A method to determine crystallization temperatures of hydrated crystals by intracrystalline oxygen isotope effects

The fractionation of the oxygen isotopes between water molecules from different sites in CuSO₄ · 5H₂O has been measured for crystallization temperatures of 25, 40 and 50°C. The temperature dependence found provides a basis for the determination of crystallization temperatures from such intracrystalline oxygen isotope effects; also for hydrated crystals of mineralogical and geological interest. Necessary suppositions for the application of this method are discussed.     

Temporal and geochemical evolution of the Cenozoic intraplate volcanism of Zealandia

In order to constrain better the distribution, age, geochemistry and origin of widespread Cenozoic intraplate volcanism on Zealandia, the New Zealand micro-continent, we report new ⁴⁰Ar/³⁹Ar and geochemical (major and trace element and Sr–Nd–Hf–Pb isotope) data from offshore (Chatham Rise, Campbell and Challenger Plateaus) and onland (North, South, Auckland, Campbell, Chatham and Antipodes Islands of New Zealand) volcanism on Zealandia. The samples include nephelinite, basanite through phonolite, alkali basalt through trachyte/rhyolite, and minor tholeiite and basaltic andesite, all of which have ocean island basalt (OIB)-type trace element signatures and which range in age from 64.8 to 0.17 Ma. Isotope ratios show a wide range in composition (⁸⁷Sr/⁸⁶Sr = 0.7027–0.7050, ¹⁴³Nd/¹⁴⁴Nd = 0.5128–0.5131, ¹⁷⁷Hf/¹⁷⁶Hf = 0.2829–0.2831, ²⁰⁶Pb/²⁰⁴Pb = 18.62–20.67, ²⁰⁷Pb/²⁰⁴Pb = 15.54–15.72 and ²⁰⁸Pb/²⁰⁴Pb = 38.27–40.34) with samples plotting between mid-ocean-ridge basalts (MORB) and Cretaceous New Zealand intraplate volcanic rocks.Major characteristics of Zealandia's Cenozoic volcanism include longevity, irregular distribution and lack of age progressions in the direction of plate motion, or indeed any systematic temporal or spatial geochemical variations. We believe that these characteristics can be best explained in the context of lithospheric detachment, which causes upwelling and melting of the upper asthenospheric mantle and portions of the removed lithosphere. We propose that a large-scale seismic low-velocity anomaly, that stretches from beneath West Antarctica to Zealandia at a depth of > 600 km may represent a geochemical reservoir that has been in existence since the Cretaceous, and has been supplying the upper mantle beneath Zealandia with HIMU-type plume material throughout the Cenozoic. In addition, the sources of the Cenozoic intraplate volcanism may be at least partially derived through melting of locally detached Zealandia lower lithosphere.     

Size distribution of the Late Devonian ammonoid Prolobites: indication for possible mass spawning events

Worldwide, the ammonoid genus Prolobites is only known from a few localities, and from these fossil beds almost all of the specimens are adults as shown by the presence of a terminal growth stage. This is in marked contrast to the co-occurring ammonoid genera such as Sporadoceras, Prionoceras, and Platyclymenia. Size distribution of specimens of Prolobites from three studied localities show that, unlike in the co-occurring ammonoid species, most of the material belongs to adult individuals. The morphometric analysis of Prolobites delphinus (Sandberger & Sandberger 1851) demonstrates the intraspecific variability including variants with elliptical coiling and that dimorphism is not detectable. The Prolobites material shows close resemblance to spawning populations of Recent coleoids such as the squid Todarodes filippovae Adam 1975. Possible mass spawning events are discussed in the context of the size distribution and limited geographic range of Prolobites. Finally, the potential fecundity and brooding behaviour of Prolobites is hypothesized using the examples of post spawning egg care in Recent coleoids.     

Element signatures of subduction-zone fluids. An experimental study of the element partitioning (Dfluid/rock) of natural partly altered igneous rocks from the ODP drilling site 1,256

The trace element signatures of fluids were investigated by leaching experiments on natural samples of partly altered mafic igneous rocks recovered from the drilling site 1,256 of ODP Leg 206 on the Cocos plate (Central America). Experiments with ultrapure water were performed at 400 °C/0.4 GPa and 500 °C/0.7 GPa. Both fluids and residual solids were examined to obtain the partition coefficients (D^fluid/rock) of various trace elements. Element partition coefficients (D^fluid/rock) obtained at 500 °C/0.7 GPa are significantly lower compared to results obtained at 400 °C/0.4 GPa, which is in contrast to observations at higher pressures (2.2–6 GPa) and temperatures between 700 and 1,400 °C (Kessel et al. in Earth Planet Sci Lett 237: 873–892, 2005a; Spandler et al. in Chem Geol 239: 228–249, 2007). This finding may indicate a considerable pressure effect on the leaching processes and strongly divergent fluid–rock interactions in the upper part of a subduction zone at 0.4–0.7 GPa compared to deeper subduction areas with higher pressures. Furthermore, this may be interpreted as one of the earliest fractionation processes during the subduction of crustal material.     

The age of the Roter Kamm impact crater,Namibia: Constraints from 40Ar-39Ar,K-Ar,Rb-Sr,fission track,and 10Be-26Al studies

Abstract The well-preserved 2.5 km diameter Roter Kamm impact crater is located in the Namib desert in Namibia. The impact has occurred in Precambrian granitic and granodioritic orthogneisses of the 1200–900 Ma old Namaqualand Metamorphic Complex which were partly covered by Gariep metasediments; the granites are invaded by quartz veins and quartz-feldspar-pegmatites. Previous geological field evidence suggested a crater age of about 5–10 Ma. In order to constrain this age, we selected a set of basement rocks (granites, granodiorites) exposed at the crater rim and studied the Rb-Sr, K-Ar, ⁴⁰Ar-³⁹Ar, and ¹⁰Be-²⁶Al isotopic systems as well as apatite fission track ages of these samples. The Rb-Sr isotopic systematics confirm the derivation of these samples from the Namaqualand basement (age about 1.29 Ga), which underwent Damaran orogenesis at about 650 Ma. No basement rocks with Rb-Sr ages younger than about 410 Ma were identified. The K-Ar ages of pseudotachylite and melt breccia samples show that these samples are dominated by incompletely degassed fragments of basement rocks, with some retaining their original metamorphic ages of about 470 Ma. The apatite fission track ages range from 20–28 Ma, which may be interpreted as an extension of the 25 Ma Burdigalian peneplanation event, or as incomplete resetting of the apatite fission tracks during the impact event. The ¹⁰Be and ²⁶Al exposure age of a quartz sample isolated from a quartz-pegmatite was found to be 150 ka; it is likely that the exposure of the sample began after material covering it had been removed by erosion 150 ka ago. Two glassy fractions extracted from a rim granite were dated by ⁴⁰Ar-³⁹Ar analysis. One sample gives practically a plateau age of 3.7 ± 0.3 Ma, while the other gives a minimum age of 3.6 Ma. The best available age estimate for the Roter Kamm crater is therefore 3.7 ± 0.3 Ma.     

Ozone production due to emissions from vegetation burning

Ozone has been observed in elevated concentrations by satellites over areas previously believed to be background. There is meteorological evidence, that these ozone plumes found over the Atlantic Ocean originate from vegetation fires on the African continent.In a previous study (DECAFE-88), we have investigated ozone and assumed precursor compounds over African tropical forest regions. Our measurements revealed large photosmog layers at altitudes from 1.5 to 4 km. Both chemical and meteorological evidence point to savanna fires up to several thousand km upwind as sources.Here we describe ozone mixing ratios observed over western Africa and compare ozone production ratios from different field measurement campaigns related to vegetation burning. We find that air masses containing photosmog ingredients require several days to develop their oxidation potential, similar to what is known from air polluted by emissions from fossil fuel burning. Finally, we estimate the global ozone production due to vegetation fires and conclude that this source is comparable in strength to the stratospheric input.     

Mesozoic (Late Jurassic) palynomorphs and charcoal from a sandstone pebble from Quaternary glacial deposits of the North Sea

The palynological contents as well as macroscopic charcoal fragments from a calcareous sandstone pebble from Quaternary glacial deposits of the North Sea (80 km SW of the Dogger Bank) are described. The taxonomic composition of the palynoflora points to a Late Jurassic (or Late Jurassic/Early Cretaceous) age of the sandstone. The charcoal is interpreted as direct evidence of palaeo‐wildfire occurring during this period in the source area of the sediments of this particular sandstone. This finding, together with already published data on Mesozoic deposits, allows to conclude that wildfires were obviously widespread during this period in the area of the modern day North Sea and adjacent areas. Copyright © 2012 John Wiley & Sons, Ltd.     

Hypolimnetic density currents traced by sulphur hexafluoride (SF6)

The artificial tracer sulphur hexafluoride (SF₆) has been used to study the density-driven deep water exchange between two sill-separated basins of Lake Lucerne, Gersauersee and Urnersee. The sources of the density gradients between the two basins are (1) salinity differences between the major inlets due to the different geology of their drainage areas, and (2) temperature differences due to spatial variation of wind forcing. Wind speeds are generally larger in Urnersee, especially in spring during the so-called Föhn events, when winds blow from the south. In contrast, Gersauersee is protected form these winds. In spring 1989, a total of 630 g of SF₆ was released at 80 to 120 m depth in the small Treib Basin located between Urnersee and Gersauersee. During about 100 days the distribution of SF₆ in the lake was determined by gaschromatography. Two models are used to quantify the exchange flow, (1) a one-box mass balance model for SF₆ in the deep part of Treib Basin, and (2) a one-dimensional diffusion/advection model describing the temporal and vertical temperature variation in Urnersee. According to the first model, the flow into the deep hypolimnion of Urnersee, decreases from 21·10⁶ m³·d^?1 at the end of March to about 8·10⁶ m³·d^?1 in late April. The second model yields similar flow rates. The decrease of the flow rate during spring, confirmed by both approaches, is consistent (1) with the decreasing strength of the density gradient above the sill during spring and early summer, and (2) with hydrographic information collected in Lake Lucerne during other years.