Sources of the transuranic elements plutonium and neptunium in arctic marine sediments

We report here thermal ionization mass spectrometry measurements of ²³⁹Pu, ²⁴⁰Pu, ²⁴¹Pu, ²⁴²Pu, and ²³⁷Np isolated from oceanic, estuarine, and riverine sediments from the Arctic Ocean Basin. ²³⁸Pu/^239+240Pu activity ratios are also reported for alpha spectrometric analyses undertaken on a subset of these samples. Our results indicate that the Pu in sediments on the Alaskan shelf and slope, as well as that in the deep basins (Amerasian and Eurasian) of the Arctic Ocean, has its origin in stratospheric and tropospheric fallout. Sediments from the Ob and Yenisei Rivers show isotopic Pu signatures that are distinctly different from those of northern-hemisphere stratospheric fallout and indicate the presence of weapons-grade Pu originating from nuclear fuel reprocessing wastes generated at Russian facilities within these river catchments. Consequently, sediments of the Eurasian Arctic Ocean, particularly those in the Barents and Kara Seas, probably contain a mixture of Pu from stratospheric fallout, tropospheric fallout, and fuel-reprocessing wastes of riverine origin. In particular, the ²⁴¹Pu/²³⁹Pu ratios observed in these sediments are inconsistent with significant contributions of Pu to the arctic sediments studied from western European reprocessing facilities, principally Sellafield in the UK. Several other potential sources of Pu to arctic sediments can also be excluded as significant based upon the transuranic isotope ratios presented.     

Evaluating different GCMs for predicting spatial recharge in an irrigated arid region

Groundwater systems in arid regions will be particularly sensitive to climate change owing to the strong dependence of rates of evapotranspiration on temperature, and shifts in the precipitation regimes. Irrigation use in these arid regions is typically a large component of the water budget, and may increase due to changes in soil moisture resulting from higher temperatures and changes in the timing of precipitation events. In this study, future predicted climate change scenarios from three global climate models (CGCM1 GHG+A1, CGCM3.1 A2, and HadCM3 A2) are used to determine the sensitivity of recharge to different climate models in an irrigated agricultural region. The arid Oliver region (annual precipitation 300 mm) in the Okanagan Basin, British Columbia, is used to demonstrate the approach. Irrigation return flow, as a contribution to total diffuse recharge, is simulated by calculating the daily applied irrigation based on estimates of seasonal crop water demand and the forecasted precipitation and evaporation data. The relative contribution of irrigation return flow to groundwater recharge under current and future climate conditions is modelled. Temperature data were downscaled using Statistical Downscaling Model (SDSM), while precipitation and solar radiation changes were estimated directly from the GCM data. Shifts in climate, from present to future predicted, were applied to a stochastic weather generator, and used to force a one-dimensional hydrologic model, HELP 3.80D. Results were applied spatially, according to different soil profiles, slope and vegetation, over a 22.5 km by 8.6 km region. Changes to recharge in future time periods for each GCM result in modest increases of recharge with the peak recharge shifting from March to February. Lower recharge rates and higher potential evapotranspiration rates are similarly predicted by all three models for the summer months. All scenarios show that the potential growing season will expand between 3 and 4 weeks due to increases in temperature. However, the magnitude of the change varies considerably between models. CGCM3.1 has the largest increases of recharge rates, CGCM1 has very minor increases, and HadCM3 is relatively stable (as indicated by the near-zero changes between climate states). The significant differences between these three models indicate that prediction of future recharge is highly dependent on the model selected. The minor increase of annual recharge in future predicted climate states is due the shift of peak recharge from increased temperature. Irrigation rates dominate total recharge during the summer months in this arid area. Recharge in irrigated areas is significantly higher than natural recharge, with irrigation return flow between 25% and 58%. A comparison of recharge results for the least efficient and the most efficient irrigation systems indicates that the latter are more sensitive to choice of GCM.     

Variability of shallow overland flow velocity and soil aggregate transport observed with digital videography

Field experiments at Tiramoana station 30 km north of Christchurch, New Zealand using an erosion plot 16·5 m long, 0·6 m wide, and with a slope of 14–14·5° on rendzina soil aimed to measure the variability of flow velocity and of soil aggregates transport rate in shallow overland flow. Discharge/cross‐section area ratio was used to estimate mean velocity, and high‐speed digital video camera and image analysis provided information about flow and sediment transport variability. Six flow runs with 0·5–3·0 L s^?1 discharges were supercritical with Froude numbers close to or more than 1. Mean flow velocity followed Poiseuille law, float numbers were more than 1·5 and hydraulic resistance was an inverse proportional function of the Reynolds number, which is typical for laminar flows. Hence actual velocity varied through time significantly and the power spectrum was of ‘red‐noise’, which is typical for turbulent flow. Sediment transport rates had even higher variability, and soil aggregates transport was a compound Poisson process. Copyright © 2008 John Wiley & Sons, Ltd.     

Dynamics of a Prorocentrum minimum bloom along the northern coast of Sinaloa,Mexico

To investigate the relative importance of mesoscale physical events, such as upwellings and physical and chemical variables during an algae bloom of Prorocentrum minimum, 25 sampling sites were established offshore of the Navachiste Lagoon Complex on the east side of the Gulf of California. Samples were analyzed for phytoplankton concentration, water chemistry, and temperature during November 1999, January, March, April, May, and August 2000. Satellite imagery of sea surface temperature (SST) for April 2000 was processed to obtain a synoptic view of the area during the extraordinary bloom of P. minimum in the open waters of the Gulf of California. The bloom was associated with change of oceanographic conditions from moderate winds to calm period, temperature increase and high nitrate (NO₃⁻-N) and ammonia (NH₄⁺-N) content in the offshore waters. Depletion of these nutrients during the bloom suggests that this species uses both types of nitrogen substrates. Cysts in the northernmost sampling stations in January and March indicate that upwelling water, rich in nitrates, also carried a seed stock population of P. minimum. SST patterns in the satellite imagery suggest wind-forcing as the responsible mechanisms triggering the algal bloom offshore of the Navachiste Lagoon Complex.     

Spatial and temporal dynamics of stream water particulate and dissolved N, P and C forms along a catchment transect, NE Scotland

The dynamics of dissolved and particulate N, P and organic C were examined for field drains, through a headwater (4 km²), into a mesoscale stream (51 km²) and river (1844 km²) catchment. Distributions of N and P forms were similar in the agricultural headwater and field drains; annual P fluxes of particulate and dissolved forms were of equal magnitude, whilst N was dominated by NO₃–N. Across all scales organic P was an important, often dominant, component of the dissolved P. Temporal variation in nutrient concentrations and proportions was greatest in the headwater, where storms resulted in the generation of large concentrations of suspended particulate matter, particulate and dissolved P, particularly following dry periods. The data suggest that groundwater and minor point source inputs to the mesoscale catchment buffered the temporal variability in hydrochemistry relative to the headwater. Summer low flows were associated with large PO₄–P concentrations in the mesoscale catchment at a critical time of biological sensitivity. At the largest river catchment scale, organic forms of C, N and P dominated. Inorganic nutrient concentrations were kept small through dilution by runoff from upland areas and biological processes converted dissolved N and P to particulate forms. The different processes operating between the drain/headwater to the large river scale have implications for river basin management. Given the prevalence of organic and particulate P forms in our catchment transect, the bioavailability of these fractions needs to be better understood.     

Aeolian fetch distance and secondary airflow effects: the influence of micro‐scale variables on meso‐scale foredune development

Unsuccessful attempts to use process‐scale models to predict long‐term aeolian sediment transport patterns have long been a feature of aeolian research. It has been proposed that one approach to overcome these problems is to identify micro‐scale variables that are important at longer timescales. This paper assesses the contribution of two system variables (secondary airflow patterns and fetch distance) to medium‐term (months to years) dune development. The micro‐scale importance of these variables had been established during previous work at the site (Magilligan Strand, Northern Ireland). Three methods were employed. First, sand drift potentials were calculated using 2 years of regional wind data and a sediment transport model. Second, wind data and large trench traps (2 m length × 1 m width × 1·5 m depth) were used to assess the actual sediment transport patterns over a 2‐month period. Third, a remote‐sensing technique for the identification of fetch distance, a saltation impact sensor (Safire) and wind data were utilized to gauge, qualitatively, sediment transport patterns over a 1‐month period. Secondary airflow effects were found to play a major role in the sediment flux patterns at these timescales, with measured and predicted rates matching closely during the trench trap study. The results suggest that fetch distance is an unimportant variable at this site. Copyright © 2007 John Wiley & Sons, Ltd.     

The association of potassic trachytes and carbonatites at the Dicker Willem Complex, southwest Namibia: coexisting, immiscible, but not cogenetic magmas

The only significant silicate intrusive rock type in the Dicker Willem carbonatite complex is trachyte, forming, in places, an anastomosing array of minor intrusions cutting basement gneiss close to the carbonatite contact. Bodies are predominantly composite breccias, composed of trachyte clasts, commonly in the form of ellipsoidal pellets, enclosed within, and sharply delineated from, a matrix of carbonatite. Despite close temporal and spatial relationships to carbonatite magmatism, the ultrapotassic, quartz-normative composition and isotope systematics of the trachytes preclude any genetic derivation from the carbonatitic and ijolitic rocks of the central complex. Sr, Nd and Pb isotope ratios of trachytes strongly resemble those of the highest grade, potassic fenites, whose metasomatic trend converges from the unaltered basement gneiss towards the homogeneous signature of the nepheline sövite–sövite–ijolite suite. Trachytes are interpreted as forming by melting of a cupola of high-grade fenite in response to the advective heat flux from rising carbonatite magma or fluid. Mixed carbonatite and trachyte were emplaced in a fluidised system as contemporaneous, but genetically unrelated, immiscible magmas.     

SEDIMENT RETENTION AND WATER QUALITY ENHANCEMENT IN DISTURBED WATERSHEDS

lPRoBLEMSTATEMENTANDOVERVIEWQualitywateriswithoutdoubtalimitingsubstance,notonlyforhumansbutforalllife.Yet,ashumanpopulation,activity,andpollutioncontinuetoincrease,naturalsourcesofreadilyuseablewateraredecliningatanalarmingfate.Humanscurrentlydiveftorregulatemorethanhalfofgloballyavailablefreshwaterrunofffortheirownpurposes(Posteletal.,l996),includingtheuseoflargedamsordiversionsonriversandthewidespreadcreationofotherartificialcatchments.Additionally,groundwatersourcesarebecomingin…     

Pigmentation of massive corals as a simple bioindicator for marine water quality

Photo-acclimatisation by the algal endosymbionts of scleractinian corals to changes in environmental conditions may influence their density and/or the concentration of photosynthetic pigments, and hence coral brightness, on short time-scales. To examine coral pigmentation as a bioindicator of water quality, the brightness of massive corals was quantified using colour charts, concentrations of the pigment chlorophyll a and reflectance spectrometry in the field and with manipulative experiments. Along a water quality gradient, massive Porites became progressively lighter as nutrients decreased and irradiance increased. A laboratory experiment showed that Porites nubbins darkened within 25 days following exposure to reduced water quality. The results of a transplantation experiment of Porites nubbins in a manipulation incorporating multiple depths and zones of water quality confirmed colony brightness as a simple tool to monitor changes in marine water quality, provided effects due to other influences on pigmentation, e.g. seawater temperatures, are taken into consideration.     

Setting limits for acceptable change in sediment particle size composition following marine aggregate dredging

In the UK, Government policy requires marine aggregate extraction companies to leave the seabed in a similar physical condition after the cessation of dredging. This measure is intended to promote recovery, and the return of a similar faunal community to that which existed before dredging. Whilst the policy is sensible, and in line with the principles of sustainable development, the use of the word 'similar' is open to interpretation. There is, therefore, a need to set quantifiable limits for acceptable change in sediment composition. Using a case study site, it is shown how such limits could be defined by the range of sediment particle size composition naturally found in association with the faunal assemblages in the wider region. Whilst the approach offers a number of advantages over the present system, further testing would be required before it could be recommended for use in the regulatory context.