New Olivine Reference Material for In Situ Microanalysis

A new olivine reference material – MongOL Sh11‐2 – for in situ analysis has been prepared from the central portion of a large (20 × 20 × 10 cm) mantle peridotite xenolith from a ~ 0.5 My old basaltic breccia at Shavaryn‐Tsaram, Tariat region, central Mongolia. The xenolith is a fertile mantle lherzolite with minimal signs of alteration. Approximately 10 g of 0.5–2 mm gem quality olivine fragments were separated under binocular microscope and analysed by EPMA, LA‐ICP‐MS, SIMS and bulk analytical methods (ID‐ICP‐MS for Mg and Fe, XRF, ICP‐MS) for major, minor and trace elements at six institutions world‐wide. The results show that the olivine fragments are sufficiently homogeneous with respect to major (Mg, Fe, Si), minor and trace elements. Significant inhomogeneity was revealed only for phosphorus (homogeneity index of 12.4), whereas Li, Na, Al, Sc, Ti and Cr show minor inhomogeneity (homogeneity index of 1–2). The presence of some mineral and fluid‐melt micro‐inclusions may be responsible for the inconsistency in mass fractions obtained by in situ and bulk analytical methods for Al, Cu, Sr, Zr, Ga, Dy and Ho. Here we report reference and information values for twenty‐seven major, minor and trace elements.     

Interaction of waves,currents and tides,and wave-energy impact on the beach area of Sylt Island

Erosion due to waves is an important and actual problem for most coastal areas of the North Sea. The objective of this study was to estimate the impact of wave action on the coastline of Sylt Island. From a 2-year time series (November 1999 to October 2001) of hydrological and wave parameters generated with a coupled wave–current modelling system, a period comprising storm ‘Anatol’ (3–4 December 1999) is used to investigate the effects of waves on currents and water levels and the input of wave energy into the coastline. The wave-induced stress causes an increase of the current velocity of 1 m/s over sand and an additional drift along the coast of about 20 cm/s. This produces a water level increase of more than 20 cm in parts of the tidal basin. The model system also calculates the wave energy input into the coastline. Scenario runs for December 1999 with a water level increase of 50 cm and wind velocity increased by 10% show that the input of the wave energy into the west coast of Sylt Island increases by 30% compared to present conditions. With regard to the forecasted near-future (Woth et al., Ocean Dyn 56:3–15, 2006) increase of strong storm surges, the scenario results indicate an increased risk of coastal erosion in the surf zone of Sylt Island.     

Tools and cover effects in bedload transport observations in the Pitzbach,Austria

We report bedload data and acoustic impulse measurements due to particle impact from the Pitzbach in Austria. Impulse counts can be viewed as a measure of the energy delivered to the bed by moving particles. Impulse counts show a large scatter even for the same discharge and bedload supply. This scatter is due to varying grain size distribution, grain shape, mode of transport of the sediment particles and spatial and temporal distribution of the sediment load. The mean impulse count at given hydraulic conditions may increase or decrease with increasing sediment supply, suggesting that both tools and cover effects are active on the channel bed. Dependent on the local balance between sediment supply and transport capacity, either effect may be dominant at different locations along the cross‐section at the same time. Furthermore, the same bed location may respond to increasing sediment supply as tools‐dominated at some discharges and cover‐dominated at other discharges. Our observations may have implications for modelling of bedrock erosion in landscape evolution models and of bedrock channel morphology. Erosion models that do not incorporate both tools and cover effects are not sufficient to describe observations. Furthermore, a local erosion law cannot in general be used to describe erosion averaged over the channel cross‐section. The changing balance between sediment supply and transport capacity with increasing discharge highlights that a single representative discharge is not sufficient to capture the full erosion dynamics. Copyright © 2008 John Wiley & Sons, Ltd.     

Variations of daytime and nighttime electron temperature and heat flux in the upper ionosphere,topside ionosphere and lower plasmasphere for low and high solar activity

A database of the electron temperature (T_e) comprising of most of the available LEO satellite measurements is used for studying the solar activity variations of T_e. The T_e data are grouped for two levels of solar activity (low LSA and high HSA), five altitude ranges between 350 and 2000 km, and day and night. By fitting a theoretical expression to the T_e values we obtain variation of T_e along magnetic field lines and heat flux for LSA and HSA. We have found that T_e increases with increase in solar activity at low and mid-latitudes during nighttime at all altitudes studied. During daytime the T_e response to solar activity depends on latitude, altitude, and season. This analysis shows existence of anti-correlation between T_e and solar activity at mid-latitudes below 700 km during the equinox and winter day hours. Heat fluxes show small latitudinal dependence for daytime but substantial for nighttime.     

The great Sumatra–Andaman earthquakes — Imaging the boundary between the ruptures of the great 2004 and 2005 earthquakes

Segmentation along convergent margins controls earthquake magnitude and location, but the physical causes of segment boundaries, and their impact on earthquake rupture dynamics, are still poorly understood. One aspect of the 2004 and 2005 great Sumatra–Andaman earthquakes is their abrupt termination along a common boundary. This has led to speculation on the nature of the boundary, its origin and why it was not breached.

For the first time the boundary has been imaged and, with newly acquired marine geophysical data, we demonstrate that a ridge on the subducting Indo-Australian oceanic crust may exert a control on margin segmentation. This suggests a lower plate influence on margin structure, particularly its segmentation. The ridge is masked by the sedimentary cover in the trench. Its most likely trend is NNE–SSW. It is interpreted as a fracture zone on the subducting oceanic plate. A ramp or tear along the eastern flank of the subducting fracture zone beneath Simeulue Island may be considered as an intensification factor in terms of rupture propagation barrier.     

Determination of Trace Elements in the Quartz Reference Material UNS-SpS and in Natural Quartz Samples by ICP-MS

A procedure for the digestion and analysis of quartz samples was developed to measure trace element concentrations in natural quartz. The certified glass sand reference material UNS-SpS was chosen to assess the precision, accuracy and detection limit of the analytical method. Quartz was digested with HF/HNO₃ in a closed glassy carbon vessel and analysed by means of quadrupole ICP-MS with external calibration. Analyte concentrations of the sand UNS-SpS were compared with certified and other values from the literature. The abundances of a number of elements (Pr, Gd, Ho and Er) in the reference material are reported here for the first time. The procedure was then applied to three quartz samples from different geological settings to show that trace element data by ICP-MS can distinguish the origin of the sample.     

Significance of sediment transport processes during piedmont floods: the 2005 flood events in Switzerland

A long‐lasting rainstorm event from 20 to 22 August 2005 affected a large part of the northern Alps and Prealps in Switzerland. It resulted in elevated discharges and flooding in many headwater catchments and mountain rivers. The associated geomorphic processes included shallow landslides, deep‐seated slope instabilities, debris flows, and fluvial sediment transport. In many parts of the affected areas human activities are important, including many buildings, traffic lines and other infrastructure. In the steeper parts, geomorphic processes were mainly responsible for flow overtopping and sediment deposition both in and outside of the channel network. In the lower parts, lateral erosion and exceedance of the channel discharge capacity were the main reasons for morphologic channel modification and flooding. Sediment‐related processes contributed a lot to the overall damage. Copyright © 2015 John Wiley & Sons, Ltd.     

The youngest basic oceanic magmatism in the Alps (Late Cretaceous<Emphasis Type="Italic">;</Emphasis> Chiavenna unit,Central Alps): geochronological constraints and geodynamic significance

Cathodoluminescence-controlled radiometric dating (U–Pb SHRIMP) was carried out on zircon domains from metabasic rocks of the Chiavenna unit, a major mafic/ultramafic-bearing unit in the Central Alps. Co-magmatic zircon domains from amphibolites near Chiavenna and Prata areas yielded weighted mean ²⁰⁶Pb/²³⁸U ages at 93.0±2.0 and 93.9±1.8 Ma, respectively, interpreted as the age of crystallization of the magmatic protoliths. These ages fit well with the time of late spreading in the Valais Ocean, as suggested by previous paleogeographic reconstructions. Inherited zircon grains and/or core domains (Permo-Triassic, Carboniferous, Proterozoic) are abundant, indicating proximity of the Chiavenna unit to thinned continental crust. This is in line with the origin of this unit from subcontinental mantle sources, as suggested previously on petrological and structural grounds. Metamorphic zircon domains from one amphibolite near Chiavenna yielded a weighted mean ²⁰⁶Pb/²³⁸U age at 37.1±0.9 Ma, identical to the 38.5±0.9 Ma SHRIMP age of an amphibolitized eclogite of the Antrona ophiolites (Valais domain, Western Alps). Precise metamorphic ages were difficult to obtain from the composite (poly)metamorphic rim domains of the Prata amphibolite. This is attributed to the location of the Prata area close to the granulite-facies Gruf unit (metamorphosed at ca. 33 Ma) and to the 24–25 Ma old Novate granite, where metamorphic/fluid events probably caused multiple resetting to various degrees. The ca. 93 Ma old magmatism, identified for the first time in the Chiavenna unit, is the youngest basic oceanic magmatism reported in the Alps. The 37.1±0.9 Ma old metamorphism in the Chiavenna unit, attributed to the Valais domain, confirms the model suggesting stepwise younging of metamorphic ages from the south (Adriatic plate) to the north (European plate). It is older than metamorphism in the European margin (ca. 35–31 Ma) lying to the north of the Valais domain and younger than that in the Piemont–Ligurian Ocean (ca. 44–45 Ma) lying to the south of the Valais domain.Editorial responsibility: W. Schreyer     

The solar system abundances of phosphorus and titanium and the nebular volatility of phosphorus

Abstract— The bulk chemical composition of Orgueil and 25 other carbonaceous chondrites was determined by x‐ray fluorescence analysis. The sample sizes of the analyzed meteorites were in all cases 120 mg. The abundances of P and Ti in Orgueil and Ivuna were precisely determined by the standard addition method. The new P CI abundance is 926 ± 65 ppm. Excluding the low P of Ivuna and one Orgueil sample with unusual chemistry gives a CI P content of 930 ± 23 ppm. A CI abundance of 926 ppm corresponds to a P/Si wt ratio of 8.66 times 10^?3 (atomic ratio 7.85 times 10^?3). For Ti a CI content of 458 ± 18 ppm and a Ti/Si wtratio of 4.28 times 10^?3 (atomic ratio 2.51 times 10^?3) were found. A Si content of 10.69% was obtained for average CI. The new P CI abundance is 20 to 30% below earlier estimates, while the Ti CI abundance is in agreement with earlier determinations. From the results of the analyses of bulk carbonaceous chondrites it is concluded: (1) Refractory element/Mg ratios increase from CI through CM and C3O to C3V, but ratios among Al, Ca and Ti are constant, except for low Ca/Al ratios in the reduced subgroup of C3V. (2) The Si/Mg ratios are constant in all groups of carbonaceous chondrites. (3) There is a volatility related depletion of Cr and Fe, but the Cr/Fe ratios are constant. (4) The sequence of volatility related depletions of the moderately volatile elements P, Au, As, Mn, and Zn follows condensation temperatures (except for As), if in condensation calculations non‐ideal solid solution in the host phase is considered.