Dissolved nitrous oxide (N2O) dynamics in agricultural field drains and headwater streams in an intensive arable catchment

Indirect nitrous oxide (N₂O) emissions produced by nitrogen (N) leaching into surface water and groundwater bodies are poorly understood in comparison to direct N₂O emissions from soils. In this study, dissolved N₂O concentrations were measured weekly in both lowland headwater streams and subsurface agricultural field drain discharges over a 2‐year period (2013–2015) in an intensive arable catchment, Norfolk, UK. All field drain and stream water samples were found to have dissolved N₂O concentrations higher than the water–air equilibrium concentration, illustrating that all sites were acting as a net source of N₂O emissions to the atmosphere. Soil texture was found to significantly influence field drain N₂O dynamics, with mean concentrations from drains in clay loam soils (5.3 μg N L^?1) being greater than drains in sandy loam soils (4.0 μg N L^?1). Soil texture also impacted upon the relationships between field drain N₂O concentrations and other water quality parameters (pH, flow rate, and nitrate (NO₃) and nitrite (NO₂) concentrations), highlighting possible differences in N₂O production mechanisms in different soil types. Catchment antecedent moisture conditions influenced the storm event mobilisation of N₂O in both field drains and streams, with the greatest concentration increases recorded during precipitation events preceded by prolonged wet conditions. N₂O concentrations also varied seasonally, with the lowest mean concentrations typically occurring during the summer months (JJA). Nitrogen fertiliser application rates and different soil inversion regimes were found to have no effect on dissolved N₂O concentrations, whereas higher N₂O concentrations recorded in field drains under a winter cover crop compared to fallow fields revealed cover crops are an ineffective greenhouse gas emission mitigation strategy. Overall, this study highlights the complex interactions governing the dynamics of dissolved N₂O concentrations in field drains and headwater streams in a lowland intensive agricultural catchment.     

An experimental study of amphibole stability in low-pressure granitic magmas and a revised Al-in-hornblende geobarometer

We report new experimental data on the composition of magmatic amphiboles synthesised from a variety of granite (sensu lato) bulk compositions at near-solidus temperatures and pressures of 0.8–10 kbar. The total aluminium content (Al^tot) of the synthetic calcic amphiboles varies systematically with pressure (P), although the relationship is nonlinear at low pressures (<2.5 kbar). At higher pressures, the relationship resembles that of other experimental studies, which suggests of a general relationship between Al^tot and P that is relatively insensitive to bulk composition. We have developed a new Al-in-hornblende geobarometer that is applicable to granitic rocks with the low-variance mineral assemblage: amphibole + plagioclase (An_15–80) + biotite + quartz + alkali feldspar + ilmenite/titanite + magnetite + apatite. Amphibole analyses should be taken from the rims of grains, in contact with plagioclase and in apparent textural equilibrium with the rest of the mineral assemblage at temperatures close to the haplogranite solidus (725 ± 75 °C), as determined from amphibole–plagioclase thermometry. Mean amphibole rim compositions that meet these criteria can then be used to calculate P (in kbar) from Al^tot (in atoms per formula unit, apfu) according to the expression:

$${\textit{P }}\left( {\text{kbar}} \right) = 0.5 + 0.331\left( 8 \right) \times {\text{Al}}^{\text{tot}} + 0.995\left( 4 \right) \times \left( {{\text{Al}}^{\text{tot}} } \right)^{2}$$

This expression recovers equilibration pressures of our calibrant dataset, comprising both new and published experimental and natural data, to within ±16 % relative uncertainty. An uncertainty of 10 % relative for a typical Al^tot value of 1.5 apfu translates to an uncertainty in pressure estimate of 0.5 kbar, or 15 % relative. Thus the accuracy of the barometer expression is comparable to the precision with which near-solidus amphibole rim composition can be characterised.

     

Toxic metals in a highly urbanized industry-impacted estuary (Bahia Blanca Estuary,Argentina): spatio-temporal analysis based on GIS

Cadmium, chromium, nickel, and lead were evaluated in the particulate fraction at one of the most industrialized estuaries at the Southwestern Atlantic Ocean, through Geographic Information System (GIS). Concentrations were analyzed at 21 stations during 2008–2010. The highest metal concentrations (Cd: 8,9; Cr: 256,49; Ni: 27,02; Pb: 78,43 µg g^??1 d. w.) were recorded at the stations located near industrial and urban discharges situated along the estuary. In addition, Pb presented a different seasonal and spatial behavior in comparison with Cd, Cr and Ni. Winter and spring presented the higher concentrations of Pb, and the inner stations presented the higher values. The estuary is considered a moderate to strongly polluted and significantly polluted according to the Index of geoaccumulation (I_geo) and the Enrichment Factor of Cd, respectively. The Multidimensional Scaling plot showed three groups of stations: the inner, associated to low levels of metals (G1), middle stations (G2) with intermediate levels and the outer (G3) with the highest ones. In addition, this work reveals the usefulness of the GIS-mapping techniques in the distribution of pollutants along an estuarine environment and the environmental quality assessment of estuarine systems.     

Socioeconomic vulnerability and electric power restoration timelines in Florida: the case of Hurricane Irma

Large-scale damage to the power infrastructure from hurricanes and high-wind events can have devastating ripple effects on infrastructure, the broader economy, households, communities, and regions. Using Hurricane Irma’s impact on Florida as a case study, we examined: (1) differences in electric power outages and restoration rates between urban and rural counties; (2) the duration of electric power outages in counties exposed to tropical storm force winds versus hurricane Category 1 force winds; and (3) the relationship between the duration of power outage and socioeconomic vulnerability. We used power outage data for the period September 9, 2017–September 29, 2017. At the peak of the power outages following Hurricane Irma, over 36% of all accounts in Florida were without electricity. We found that the rural counties, predominantly served by rural electric cooperatives and municipally owned utilities, experienced longer power outages and much slower and uneven restoration times. Results of three spatial lag models show that large percentages of customers served by rural electric cooperatives and municipally owned utilities were a strong predictor of the duration of extended power outages. There was also a strong positive association across all three models between power outage duration and urban/rural county designation. Finally, there is positive spatial dependence between power outages and several social vulnerability indicators. Three socioeconomic variables found to be statistically significant highlight three different aspects of vulnerability to power outages: minority groups, population with sensory, physical and mental disability, and economic vulnerability expressed as unemployment rate. The findings from our study have broader planning and policy relevance beyond our case study area, and highlight the need for additional research to deepen our understanding of how power restoration after hurricanes contributes to and is impacted by the socioeconomic vulnerabilities of communities.     

New observations and transit solutions of the inflated exoplanets HAT-P-40b and HAT-P-51b

We present high-precision photometric observations of the transiting exoplanets HAT-P-40 b and HAT-P-51 b by the Rozhen 2-m telescope.The newly-observed transit of HAT-P-40 b is the first one with a complete curve.The orbital periods of the two targets were improved.We modeled the observed transits and found bigger stellar radii than those derived from the stellar models.The planet radii of HATP-40 b and HAT-P-51 b obtained from our transit solutions are bigger than the values calculated by the empirical relations for Jupiter-mass and Saturn-mass planets respectively.Their values reveal the highlyinflated nature of the two targets,especially that of HAT-P-51 b.We established that the best transit solutions correspond to a quadratic limb-darkening law.The fitted limb-darkening coefficients of HAT-P-40 are close to the theoretical ones while those of HAT-P-51 are a little different.The precise astrometric Gaia distances of the two targets are smaller by 6%–7%than the calculated values from the stellar models.We propose the Gaia distances to be used for improvement of the stellar models as well as for more reliable calculation of the parameters of the known exoplanets.     

Managing by principle: A critical analysis of the European principles of Integrated Coastal Zone Management (ICZM)

A set of eight principles is contained in the European Recommendation on Integrated Coastal Zone Management. The principles have been adopted with the minimum of critical review. The six core principles form two groups, one concerned with strategic goals and one that has a local focus. The principles are presented as a menu of free-standing options, with no prioritization either within or between groups. This can produce irreconcilable differences in strategy. The principles require clarification, prioritization of the strategic principles and recognition that they are an indivisible integrated set which should not be used to select principles to advance a particular agenda.     

NSVS 2569022:a peculiar binary among W UMa stars with extremely small mass ratios

Photometric observations of the W UMa binary NSVS 2569022 are presented. The light curve solution reveals that both components are of F spectral type(temperatures T_1= T_2= 6100 K). NSVS2569022 undergoes a total eclipse of W subtype and the mass ratio is well-determined. Its extremely small value of only 0.077 implies that the target will probably experience instability and a possible merger. This value ranks NSVS 2569022 in sixth place among binaries with the smallest mass ratio.Based on an empirical relation of "period – total mass" for low mass-ratio binaries, we estimate the global parameters of NSVS 2569022: masses M_1= 1.17 M⊙and M_2= 0.09 M⊙; radii R_1= 1.19 R⊙and R_2= 0.38 R⊙; luminosities L_1= 1.73 L⊙and L_2= 0.17 L⊙. An analysis of the characteristics of binaries with extremely low-mass ratios is made. NSVS 2569022 turns out to be a peculiar binary among W UMa stars with extremely small mass ratios due to its unexpectedly small fill-out factor of only 0.014(slightly overcontact configuration).     

Characterization of chromophoric dissolved organic matter (CDOM) in the Baltic Sea by excitation emission matrix fluorescence spectroscopy

Chromophoric dissolved organic matter (CDOM) is the major light absorber in the Baltic Sea. In this study, excitation emission matrix (EEM) fluorescence spectra and UV–visible absorption spectra of CDOM are reported as a function of salinity. Samples from different locations and over different seasons were collected during four cruises in 2002 and 2003 in the Baltic Sea in both Pomeranian Bay and the Gulf of Gdansk. Absorption by CDOM decreased with increased distance from the riverine source and reached a relatively stable absorption background in the open sea. Regression analysis showed that fluorescence intensity was linearly related to absorption by CDOM at 375 nm and a_CDOM(375) absorption coefficients were inversely related to salinity. Analysis of CDOM-EEM spectra indicated that a change in composition of CDOM occurred along the salinity gradient in the Baltic Sea. Analysis of percent contribution of respective fluorophore groups to the total intensity of EEM spectra indicated that the fluorescence peaks associated with terrestrial humic components of the CDOM and total integrated fluorescence decreased with decreasing CDOM absorption. In contrast, the protein-like fraction of CDOM decreased to a lesser degree than the others. Analysis of the percent contribution of fluorescence peak intensities to the total fluorescence along the salinity gradient showed that the contribution of protein-like fluorophores increased from 2.6% to 5.1% in the high-salinity region of the transect. Fluorescence and absorption changes observed in the Baltic Sea were similar to those observed in similar transects that have been sampled elsewhere, e.g. in European estuaries, Gulf of Mexico, Mid-Atlantic Bight and the Cape Fear River plume in the South Atlantic Bight, although the changes in the Baltic Sea occurred over a much smaller salinity gradient.     

Limpets as prey: Lipophrys pholis choice for size

Patellid limpets are key species on rocky shores, structuring intertidal assemblages through their grazing. Their role as prey for fish is, however, often overlooked in studies of intertidal ecosystem functioning. The shanny Lipophrys pholis is a common predator of limpets on rocky shores in Northern Europe and, in this study, we examined the characteristics of its predation on limpets based on prey size. The limpet size range that adult L. pholis (10–12.5 cm) can eat was examined in the laboratory using Patella depressa in 0.2 cm classes, varying between 0.5 cm and 3.0 cm in maximum shell length. There was a limpet size refuge above 1.8 cm, while all smaller sizes were readily consumed by the shanny. The predator attacking behaviour was also examined and found to vary with prey size. Limpets up to 0.8 cm were crushed by the jaw‐constricting force and eaten whole, whereas larger prey were prised from the substratum and the body subsequently separated from the shell. To examine whether there was a L. pholis preference for P. depressa size, a two‐stage laboratory experiment was done using two size classes defined as small (0.7–0.8 cm maximum shell length) and large (1.5–1.6 cm maximum shell length). In the first stage, the predator was given each limpet size class separately. In the second stage, the fish was given a choice between the two classes. Lipophrys pholis was shown to have a preference for the large size class (1.5–1.6 cm). The average number of limpets consumed by the shanny was examined for the duration of one high‐tide typical of the central region of Portugal (≈ 4 h). On average, approximately five limpets (up to an eight limpet maximum) were consumed. The present study shows that L. pholis has a feeding preference based on limpet size, which suggests that the limpet population structure and intra‐ and inter‐specific interactions may be influenced by the shanny predation.     

How U.S. ocean policy and market power can reform the coral reef wildlife trade

As the world’s largest importer of marine ornamental species for the aquaria, curio, home décor, and jewelry industries, the United States has an opportunity to leverage its considerable market power to promote more sustainable trade and reduce the effects of ornamental trade stress on coral reefs worldwide. Evidence indicates that collection of some coral reef animals for these trades has caused virtual elimination of local populations, major changes in age structure, and promotion of collection practices that destroy reef habitats. Management and enforcement of collection activities in major source countries such as Indonesia and the Philippines remain weak. Strengthening US trade laws and enforcement capabilities combined with increasing consumer and industry demand for responsible conservation can create strong incentives for improving management in source countries. This is particularly important in light of the March 2010 failure of the parties to the Convention on International Trade in Endangered Species (CITES) to take action on key groups of corals.