linearity in the pattern and time evolution of El Niño southern oscillation

In this study the observed non-linearity in the spatial pattern and time evolution of El Niño Southern Oscillation (ENSO) events is analyzed. It is shown that ENSO skewness is not only a characteristic of the amplitude of events (El Niños being stronger than La Niñas) but also of the spatial pattern and time evolution. It is demonstrated that these non-linearities can be related to the non-linear response of the zonal winds to sea surface temperature (SST) anomalies. It is shown in observations as well as in coupled model simulations that significant differences in the spatial pattern between positive (El Niño) versus negative (La Niña) and strong versus weak events exist, which is mostly describing the difference between central and east Pacific events. Central Pacific events tend to be weak El Niño or strong La Niña events. In turn east Pacific events tend to be strong El Niño or weak La Niña events. A rotation of the two leading empirical orthogonal function modes illustrates that for both El Niño and La Niña extreme events are more likely than expected from a normal distribution. The Bjerknes feedbacks and time evolution of strong ENSO events in observations as well as in coupled model simulations also show strong asymmetries, with strong El Niños being forced more strongly by zonal wind than by thermocline depth anomalies and are followed by La Niña events. In turn strong La Niña events are preceded by El Niño events and are more strongly forced by thermocline depth anomalies than by wind anomalies. Further, the zonal wind response to sea surface temperature anomalies during strong El Niño events is stronger and shifted to the east relative to strong La Niña events, supporting the eastward shifted El Niño pattern and the asymmetric time evolution. Based on the simplified hybrid coupled RECHOZ model of ENSO it can be shown that the non-linear zonal wind response to SST anomalies causes the asymmetric forcings of ENSO events. This also implies that strong El Niños are mostly wind driven and less predictable and strong La Niñas are mostly thermocline depth driven and better predictable, which is demonstrated by a set of 100 perfect model forecast ensembles.     

Distribution of phosphine in the offshore area of the Southwest Yellow Sea,East Asia

Phosphine is a natural gaseous compound in the phosphorus biogeochemical cycle. This paper studies the spatial and temporal distributions of matrix-bound phosphine (MBP) and gaseous phosphine in the offshore area of the Southwest Yellow Sea, East Asia. The results show that MBP concentrations in marine surface sediments range from 0.69 ± 0.06 ng/kg (dry) to 179 ± 29 ng/kg (dry). Higher seasonal MBP concentrations in sediments are found in fall than in spring or winter in most sites. High MBP contents are observed in two fish-breeding areas. MBP concentrations decrease with distance to the coast, except in the southeast of the sampling area. MBP levels in marine sediments are found to be higher than those at several other places: freshwater sediments and soil, except eutrophic lakes. Gaseous phosphine contents in fall range from 0.14 ± 0.00 ng/m³ to 9.83 ± 0.97 ng/m³. No correlation is observed between MBP and gaseous phosphine.     

Observations of comet impact by reflections from the Galilean satellites

Results of observations of the Galilean satellites during the week of the impact of comet Shoemaker-Levy 9 on Jupiter are reported. These observations have been carried out at the Pico dos Dias observatory, at Brasópolis, Brazil. The satellites's light flux was monitored with a photometer during the time of the predicted impact of fragments B, F, J and L. No conclusive flash was observed in any of the data adquired. This non-detection imposes an upper limit to the energy released during the impact of these fragments.Observations carried out at the Observatório do Pico dos Dias, operated by the Laboratório Nacional de Astrofísica/CNPq/MCT, Brazil     

Prätektonisches Sulfiderz aus dem Pinzgauer Phyllit westlich Mitterberg (Salzburg)

The country rocks occurring with the copper ore-deposit at Mitterberg/Austria have been divided into two different units: the Violet Series and the underlying Pinzgau Phyllite Zone. The epigenetic character of the ore within the Violet Series has been confirmed. Within the Pinzgau Phyllite Zone a stratabound ore band, which occurs about 4 km west of Mitterberg, has been described. The primary nature of this ore band, together with the observations of relict fabrics from Mitterberg itself, support the author's explanation that the vein-type deposits in the Violet Series are a result of a partial remobilisation.     

Walker circulation controls ENSO atmospheric feedbacks in uncoupled and coupled climate model simulations

Many climate models strongly underestimate the two most important atmospheric feedbacks operating in El Niño/Southern Oscillation (ENSO), the positive (amplifying) zonal surface wind feedback and negative (damping) surface-heat flux feedback (hereafter ENSO atmospheric feedbacks, EAF). This hampers a realistic representation of ENSO dynamics in these models. Here we show that the atmospheric components of climate models participating in the 5th phase of the Coupled Model Intercomparison Project (CMIP5) when forced by observed sea surface temperatures (SST), already underestimate EAF on average by 23%, but less than their coupled counterparts (on average by 54%). There is a pronounced tendency of atmosphere models to simulate stronger EAF, when they exhibit a stronger mean deep convection and enhanced cloud cover over the western equatorial Pacific (WEP), indicative of a stronger rising branch of the Pacific Walker Circulation (PWC). Further, differences in the mean deep convection over the WEP between the coupled and uncoupled models explain a large part of the differences in EAF, with the deep convection in the coupled models strongly depending on the equatorial Pacific SST bias. Experiments with a single atmosphere model support the relation between the equatorial Pacific atmospheric mean state, the SST bias and the EAF. An implemented cold SST bias in the observed SST forcing weakens deep convection and reduces cloud cover in the rising branch of the PWC, causing weaker EAF. A warm SST bias has the opposite effect. Our results elucidate how biases in the mean state of the PWC and equatorial SST hamper a realistic simulation of the EAF.     

A new magnetostratigraphic framework for the Lower Miocene (Burdigalian/Ottnangian, Karpatian) in the North Alpine Foreland Basin

Oligocene–Miocene chronostratigraphic correlations within the Paratethys domain are still highly controversial. This study focuses on the late Early Miocene of the Swiss and S-German Molasse Basin (Late Burdigalian, Ottnangian–Karpatian). Previous studies have published different chronologies for this time interval that is represented by the biostratigraphically well constrained Upper Marine Molasse (OMM, lower and middle Ottnangian), Upper Brackish Molasse (OBM, Grimmelfingen and Kirchberg Formations, middle and upper Ottnangian to lower Karpatian, MN 4a–MN 4b) and Upper Freshwater Molasse (OSM, Karpatian–Badenian, MN 5). Here, we suggest a new chronostratigraphic framework, based on integrated magneto-litho-biostratigraphic studies on four sections and three boreholes. Our data indicate that the OBM comprises chrons 5D.1r and 5Dn (Grimmelfingen Fm), chron 5Cr (lower Kirchberg Fm) and the oldest part of chron 5Cn.3n (upper Kirchberg Fm). The OSM begins during chron 5Cn.3n, continues through 5Cn, and includes a long reversed segment that can be correlated to chron 5Br. The OMM-OSM transition was completed at 16.0 Ma in the Swiss Molasse Basin, while the OBM-OSM changeover ended at 16.6 Ma in the S-German Molasse Basin. As the lower Kirchberg Fm represents a facies of the Ottnangian, our data suggest that the Ottnangian–Karpatian boundary in the Molasse Basin is approximately at 16.8 Ma, close to the 5Cr–5Cn.3n magnetic reversal, and thus 0.4 Myr younger than the inferred age of 17.2 Ma used in recent Paratethys time scales. Notably, this would not be problematic for the Paratethys stratigraphy, because chron 5Cr is mainly represented by a sedimentation gap in the Central Paratethys. We also realise, however, that additional data is still required to definitely solve the age debate concerning this intriguing time interval in the North Alpine Foreland Basin. We dedicate this work to our dear friend and colleague Jean-Pierre Berger (8 July 1956–18 January 2012).     

Comparing the spatial structure of variability in two datasets against each other on the basis of EOF-modes

In analysis of climate variability or change it is often of interest how the spatial structure in modes of variability in two datasets differ from each other, e.g. between past and future climate or between models and observations. Often such analysis is based on Empirical Orthogonal Function (EOF) analysis or other simple indices of large-scale spatial structures. The present analysis lays out a concept on how two datasets of multivariate climate variability can be compared against each other on basis of EOF analysis and how the differences in the multivariate spatial structure between the two datasets can be quantified in terms of explained variance in the leading spatial patterns. It is also illustrated how the patterns of largest differences between the two datasets can be defined and interpreted. We illustrate this method on the basis of several well-defined artificial examples and by comparing our approach with examples of climate change studies from the literature. These literature examples include analysis of changes in the modes of variability under climate change for the sea level pressure (SLP) of the North Atlantic and Europe, the SLP of the Southern Hemisphere, the surface temperature of the Northern Hemisphere, the sea surface temperature of the North Pacific and for precipitation in the tropical Indo-Pacific.     

The May 1985 superoutburst of OY Carinae: I. Structure of the outer disk from optical and IR observations

We present optical and IR observations of the dwarf nova OY Car during the May 1985 superoutburst. From them we find that the superhump has a temperature of 8000K and an area of order half the size of the red dwarf or accretion disk. We also compare the behaviour during two simultaneous optical/IR observations. Whilst the light curves in the two pass bands are similar during one observation, in the other observation they show marked differences that may be due to a cool region in the outer disk.Paper presented at the IAU Colloquium No. 93 on Cataclysmic Variables. Recent Multi-Frequency Observations and Theoretical Developments, held at Dr. Remeis-Sternwarte Bamberg, F.R.G., 16–19 June, 1986.     

Depth to basement and geoid expression of the Kane Fracture Zone: A comparison

Geoid data from Geosat and subsatellite basement depth profiles of the Kane Fracture Zone in the central North Atlantic were used to examine the correlation between the short-wavelength geoid (=25–100 km) and the uncompensated basement topography. The processing technique we apply allows the stacking of geoid profiles, although each repeat cycle has an unknown long-wavelength bias. We first formed the derivative of individual profiles, stacked up to 22 repeat cycles, and then integrated the average-slope profile to reconstruct the geoid height. The stacked, filtered geoid profiles have a noise level of about 7 mm in geoid height. The subsatellite basement topography was obtained from a recent compilation of structure contours on basement along the entire length of the Kane Fracture Zone. The ratio of geoid height to topography over the Kane Fracture Zone valley decreases from about 20–25 cm km^-1 over young ocean crust to 5–0 cm km^-1 over ocean crust older than 140 Ma. Both geoid and basement depth of profiles were projected perpendicular to the Kane Fracture Zone, resampled at equal intervals and then cross correlated. The cross correlation shows that the short-wavelength geoid height is well correlated with the basement topography. For 33 of the 37 examined pro-files, the horizontal mismatches are 10 km or less with an average mismatch of about 5 km. This correlation is quite good considering that the average width of the Kane Fracture Zone valley at median depth is 10–15 km. The remaining four profiles either cross the transverse ridge just east of the active Kane transform zone or overlie old crust of the M-anomaly sequence. The mismatch over the transverse ridge probably is related to a crustal density anomaly. The relatively poor correlation of geoid and basement depth in profiles of ocean crust older than 130–140 Ma reflects poor basement-depth control along subsatellite tracks.     

Marble-hosted ruby deposits from Central and Southeast Asia: Towards a new genetic model

Marble-hosted ruby deposits represent the most important source of colored gemstones from Central and South East Asia. These deposits are located in the Himalayan mountain belt which developed during Tertiary collision of the Indian plate northward into the Eurasian plate. They are spatially related to granitoid intrusions and are contained in platform carbonates series that underwent high-grade metamorphism. All occurrences are located close to major tectonic features formed during Himalayan orogenesis, directly in suture zones in the Himalayas, or in shear zones that guided extrusion of the Indochina block after the collision in South East Asia. Ar–Ar dating of micas syngenetic with ruby and U–Pb dating of zircon included in ruby gives evidence that these deposits formed during Himalayan orogenesis, and the ages document the extensional tectonics that were active, from Afghanistan to Vietnam, between the Oligocene and the Pliocene.The petrography shows that ruby-bearing marbles formed in the amphibolite facies (T = 610 to 790 °C and P ~ 6 kbar). A fluid inclusion study defines the conditions of gem ruby formation during the retrograde metamorphic path (620 < T < 670 °C and 2.6 < P < 3.3 kbar) for the deposits of Jegdalek, Hunza and northern Vietnam.Whole rock analyses of non-ruby-bearing marbles indicate that they contain enough aluminum and chromiferous elements to produce all the ruby crystals that they contain. In addition, (C, O)-isotopic analyses of carbonates from the marbles lead to the conclusion that the marbles acted as a metamorphic closed fluid system that were not infiltrated by externally-derived fluids. The carbon isotopic composition of graphite in marbles reveals that it is of organic origin and that it exchanged C-isotopes with the carbonates during metamorphism. Moreover, the O-isotopic composition of ruby was buffered by metamorphic CO₂ released during devolatilisation of marble and the H-isotopic composition of mica is consistent with a metamorphic origin for water in equilibrium with the micas. The (C, O, H)-isotopic compositions of minerals associated with marble-hosted ruby are all in agreement with the hypothesis, drawn from the unusual chemistry of CO₂–H₂S–COS–S₈–AlO(OH)-bearing fluids contained in fluid inclusions, that gem ruby formed at P ~ 3 kbar and 620 < T < 670 °C, during thermal reduction of evaporite by organic matter, at high temperature-medium pressure metamorphism of platform carbonates during the Tertiary India–Asia collision. The carbonates were enriched in Al- and chromiferous-bearing detrital minerals, such as clay minerals that were deposited on the platform with the carbonates, and in organic matter. Ruby formed during the retrograde metamorphic path, mainly by destabilization of muscovite or spinel. The metamorphic fluid system was rich in CO₂ released from devolatilisation of carbonates, and in fluorine, chlorine and boron released by molten salts (NaCl, KCl, CaSO₄). Evaporites are key to explaining the formation of these deposits. Molten salts mobilized in situ Al and metal transition elements contained in marbles, leading to crystallization of ruby.