Mendigite,Mn2Mn2MnCa(Si3O9)2, a new mineral species of the bustamite group from the Eifel volcanic region,Germany

A new mineral, mendigite (IMA no. 2014-007), isostructural with bustamite, has been found in the In den Dellen pumice quarry near Mendig, Laacher Lake area, Eifel Mountains, Rhineland-Palatinate (Rheinland-Pfalz), Germany. Associated minerals are sanidine, nosean, rhodonite, tephroite, magnetite, and a pyrochlore-group mineral. Mendigite occurs as clusters of long-prismatic crystals (up to 0.1 × 0.2 × 2.5 mm in size) in cavities within sanidinite. The color is dark brown with a brown streak. Perfect cleavage is parallel to (001). D _calc = 3.56 g/cm³. The IR spectrum shows the absence of H₂O and OH groups. Mendigite is biaxial (–), α = 1.722 (calc), β = 1.782(5), γ = 1.796(5), 2V _meas = 50(10)°. The chemical composition (electron microprobe, mean of 4 point analyses, the Mn²⁺/Mn³⁺ ratio determined from structural data and charge-balance constraints) is as follows (wt %): 0.36 MgO, 10.78 CaO, 37.47 MnO, 2.91 Mn₂O₃, 4.42 Fe₂O₃, 1.08 Al₂O₃, 43.80 SiO₂, total 100.82. The empirical formula is Mn_2.00(Mn_1.33Ca_0.67) (Mn_0.50 ²⁺ Mn_0.28 ³⁺ Fe_0.15 ³⁺ Mg_0.07)(Ca_0.80 (Mn_0.20 ²⁺)(Si_5.57 Fe_0.27 ³⁺ Al_0.16O₁₈). The idealized formula is Mn₂Mn₂MnCa(Si₃O₉)₂. The crystal structure has been refined for a single crystal. Mendigite is triclinic, space group \(P\bar 1\); the unit-cell parameters are a = 7.0993(4), b = 7.6370(5), c = 7.7037(4) Å, α = 79.58(1)°, β = 62.62(1)°, γ = 76.47(1)°; V = 359.29(4) ų, Z = 1. The strongest reflections on the X-ray powder diffraction pattern [d, Å (I, %) (hkl)] are: 3.72 (32) (020), 3.40 (20) (002, 021), 3.199 (25) (012), 3.000 (26), (\(01\bar 2\), \(1\bar 20\)), 2.885 (100) (221, \(2\bar 11\), \(1\bar 21\)), 2.691 (21) (222, \(2\bar 10\)), 2.397 (21) (\(02\bar 2\), \(21\bar 1\), 203, 031), 1.774 (37) (412, \(3\bar 21\)). The type specimen is deposited in the Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, registration number 4420/1.     

High resolution regional climate model simulations for Germany: Part II—projected climate changes

The projected climate change signals of a five-member high resolution ensemble, based on two global climate models (GCMs: ECHAM5 and CCCma3) and two regional climate models (RCMs: CLM and WRF) are analysed in this paper (Part II of a two part paper). In Part I the performance of the models for the control period are presented. The RCMs use a two nest procedure over Europe and Germany with a final spatial resolution of 7 km to downscale the GCM simulations for the present (1971–2000) and future A1B scenario (2021–2050) time periods. The ensemble was extended by earlier simulations with the RCM REMO (driven by ECHAM5, two realisations) at a slightly coarser resolution. The climate change signals are evaluated and tested for significance for mean values and the seasonal cycles of temperature and precipitation, as well as for the intensity distribution of precipitation and the numbers of dry days and dry periods. All GCMs project a significant warming over Europe on seasonal and annual scales and the projected warming of the GCMs is retained in both nests of the RCMs, however, with added small variations. The mean warming over Germany of all ensemble members for the fine nest is in the range of 0.8 and 1.3 K with an average of 1.1 K. For mean annual precipitation the climate change signal varies in the range of ?2 to 9 % over Germany within the ensemble. Changes in the number of wet days are projected in the range of ±4 % on the annual scale for the future time period. For the probability distribution of precipitation intensity, a decrease of lower intensities and an increase of moderate and higher intensities is projected by most ensemble members. For the mean values, the results indicate that the projected temperature change signal is caused mainly by the GCM and its initial condition (realisation), with little impact from the RCM. For precipitation, in addition, the RCM affects the climate change signal significantly.     

Shock metamorphism of quartz in nature and experiment: II. Significance in geoscience*

Abstract— The occurrence of shock metamorphosed quartz is the most common petrographic criterion for the identification of terrestrial impact structures and lithologies. Its utility is due to its almost ubiquitous occurrence in terrestrial rocks, its overall stability and the fact that a variety of shock metamorphic effects, occurring over a range of shock pressures, have been well documented. These shock effects have been generally duplicated in shock recovery experiments and, thus, serve as shock pressure barometers. After reviewing the general character of shock effects in quartz, the differences between experimental and natural shock events and their potential effects on the shock metamorphism of quartz are explored. The short pulse lengths in experiments may account for the difficulty in synthesizing the high-pressure polymorphs, coesite and stishovite, compared to natural occurrences. In addition, post-shock thermal effects are possible in natural events, which can affect shock altered physical properties, such as refractive index, and cause annealing of shock damage and recrystallization. The orientations of planar microstructures, however, are unaffected by post-impact thermal events, except if quartz is recrystallized, and provide the best natural shock barometer in terms of utility and occurrence. The nature of planar microstructures, particularly planar deformation features (PDFs), is discussed in some detail and a scheme of variations in orientations with shock pressure is provided. The effect of post-impact events on PDFs is generally limited to annealing of the original glass lamellae to produce decorated PDFs, resulting from the exsolution of dissolved water during recrystallization. Basal (0001) PDFs differ from other PDF orientations in that they are multiple, mechanical Brazil twins, which are difficult to detect if not partially annealed and decorated. The occurrence and significance of shock metamorphosed quartz and its other phases (namely, coesite, stishovite, diaplectic glass and lechatelierite) are discussed for terrestrial impact structures in both crystalline (non-porous) and sedimentary (porous) targets. The bulk of past studies have dealt with crystalline targets, where variations in recorded shock pressure in quartz have been used to constrain aspects of the cratering process and to estimate crater dimensions at eroded structures. In sedimentary targets, the effect of pore space results in an inhomogeneous distribution in recorded shock pressure and temperature, which requires a different classification scheme for the variation of recorded shock compared to that in crystalline targets. This is discussed, along with examples of variations in the relative abundances of planar microstructures and their orientations, which are attributed to textural variations in sedimentary target rocks. Examples of the shock metamorphism of quartz in distal ejecta, such as at the K/T boundary, and from nuclear explosions are illustrated and are equivalent to that of known impact structures, except with respect to characteristics that are due to long-term, post-shock thermal effects. Finally, the differences between the deformation and phase transformation of quartz by shock and by endogenic, tectonic and volcanic processes are discussed. We confirm previous conclusions that they are completely dissimilar in character, due to the vastly different physical conditions and time scales typical for shock events, compared to tectonic and volcanic events. Well-characterized and documented shock effects in quartz are unequivocal indicators of impact in the natural environment.     

Neutron and proton interaction backgrounds in compton-telescopes used for gamma-ray astronomy

Gamma-ray background counting rates encountered in astronomy observations are calculated for a double Compton scatter telescope. Backgrounds not eliminated by the usual growth curve could be produced by albedo neutrons and/or cosmic ray protons interacting with the carbon and/or hydrogen of the detector. They are the albedo neutron-carbon interaction gamma-rays, cosmic ray proton interaction delayed gamma rays and the moderated albedo neutron-proton photocapture gamma rays. It is decisive to know the contribution of these backgrounds, because they must be subtracted before the cosmic diffuse flux can be determined. Estimates of the neutron induced background events in a Compton telescope show that they might contribute a considerable fraction of the counting rate. In the near future the calculations will be checked with a calibrated neutron beam.     

Literal solution for Hill's lunar problem

A computer program for the manipulation of power series in several variables is used to find the first order solution to Hill's lunar problem. The ratiom of the mean motion of the Sun to that of the Moon is kept as a formal parameter. The series inm are known to converge very poorly. It is shown how efficient algorithms among them the Lie transformation allow us to compute the series inm as far as they are needed. When the series are evaluated at Brown's numerical value form the results achieve or exceed his accuracy.