Ozonation of seawater from different locations: formation and decay of total residual oxidant--implications for ballast water treatment

Ballast water is a likely cause for worldwide transfer of non-indigenous aquatic species because of the large volumes and frequency of possible inoculations. Ozone is one treatment option being considered for eliminating non-indigenous species in ballast water. When ozone is applied to seawater, secondary disinfectants are formed, commonly measured and expressed as total residual oxidant (TRO). The goal of this study was to determine those variables most likely to affect the rate of TRO increase during ozonation and the subsequent TRO decline that occurs over time. These parameters strongly influence the efficacy of ozone treatments aimed to eliminate organisms present in ballast water. Seawater was obtained from Puget Sound, Washington; Cape Fear, North Carolina; and San Francisco Bay. Results indicated that seawater characteristics, including the organic content and ammonia, affect the amount of ozone required to achieve a desired TRO level and rate of TRO decay, and therefore need to be considered in determining ozone requirements for ballast water treatment.     

Detection and discrimination of sulfate minerals using reflectance spectroscopy

A suite of sulfate minerals were characterized spectrally, compositionally, and structurally in order to develop spectral reflectance-compositional-structural relations for this group of minerals. Sulfates exhibit diverse spectral properties, and absorption-band assignments have been developed for the 0.3-26 μm range. Sulfate absorption features can be related to the presence of transition elements, OH, H₂O, and SO₄ groups. The number, wavelength position, and intensity of these bands are a function of both composition and structure. Cation substitutions can affect the wavelength positions of all major absorption bands. Hydroxo-bridged Fe³⁺ results in absorption bands in the 0.43, 0.5, and 0.9 μm regions, while the presence of Fe²⁺ results in absorption features in the 0.9-1.2 μm interval. Fundamental SO bending and stretching vibration absorption bands occur in the 8-10, 13-18, and 19-24 μm regions (1000-1250, 550-770, and 420-530 cm⁻¹). The most intense combinations and overtones of these fundamentals are found in the 4-5 μm (2000-2500 cm⁻¹) region. Absorption features seen in the 1.7-1.85 μm interval are attributable to HOH/OH bending and translation/rotation combinations, while bands in the 2.1-2.7 μm regions can be attributed to H₂O- and OH-combinations as well as overtones of SO bending fundamentals. OH- and H₂O-bearing sulfate spectra are fundamentally different from each other at wavelengths below ∼6 μm. Changes in H₂O/OH content can shift SO band positions due to change in bond lengths and structural rearrangement. Differences in absorption band wavelength positions enable discrimination of all the sulfate minerals used in this study in a number of wavelength intervals. Of the major absorption band regions, the 4-5 μm region seems best for identifying and discriminating sulfates in the presence of other major rock-forming minerals.     

Determining the depth and location of potential field sources without specifying the structural index

There are many semiautomatic interpretation methods for potential field data. Some only work for a specific model, such as a contact or dyke, while others can be applied to any structure which has a known structural index (S.I.) (which gives the rate of decrease with distance of the amplitude of the anomaly). Various strategies exist for the automatic determination of the S.I., some of which involve inversion, or the use of data from different altitudes. A simple new method of determining the depth, location, and S.I. of potential field sources is introduced here and demonstrated on potential field data from South Africa.     

Parametrization of peatland hydraulic properties for the Canadian land surface scheme

Abstract

A hydraulic parametrization is developed for peatland environments in the Canadian Land Surface Scheme (CLASS). Three ‐wetland soil classes account for the typical variation in the hydraulic characteristics of the uppermost 0.5 m of organic soils. Review of the literature reveals that saturated hydraulic conductivity varies from a median of 1.0 × 10^?7m/s in deeply humified sapric peat to 2.8 × 10^?4 m/s in relatively undecomposed fibric peat. Average pore volume fraction ranges from 0.83 to 0.93. Parameters have been designed for the soil moisture characteristic curves for fibric, hemic and sapric peat using the Campbell (1974) equation employed in CLASS, and the van Genuchten (1980) formulation. There is little difference in modelled soil moisture between the two formulations within the range of conditions normally found in peatlands. Validation of modelled water table depth and peat temperature is performed for a fen in northern Québec and a bog in north‐central Minnesota. The new parametrization results in a more realistic simulation of these variables in peatlands than the previous version of CLASS, in which unrealistic mineral soil “equivalents “ were used for wetland soil climate modelling.     

ENSIP: the El Niño simulation intercomparison project

An ensemble of twenty four coupled ocean-atmosphere models has been compared with respect to their performance in the tropical Pacific. The coupled models span a large portion of the parameter space and differ in many respects. The intercomparison includes TOGA (Tropical Ocean Global Atmosphere)-type models consisting of high-resolution tropical ocean models and coarse-resolution global atmosphere models, coarse-resolution global coupled models, and a few global coupled models with high resolution in the equatorial region in their ocean components. The performance of the annual mean state, the seasonal cycle and the interannual variability are investigated. The primary quantity analysed is sea surface temperature (SST). Additionally, the evolution of interannual heat content variations in the tropical Pacific and the relationship between the interannual SST variations in the equatorial Pacific to fluctuations in the strength of the Indian summer monsoon are investigated. The results can be summarised as follows: almost all models (even those employing flux corrections) still have problems in simulating the SST climatology, although some improvements are found relative to earlier intercomparison studies. Only a few of the coupled models simulate the El Niño/Southern Oscillation (ENSO) in terms of gross equatorial SST anomalies realistically. In particular, many models overestimate the variability in the western equatorial Pacific and underestimate the SST variability in the east. The evolution of interannual heat content variations is similar to that observed in almost all models. Finally, the majority of the models show a strong connection between ENSO and the strength of the Indian summer monsoon.     

Parameterization of snow-free land surface albedo as a function of vegetation phenology based on MODIS data and applied in climate modelling

The aim of this study was to develop an advanced parameterization of the snow-free land surface albedo for climate modelling describing the temporal variation of surface albedo as a function of vegetation phenology on a monthly time scale. To estimate the effect of vegetation phenology on snow-free land surface albedo, remotely sensed data products from the Moderate-Resolution Imaging Spectroradiometer (MODIS) on board the NASA Terra platform measured during 2001 to 2004 are used. The snow-free surface albedo variability is determined by the optical contrast between the vegetation canopy and the underlying soil surface. The MODIS products of the white-sky albedo for total shortwave broad bands and the fraction of absorbed photosynthetically active radiation (FPAR) are analysed to separate the vegetation canopy albedo from the underlying soil albedo. Global maps of pure soil albedo and pure vegetation albedo are derived on a 0.5° regular latitude/longitude grid, re-sampling the high-resolution information from remote sensing-measured pixel level to the model grid scale and filling up gaps from the satellite data. These global maps show that in the northern and mid-latitudes soils are mostly darker than vegetation, whereas in the lower latitudes, especially in semi-deserts, soil albedo is mostly higher than vegetation albedo. The separated soil and vegetation albedo can be applied to compute the annual surface albedo cycle from monthly varying leaf area index. This parameterization is especially designed for the land surface scheme of the regional climate model REMO and the global climate model ECHAM5, but can easily be integrated into the land surface schemes of other regional and global climate models.     

On the occurrence of an unusual form of monazite in panned stream sediments in Wales

An unusual nodular form of monazite has been found to account for abnormally high levels of cerium in panned heavy mineral concentrates from stream sediments in several areas in Wales and pan of Exmoor. Textural features indicate a pre-metamorphic, diagenetic origin within Lower Palaeozoic shale or siltstone host-rocks but REE patterns show only minor variation, including relative enrichment in europium, from ‘average’ granitic monazite. The similarities between these occurrences, described for the first time from the British Isles, and those previously described from Brittany and elsewhere are discussed.