柴达木盆地北缘中、新生代构造演化探讨

本文通过近年来的地震反射信息研究,对柴达木盆地北缘中、新生代地质构造演化进行了分析,透过红山地区这个窗口,揭示柴达木盆地内中、新生代两个世代的构造成因类型,展示二者叠置关系和构造样式,认为该区存在先张后压的演化历史,且后期挤压作用破坏和改造早期拉张构造样式,从而更有效地指导盆地中生代油气藏的勘探。     

岩溶铅锌矿区土壤重金属污染特征

以DX、DW铅锌矿区土壤为研究对象,利用原子吸收光谱法（AA800）、原子荧光光谱法（AF-640）测定土壤中铅、铬、镉、铜、锌、镍、汞和砷等重金属的含量,利用单因子污染指数法、N.L.Nemerow综合污染指数法对比分析土壤中重金属的污染特征,采用PCC统计学方法分析矿区土壤中重金属之间的相关性。结果表明:两矿区土壤中除Cu、Cr外,其余重金属均已对土壤造成单一或复合污染,其中Cd污染最为严重,对综合污染贡献最大。DX、DW矿区土壤重金属的Nemerow指数分别为27.61、63.54,均达到极强污染水平,且DW矿区污染较为严重。DX矿区,除Ni外,Pb、Cr等7种重金属元素之间存相关性;DW矿区,除Cr外,Pb、Ni等7种重金属元素之间存相关性,这可能与二矿区均属多金属伴生、共生矿床有关;土壤中各重金属总含量与pH值没有显著的相关性。研究结果将为合理制定矿区土壤污染的修复和治理措施提供依据。      

Mantle source heterogeneity in the Campanian Region (South Italy) as inferred from geochemical and isotopic features of mafic volcanic rocks with shoshonitic affinity

Summary Major, trace element and Sr-Nd-isotopic data on mafic volcanic rocks with shoshonitic affinity from the islands of Procida and Ventotene (Campanian Region, South Italy) are reported. Within-suite chemical and isotopic variations are interpreted in terms of open system differentiation processes held responsible for enrichment in a number of trace elements and for radiogenic Sr observed in both Procida and Ventotene volcanic sequences. Conversely, trace element contents and Sr-Nd-isotopic compositions of the least-evolved among the investigated samples are thought to reflect source region characteristics with only negligible crustal contamination of the primary magmas.The data support an origin from distinct source regions for the primary magmas. In the case of Ventotene, the source would have been asthenospheric and/or lithospheric mantle with features similar to transitional mid-ocean ridge basalts (T-MORB), modified by enriching agents made up mainly of subducted slab-released components coming from marly sediments (about 7%) similar to cherts from Tuscan Apennines plus a limestone contribution. In the case of Procida, the source would have been asthenospheric and/or lithospheric mantle with a slightly more enriched T-MORB-like feature with respect to Ventotene, modified by slab-derived enriching agents, likely represented by a small amount of sediments (about 2.5%) of oceanic nature (mostly terrigenous/pelagic). These differences are constrained by lower Zr/Nb, Y/Nb, Sc/Nb, V/Nb, LILE/HFSE, LREE/HFSE and⁸⁷Sr/⁸⁶Sr, higher Ba/La and¹⁴³Nd/¹⁴⁴Nd ratios, as well as by the lack of a detectable negative Eu anomaly, in the least-evolved volcanic rocks of Procida, with respect to those of Ventotene, which show conversely a significant negative Eu anomaly. Thus, a sharp heterogeneity exists in the mantle beneath the Campanian Region. It is thought to be the consequence of two different slabs which are in contact along the Volturno River Plain tectonic line: a continental slab, seismically inactive, descending beneath the Latium Region, and an oceanic slab, seismically active, descending beneath the Calabria, up to the Campanian Region.

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Résumé De nouvelles analyses géochimiques d'éléments majeurs et en traces ainsi que des rapports isotopiques du Sr et du Nd sont été obtenues sur des roches volcaniques mafiques à affinité shoshonitiques provenant des îles de Procida et Ventotene (Région Campanienne, Italie du Sud). Les variations géochimiques et isotopiques observées au sein des séries volcaniques de ces deux îles sont interprétées en terme de processus de différenciation en système ouvert, tenu pour responsable d'un enrichissement d'un certain nombre d'éléments en traces et de leur composition en Sr radiogénique. Cependant, les teneurs en éléments traces et les compositions isotopiques en Sr et Nd des échantillons les moins évolués parmi ceux étudiés reflètent les caractéristiques de leur source, avec une contamination crustale très négligeable des magmas primitifs.Ces données démontrent que des sources distinctes sont à l'origine des magmas primitifs. Pour Ventotene, cette source doit être un manteau asthénosphérique et/ou lithosphérique dont la signature est similaire à celle de basaltes transitionnels de dorsale océanique (T MORB), légèrement enrichie en éléments dérivants d'une croûte plongeant dans une subduction comme des sédiments mameux (pour environ 7%) analogues aux cherts des Appenins de Toscane et comportant un apport en calcaire. Dans le cas de Procida, cette source doit être un manteau asthénosphérique et/ou lithosphérique montrant une signature de type T-MORB légèrement plus enrichie qu' à Ventotene, également modifiée par un apport venant d'une croûte en subduction, probablement une faible quantité (environ 2.5%) de sédiments de nature océanique (principalement terrigène/pélagique). Ces différences sont attestées par des rapports Zr/Nb, Y/Nb, Sc/Nb, V/Nb, LILE/HFSE, LREE/HSFE and⁸⁷Sr/⁸⁶Sr plus bas et des rapports Ba/La et¹⁴³Nd/¹⁴⁴Nd plus harts, ainsi que par l'absence d'une anomalie en Eu dans les compositions des roches volcaniques les moins évoluées de Procida par rapport à celles de Ventotene, qui elles, au contraire, montrent une anomalie en Eu significative.Ainsi, une importante hétérogénéité du manteau existe sous la Campanie. Cette hétérogénéité doit être la conséquence de la nature différente des croûtes en subduction et qui sont en contact le long de la ligne tectonique de la plaine de la rivière Volturno: an Nord-Ouest, une croûte continentale, sismiquement inactive, plonge sous le Latium alors qu'au Sud-Est, une croûte océanique, sismiquement active, plonge sous la Calabre et jusque sous la Campanie.

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With 9 Figures     

关于火山岩型铀矿床成矿规律中一些问题的讨论

火山岩型铀矿常位于大的地质构造单元界线附近,特别是稳定区与活动区之间的过渡带上。矿区的基底不仅需有较高的成熟度而且是在火山岩形成前或长期处于隆起状态者。负向火山构造,上叠式或拗凸型上叠式火盆是铀矿田的有利构造形式。红盆对成矿的作用不是古气候方面的而是构造方面的。火山岩型铀矿成矿深度可以较大,而且在垂向上不只一个富集高峰。铀及其主要伴生组份不是来源于赋矿围岩,而是来自基底或更深处。     

The effects of soil sand contents on characteristics of humic acids along soil profiles

It is generally accepted that the compositions and properties of soil organic matter (SOM) are influenced by many factors. In order to reveal the effects of soil texture on characteristics and dynamics of SOM and its sub-fraction, humic acid (HA), along two soil profiles, a yellow soil profile and a purplish soil profile, under the same climate and vegetation conditions were determined. Results indicate that the decomposition and humification degrees of SOM and HA of the purplish soils are higher than those of the corresponding yellow soils indicated by A/O–A ratios of HAs, TOCs and HA yields of bulk soil samples, nevertheless, the development degree of the purplish soil is lower than that of the yellow soil. The variations of E₄/E₆ ratios of HAs along the soil profiles indicate the overall molecular sizes of HAs decreased downward along the soil profiles. A/O–A ratios of HAs decreased downward along both the soil profiles indicate that humification processes decrease downward along both the soil profiles. Leaching of SOM shows significant effects on the distribution and characteristics of HAs in the yellow soil profile but the purplish soil profile, which is consistent with the higher hydrophobicity of HAs in purplish soils, shows that the distribution characteristics of SOM along the soil profiles are a complex result of the combination of soil texture and characteristics of SOM itself. The remarkably different sand contents are concluded tentatively as one of reasons to the different distributions and dynamics of HAs along the soil profiles, however, to profoundly understand the evolution and transport of SOM along soil profiles needs more researches.     

巴布亚新几内亚奥克泰迪铜金矿床成矿特征和控制因素

巴布亚新几内亚西部Fubilan山奥克泰迪矿床是一个世界级铜金矿床,在大地构造上位于新几内亚造山带的巴布亚褶皱带。该矿床的铜金矿化赋存于Fubilan二长斑岩及其周边的磁铁矿夕卡岩和硫化物夕卡岩中。矿石类型以原生硫化物矿石为主,金属矿物包括磁铁矿、黄铁矿、磁黄铁矿、白铁矿、黄铜矿、斑铜矿等。蚀变类型包括夕卡岩化、钾化、泥化和青盘岩化。矿床氧化次生富集带发育,表生矿石矿物为蓝辉铜矿、辉铜矿、自然铜、铜蓝和银金矿。成矿作用主要受区域构造、侵入杂岩体、Darai组灰岩地层、断裂等因素的控制。根据矿床的主岩、矿石特征、蚀变特征和控矿因素,认为该矿床成因类型属于较为典型的夕卡岩—斑岩型矿床。     

Spectroscopic analysis (FTIR, Raman) of water in mafic and intermediate glasses and glass inclusions

Micro-Raman spectroscopy, even though a very promising technique, is not still routinely applied to analyse H₂O in silicate glasses. The accuracy of Raman water determinations critically depends on the capability to predict and take into account both the matrix effects (bulk glass composition) and the analytical conditions on band intensities. On the other hand, micro-Fourier transform infrared spectroscopy is commonly used to measure the hydrous absorbing species (e.g., hydroxyl OH⁻ and molecular H₂O) in natural glasses, but requires critical assumptions for the study of crystal-hosted glasses. Here, we quantify for the first time the matrix effect of Raman external calibration procedures for the quantification of the total H₂O content (H₂O_T = OH⁻ + H₂O_m) in natural silicate glasses. The procedures are based on the calibration of either the absolute (external calibration) or scaled (parameterisation) intensity of the 3550 cm⁻¹ band. A total of 67 mafic (basanite, basalt) and intermediate (andesite) glasses hosted in olivines, having between 0.2 and 4.8 wt% of H₂O, was analysed. Our new dataset demonstrates, for given water content, the height (intensity) of Raman H₂O_T band depends on glass density, reflectance and water environment. Hence this matrix effect must be considered in the quantification of H₂O by Raman spectroscopy irrespective of the procedure, whereas the parameterisation mainly helps to predict and verify the self-consistency of the Raman results. In addition, to validate the capability of the micro-Raman to accurately determine the H₂O content of multicomponent aluminosilicate glasses, a subset of 23 glasses was analysed by both micro-Raman and micro-FTIR spectroscopy using the band at 3550 cm⁻¹. We provide new FTIR absorptivity coefficients (ε₃₅₅₀) for basalt (62.80 ± 0.8 L mol⁻¹ cm⁻¹) and basanite (43.96 ± 0.6 L mol⁻¹ cm⁻¹). These values, together with an exhaustive review of literature data, confirm the non-linear decline of the FTIR absorptivity coefficient (ε₃₅₅₀) as the glass depolymerisation increases. We demonstrate the good agreement between micro-FTIR and micro-Raman determination of H₂O in silicate glasses when the matrix effects are properly considered.     

Stratigraphic features of the Maltese Archipelago: a synthesis

The present study gathers a large amount of both existing and unpublished biostratigraphic data, which allows a detailed and complete definition of the stratigraphic features of the late Oligocene–late Miocene Maltese Archipelago sedimentary succession, recording in turn the tectonic and eustatic history of the Central Mediterranean region. We selected five sections in the Malta Island and three in Gozo, representative of the entire sedimentary succession, affected by well-known erosional surfaces, correlated to low-stands of the sea level, often associated with phoshatic layers, linked to the subsequent high-stands. The sedimentary interval, and thus the associated hiatuses, was constrained both by the bio-chronostratigraphic attribution and by the comparison with the third-order succession of the New Jersey passive margin, which shows strict analogy with the geodynamic context in which the Maltese succession deposited. The diachroneity at the base of the formations in the different sections, and the presence of intraformational unconformity/hiatuses, highlighted the role of the tectonic, which depicted a complex sedimentary basin, characterized by more distal versus more marginal sectors. Furthermore, the possibility to compare the sedimentary succession with the oxygen isotope curve connects the sedimentation interruptions, recorded within the Maltese Archipelago deposits, to global cooling events.

     

长江河口及其水下三角洲晚第四纪地层和环境变迁

笔者系统地研究了长江河口地区的晚第四纪地层。长江三角洲前缘区晚第四纪地层可划分为上更新统上段中部、全新统下部、全新统中部和全新统上部。上更新统顶部地层缺失。前三角洲区晚第四纪地层齐全,无缺失。武木冰期晚期,现今的长江河口和大陆架均出露成陆,古长江在大陆架外缘入海。15000aB.P,海面上升,海水逐渐向大陆架上部侵入;12000-10000aB.P,海水沿谷地侵入;6000aB.P,长江人海口在扬州、镇江附近。随着人类活动的增强,长江流域水土流失加剧,人海河口不断外移,并以南岸边滩推展,北岸沙岛并岸的形式使河口不断束狭,逐渐形成现今长江口三级分汉四口入海的态势。