Stratigraphy of the tectonically imbricated lithological succession of the Neves Corvo mine area,Iberian Pyrite Belt,Portugal

Biostratigraphic research, based on palynomorphs and ammonoids, of the tectonically imbricated lithological succession of the Neves Corvo mine, in the Portuguese part of the Iberian Pyrite Belt, has yielded ages for all formerly recognised lithostratigraphic units. These can be assembled in three main lithological sequences: (1) detrital sandy/shale substrate (Phyllite-Quartzite Formation) of late Famennian age; (2) Volcano-Sedimentary Complex, divided into a lower and an upper suite, in which one basic, three dolerite sills and four felsic volcanic units and a mineralised package of massive sulphides are identified with ages which range from the late Famennian to the late Visean; (3) flysch succession (Mértola Formation) composed of shale and greywacke dated as late Visean to early Serpukhovian. Precise biostratigraphic dating of the sedimentrary host rocks of massive sulphide mineralisation constrains the age of the latter to the late Strunian (354.8–354.0 Ma). Three stratigraphic hiatuses, corresponding to early/middle Strunian, Tournaisian and early Visean respectively and a south-westward progressive unconformity were also recognised. Sequences 1 and 2 are related to extensional episodes while sequence 3 marks the beginning of compressive tectonic inversion which gave rise to south-westward flysch progradation in close relation to a foreland basin development. Our results lead to the reinterpretation of the tectonic structure of the Neves Corvo mine, with implications for the interpretation of the regional basin dynamics and metal exploration.Editorial handling: F. Tornos     

Trace element incorporation into quartz: A combined study by ICP-MS, electron spin resonance, cathodoluminescence, capillary ion analysis, and gas chromatography

Pegmatite quartz from different occurrences in Norway and Namibia was investigated by a combination of ICP-MS, Electron Spin Resonance (ESR), Capillary Ion Analysis (CIA) and Gas Chromatography (GC) to quantify trace elements in very low concentrations and to determine their position in the quartz structure.The studied quartz samples show similar geochemical characteristics with low contents of most trace elements. Remarkable are the elevated concentrations of Al (36-636 ppm), Ti (1.6-25.2 ppm), Ge (1.0-7.1 ppm), Na (5.2 to >50 ppm), K (1.6 to >100 ppm) and Li (2.1-165.6 ppm). These elements are preferentially incorporated into the quartz lattice on substitutional (Al, Ti, Ge) and interstitial (Li, Na, K) positions. Li⁺ was found to be the main charge compensating ion for Al, Ge and Ti, whereas some ppm of Na and K may also be hosted by fluid inclusions. Ti may be incorporated as substitutional ion for Si or bound on mineral microinclusions (rutile). The results of the ESR measurements show that there may be a redistribution of alkali ions during irradiation. The diamagnetic [AlO₄/M⁺]⁰ center transforms into the paramagnetic [AlO₄]⁰ center, whilst the compensating ions diffuse away and may be captured by the diamagnetic precursor centers of [GeO₄]⁰ and [TiO₄]⁰ to form paramagnetic centers ([TiO₄/Li⁺]⁰, [GeO₄/Li⁺]⁰).In general, fluid inclusions in pegmatite quartz can be classified as H₂O-CO₂-NaCl type inclusions with water as the predominant volatile. Among the main elements hosted by fluid inclusions in quartz are Na, K, NH₄, Ca, Mg and the anionic complexes Cl⁻, NO₃⁻, HCO₃⁻ and SO₄²⁻. Gas analysis of trapped fluids shows volatile components in the following order of abundance: H₂O > CO₂ > N₂(+) ≥ CH₄ > COS > C₂ and C₃ hydrocarbons. Additionally, traces of Co, Ni, Zn, Pb, and Cu were detected by CIA in fluid inclusions of some samples. There are indications that the REE and Rb are also bound in fluid inclusions, however, the concentrations of these elements are too low to be measured by CIA. Assuming that the REE preferentially occur in fluid inclusions, the typical chondrite normalized REE distribution patterns with tetrad effects and a distinct negative Eu anomaly would reflect the composition of the mineralizing fluid.For a number of elements, especially those with extremely low concentrations, the “type” of incorporation in quartz could not directly be determined. We conclude that these ions either are too large to substitute for the small Si⁴⁺ ion or they are not soluble in the mineralizing fluids to be hosted by fluid inclusions. Some of these elements, which are concentrated in the specific mineralization of certain pegmatites, are not present in elevated concentrations in the paragenetic pegmatite quartz itself. This was observed, for instance, for Be, Cs and Rb in the Li (Be-Cs-Rb) pegmatites of Rubicon or for Nb and Ta for Nb-Ta bearing pegmatites from Norway. It may be concluded that the concentrations of these trace elements in quartz do not reflect the mineralization and that these elements thus, cannot be used as petrogenetic indicator.     

Environmental Copper and Manganese in the Pathophysiology of Neurologic Diseases (Alzheimer's Disease and Manganism)

Alzheimer's disease (AD) is the most common form of dementia. Populations migrating from developing to industrialized countries seem to elicit a higher incidence and prevalence rate of AD, suggesting lifestyle and environmental factors to have a role in the pathophysiology of AD. One of its major neuropathological hallmarks is the deposition of Aβ peptides as amyloid plaques in the brain of AD patients. Aβ is proteolytically cleaved out of the larger amyloid precursor protein (APP). Cu and Mn are often found in drinking water and may have a neurotoxic potential. APP is involved in Cu homeostasis in mouse and man. In vitro observations and in vivo data obtained from APP mouse models provide strong evidence that APP overexpression enables intracellular Cu to be transported out of the cell. Disturbed metal‐ion homeostasis with elevated serum Cu levels occurs in Alzheimer and Down's patients and lowered levels in post‐mortem AD brain. We observed that bioavailable Cu has specific beneficial effects in an Alzheimer's disease mouse model. This should be regarded as a proof‐of‐concept for a prophylactic approach to overcome the observed CNS Cu deficiency in the brain of Alzheimer's disease patients. Manganism is a disorder with symptoms similar to that of Parkinson's disease. The precise mechanism how manganese can damage the nervous system is unknown. There is some evidence that iron and manganese may utilize similar transport systems. Epidemi ologic data strongly suggests that manganese enters the body primarily via inhalation and through the ingestion of manganese in drinking water.     

Reef development on a deepening platform: two Early Cretaceous coralgal patch reefs (Catí, Llàcova Formation, eastern Spain) compared

Two coralgal patch reefs of the Hauterivian Llàcova Formation (Maestrat Basin, eastern Spain), exposed at two consecutive stratigraphic levels within a single section, have been studied to document taxonomic implications of a changing environment. These two reefal palaeocommunities differ substantially in coral taxonomic composition, microbialite formation pattern and in abundance and composition of encrusters and bioeroders. Of a total of 14 coral species, just one (Stylina parvistella) occurs in both reefs, yet is abundant in the (lower) reef A and rare, occurring near the reef base, in the reef B assemblage. Reef A is dominated by a phototrophic fauna and coral species with small corallites and imperforate septa (a stylinid-thamnasteriid-heterocoeniid-actinastreid association), along with an encruster association dominated by Bacinella and Lithocodium. Reef B is characterised by a balanced phototrophic-heterotrophic fauna that gradually passes into a heterotrophic-dominated assemblage. During this latest growth stage, microsolenid corals dominated the assemblage. The encruster fauna is characterised by sponges, polychaetes and bryozoans. Moderate deepening during a transgressive systems tract (TST) depositional sequence and elevated nutrient supply are interpreted to represent the driving environmental parameters that caused faunal compositions to differ between these two reefal palaeocommunities. Nine coral taxa, previously known only from younger (Barremian–Cenomanian) strata, have been identified, namely Dimorphocoenia? rudis, Eocomoseris raueni, Eocomoseris sp., Holocoenia jaccardi, Latusastrea irregularis, Mesomorpha sp., Microsolena kugleri, Polyphylloseris mammillata and Polyphylloseris sp. This observation emphasises the importance of the Hauterivian Stage as a period of evolutionary transition in Late Jurassic–Cretaceous coral faunas.     

CO2 Mitigation by Agriculture: An Overview

Agriculture currently contributes significantly to the increase of CO2 in the atmosphere, primarily through the conversion of native ecosystems to agricultural uses in the tropics. Yet there are major opportunities for mitigation of CO2 and other greenhouse gas emissions through changes in the use and management of agricultural lands. Agricultural mitigation options can be broadly divided into two categories: (I) strategies to maintain and increase stocks of organic C in soils (and biomass), and (ii) reductions in fossil C consumption, including reduced emissions by the agricultural sector itself and through agricultural production of biofuels to substitute for fossil fuels.Reducing the conversion of new land to agriculture in the tropics could substantially reduce CO2 emissions, but this option faces several difficult issues including population increase, land tenure and other socio-political factors in developing countries. The most significant opportunities for reducing tropical land conversions are in the humid tropics and in tropical wetlands. An important linkage is to improve the productivity and sustainability of existing agricultural lands in these regions.Globally, we estimate potential agricultural CO2 mitigation through soil C sequestration to be 0.4-0.9 Pg C y-1, through better management of existing agricultural soils, restoration of degraded lands, permanent "set-asides" of surplus agricultural lands in temperate developed countries and restoration of 10-20% of former wetlands now being used for agriculture. However, soils have a finite capacity to store additional C and therefore any increases in C stocks following changes in management would be largely realized within 50-100 years.Mitigation potential through reducing direct agricultural emissions is modest, 0.01-0.05 Pg C y-1. However, the potential to offset fossil C consumption through the use of biofuels produced by agriculture is substantial, 0.5-1.6 Pg C y-1, mainly through the production of dedicated biofuel crops with a smaller contribution (0.2-0.3 Pg C y-1) from crop residues.Many agricultural mitigation options represent "win-win" situations, in that there are important side benefits, in addition to CO2 mitigation, that could be achieved, e.g. improved soil fertility with higher soil organic matter, protection of lands poorly suited for permanent agriculture, cost saving for fossil fuel inputs and diversification of agricultural production (e.g. biofuels). However, the needs for global food production and farmer/societal acceptability suggest that mitigation technologies should conform to: (I) the enhancement of agricultural production levels in parts of the world where food production and population demand are in delicate balance and (ii) the accrual of additional benefits to the farmer (e.g., reduced labor, reduced or more efficient use of inputs) and society at large.     

In-situ Measurements of Tropospheric Hydroxyl Radicals by Folded Long-Path Laser Absorption During the Field Campaign POPCORN

Absolutely calibrated in-situ measurements of tropospheric hydroxyl radicals, formaldehyde, sulfur dioxide, and naphthalene (C10H8) were performed by long-path laser absorption spectroscopy during the field campaign POPCORN. The absorption light path was folded into an open optical multiple reflection cell with a mirror separation of 38.5 m. Using a light path length of 1848 m and an integration time of 200 s, the average 1-detection limits of OH, HCHO, SO2 and C10H8 during POPCORN were 8.7 · 105 cm–3, 8.3 · 109 cm–3, 2.4 · 109 cm–3, 1.5 · 108 cm–3, respectively. In total, 392 identifications of OH in air spectra were made in a rural environment between August 5 and August 23, 1994. We present and discuss OH absorption spectra and diurnal OH concentration profiles of three days which are representative for measurements under different pollution conditions during POPCORN. The observed maximum and median OH radical concentrations are 1.3 · 107 OH/cm3 and 4.0 · 106 OH/cm3, respectively. The measured diurnal variation of the OH concentration shows a good correlation with the primary formation reaction of OH radicals which is the photolysis of ambient ozone. Deviations from this correlation in the morning and evening hours, when the OH concentration is higher than expected from the ozone photolysis, demonstrate the importance of other photochemical HOx production pathways during POPCORN.     

Scenarios of extreme temperature events

Based on the principles of the probability theory a statistical model has been developed assessing the likelihood of occurrence of extreme temperature events from the knowledge of the statistical characteristics of the daily temperature extremes. It is demonstrated that the probability of such events is more sensitive to changes in the variability of climate than to changes in its average. Further, this sensitivity increases at a nonlinear rate the more extreme the event. The applicability of the model has been verified by comparing the simulated frequencies of a large spectrum of temperature events with the observed numbers derived from a long time series of daily temperature extremes at Potsdam. Accordingly, the relative simulation errors increase significantly as the events become more extreme. A correction is possible, because most of these errors are systematic rather than random. Moreover, in accordance with the climate observations the simulations reveal statistically significant linear trends in the number of extreme events since the end of the last century. Local scenarios of extreme temperature events have been derived for the city of Berlin by considering both hypothetical new climate states and climate changes simulated by a General Circulation Model (GCM). As a consequence of an increase in the atmospheric concentration of greenhouse gases up to the end of the next century according to the IPCC Scenario A the repetition rate of extreme events in summer (e.g., hot days) is expected to rise considerably relative to the current climate. Moreover, in the winter season cold days will become extremely rare.     

Photogrammetry as a tool for detecting recent crustal movements

Progress in model building and in advanced exposure and evaluation methods is leading photogrammetry up into the field of precise point determination, up to now solved by classical geodetic triangulation and/or trilateration. In combination with the statistical test theory, photogrammetry can be used as a tool to detect recent crustal movements or deformations of man-made constructions, such as in coal mining or oil and gas exploitation.

For these reasons, this paper deals with model building for modern aerial triangulation with respect to hypothesis tests to detect point displacements greater than the measurement noise. An example from brown-coal mining demonstrates accuracies and the application of some statistical tests shows the efficiency of advanced aerial photogrammetry.     

An optimized chemiluminescence detector for tropospheric NO measurements

A detector for the chemiluminescent measurement of NO in background air is described. A large reduction of interferences is achieved by using a stabilized ozone generator which allows operation of the instrument at lower O₃ concentrations. Purification and humidification of the O₃ stream further reduces interferences and shortens the instrumental clean-up time, which is important for aircraft missions. From a series of laboratory tests and from measurements performed aboard an aircraft it is demonstrated that the remaining interferences are acceptable for measurements in the undisturbed troposphere. In particular, no remnant NO signal is observed in clean air at night. During flight, a detection limit (2) of 20 ppt is achieved for a 1 min integration time.     

Evolution of the West Andean Escarpment at 18°S (N. Chile) during the last 25 Ma: uplift, erosion and collapse through time

The geological record of the Western Andean Escarpment (WARP) reveals episodes of uplift, erosion, volcanism and sedimentation. The lithological sequence at 18°S comprises a thick pile of Azapa Conglomerates (25–19 Ma), an overlying series of widespread rhyodacitic Oxaya Ignimbrites (up to 900 m thick, ca. 19 Ma), which are in turn covered by a series of mafic andesite shield volcanoes. Between 19 and 12 Ma, the surface of the Oxaya Ignimbrites evolved into a large monocline on the western slope of the Andes. A giant antithetically rotated block (Oxaya Block, 80 km×20 km) formed on this slope at about 10–12 Ma and resulted in an easterly dip and a reversed drainage on the block's surface. Morphology, topography and stratigraphic observations argue for a gravitational cause of this rotation. A “secondary” gravitational collapse (50 km³), extending 25 km to the west occurred on the steep western front of the Oxaya Block. Alluvial and fluvial sediments (11–2.7 Ma) accumulated in a half graben to the east of the tilted block and were later thrust over by the rocks of the escarpment wall, indicating further shortening between 8 and 6 Ma. Flatlying Upper Miocene sediments (<5.5 Ma) and the 2.7 Ma Lauca–Peréz Ignimbrite have not been significantly shortened since 6 Ma, suggesting that recent uplift is at least partly caused by regional tilting of the Western Andean slope.