Groundwater vulnerability and risk mapping of the Hajeb-jelma aquifer (Central Tunisia) using a GIS-based DRASTIC model

The aim of this study is to elaborate a synthetic document for the assessment of groundwater vulnerability to pollution in the Hajeb-Jelma aquifer. The specific object is to incorporate the Geographical Information System (GIS) to generate groundwater vulnerability and risk maps with DRASTIC model. Indeed, GIS could help to make the results of a complicated model more clear through visual representation, providing an applicable tool for decision makers. The vulnerability map of Hajeb-Jelma watershed shows three classes: moderate, high and very high depending on the intrinsic properties. The risk map shows a very high risk dependant on hydrogeological characteristics, land use and human impacts in major part of the Hajeb-Jelma region. These maps could serve as a scientific basis for sustainable land use planning and groundwater management in the Hajeb-Jelma region.     

Active crustal shortening in NE Syria revealed by deformed terraces of the River Euphrates

The Africa–Arabia plate boundary comprises the Red Sea oceanic spreading centre and the left‐lateral Dead Sea Fault Zone (DSFZ); however, previous work has indicated kinematic inconsistency between its continental and oceanic parts. The Palmyra Fold Belt (PFB) splays ENE from the DSFZ in SW Syria and persists for ～400 km to the River Euphrates, but its significance within the regional pattern of active crustal deformation has hitherto been unclear. We report deformation of Euphrates terraces consistent with Quaternary right‐lateral transpression within the PFB, indicating anticlockwise rotation (estimated as 0.3° Ma^?1 about 36.0°N 39.8°E) of the block between the PFB and the northern DSFZ relative to the Arabian Plate interior. The northern DSFZ is shown to be kinematically consistent with the combination of Euler vectors for the PFB and the Red Sea spreading, resolving the inconsistency previously evident. The SW PFB causes a significant earthquake hazard, previously unrecognized, to the city of Damascus.     

Calibration of the Hydrological Simulation Program Fortran (HSPF) model using automatic calibration and geographical information systems

Calibrating a comprehensive, multi‐parameter conceptual hydrological model, such as the Hydrological Simulation Program Fortran model, is a major challenge. This paper describes calibration procedures for water‐quantity parameters of the HSPF version 10·11 using the automatic‐calibration parameter estimator model coupled with a geographical information system (GIS) approach for spatially averaged properties. The study area was the Grand River watershed, located in southern Ontario, Canada, between 79° 30′ and 80° 57′W longitude and 42° 51′ and 44° 31′N latitude. The drainage area is 6965 km². Calibration efforts were directed to those model parameters that produced large changes in model response during sensitivity tests run prior to undertaking calibration. A GIS was used extensively in this study. It was first used in the watershed segmentation process. During calibration, the GIS data were used to establish realistic starting values for the surface and subsurface zone parameters LZSN, UZSN, COVER, and INFILT and physically reasonable ratios of these parameters among watersheds were preserved during calibration with the ratios based on the known properties of the subwatersheds determined using GIS. This calibration procedure produced very satisfactory results; the percentage difference between the simulated and the measured yearly discharge ranged between 4 to 16%, which is classified as good to very good calibration. The average simulated daily discharge for the watershed outlet at Brantford for the years 1981–85 was 67 m³ s^?1 and the average measured discharge at Brantford was 70 m³ s^?1. The coupling of a GIS with automatice calibration produced a realistic and accurate calibration for the HSPF model with much less effort and subjectivity than would be required for unassisted calibration. Copyright © 2002 John Wiley & Sons, Ltd.     

An Interacting Model of Dark Energy in Brans-Dicke Theory

In this paper it is shown that in non-minimally coupled Brans-Dicke theory containing a self-interacting potential, a suitable conformal transformation can automatically give rise to an interaction between the normal matter and the Brans-Dicke scalar field. Considering the scalar field in the Einstein frame as the quintessence matter, it has been shown that such a non-minimal coupling between the matter and the scalar field can give rise to a late time accelerated expansion for the universe preceded by a decelerated expansion for very high values of the Brans-Dicke parameter ω. We have also studied the observational constraints on the model parameters considering the Hubble and Supernova data.     

Heavy metals removal from synthetic wastewater by a novel nano-size composite adsorbent

The effects of varying operating conditions on metals removal from aqueous solution using a novel nano-size composite adsorbent are reported in this paper. Characterization of the composite adsorbent material showed successful production of carbon nanotubes on granular activated carbon using 1 % nickel as catalyst. In the laboratory adsorption experiment, initial mixed metals concentration of 2.0 mg/L Cu²⁺, 1.5 mg/L Pb²⁺ and 0.8 mg/L Ni²⁺ were synthesized based on metals concentration from samples collected from a semiconductor industry effluent. The effects of operation conditions on metals removal using composite adsorbent were investigated. Experimental conditions resulting in optimal metals adsorption were observed at pH 5, 1 g/L dosage and 60 min contact time. It was noted that the percentage of metals removal at the equilibrium condition varied for each metal, with lead recording 99 %, copper 61 % and nickel 20 %, giving metal affinity trend of Pb²⁺ > Cu²⁺ > Ni²⁺ on the adsorbent. Langmuir’s adsorption isotherm model gave a higher R² value of 0.93, 0.89 and 0.986 for copper, nickel and lead, respectively, over that of Freundlich model during the adsorption process of the three metals in matrix solution.     

Peculiarities of the kinematics of the west scotia mid-oceanic ridge

The first map of the acoustic basement and a new map of the C⁴-C¹² chrons are made for the area of the paleospreading West Scotia Ridge. The analysis of the constructed maps and the calculations showed that the bottom growth in the ridge axes began in the southeast in the interval of chron C^12r (31.116–33.266 Ma B.P.). In the period of chron C11r (30.217–30.627 Ma), a hundred-kilometer northwestward jump of the spreading axis occurred. The maximal values of the bottom growth (about 6.3 cm/yr) were in the interval of chrons C6–C6B (18.748–22.546 Ma); then, the spreading began to fade. In the time of chron C3n.1r (3.300–4.493 Ma B.P.), the axis of the paleo-mid-oceanic ridge died. The spreading was accompanied with northeastward propagating of the axes, and the propagating proper had an impulse character.     

The separation of Ceylon from Antarctica

The geometry of the junction between Ceylon and Antarctica during the Gondwanaland breakup is still under discussion. Analysis of the available geological-geophysical materials has allowed the peculiarities of Ceylon separation from Antarctica to be characterized, the new paleogeodynamical reconstruction to be elaborated, and a prognosis of the tectonic structure and mineral resources in the areas of Antarctic coast that were adjacent to Ceylon to be made.     

Deep electromagnetic (MT and AMT) sounding of the suture zones of the Ukrainian shield

The article discusses the results of deep magnetotelluric sounding of suture zones in the Precambrian structures of the Ukrainian shield in the context of collisional settings. All the considered suture zones (Orekhovo-Pavlograd, West Ingulets-Krivoi Rog, Golovanevsk-Yadlov-Traktemir, Nemirov-Kocherov or Brusilov) are associated with the regional anomalies of increased electric conductivity, which mark deep fault zones and characterize collisional settings. The nature of such deep anomalies might be due to the transport of the ore components together with the fluids from the crust and the mantle during the tectonomagmatic activation, which offers the possibility to predict the prospective areas of endogenic mineralization. A correlation has been established between the endogenic ore deposits located close to or within the suture zones and the low-resistivity anomalies.     

Towards hydrological triggering mechanisms of large deep-seated landslides

It is a widely accepted idea that hydrologically triggered deep-seated landslides are initiated by an increase in pore-water pressure on potential slip surface induced by rising groundwater level after prolonged period of intense rainfall although the process is not fully understood. In order to contribute to better understanding, the rainfall–groundwater relationships, hydrogeological monitoring and repeated geoelectrical imaging were carried out from March 2007 to April 2011 in large deep-seated landslide near ?ubietová (Western Carpathians) catastrophically reactivated at the end of February 1977. Based on our observations, groundwater level (GWL) response to precipitation differs considerably with respect to both overall hydrological conditions and GWL mean depth. While the rate of GWL increase up to 25 cm/day were measured after some rainfall events during wet periods, noticeably lower recharge rate (up to 1–2 cm/day) and delayed GWL response to rainfall (usually from 2 weeks to 2–4 months) were observed at the beginning of the wet season after considerable depression of GWLs due to previous effective rainfall deficit. Likewise, slow GWL fluctuations without short-term oscillations are typical for deeper GWLs. Thus, long-term (several seasons to several years) hydrological conditions affect markedly groundwater response to rainfall events in the studied landslide and can be crucial for its behaviour. Comparison of hydrological conditions characterising the analysed period with those that accompanied the landslide reactivation in 1977 allow us to assume that slightly above-average rainy season following the prolonged wet period can be far more responsible for movement acceleration (and possibly failure initiation) in deep landslides than the isolated season of extreme precipitation following a longer dry period. This is true especially for landslides in regions with significant seasonal temperature changes where potential effective precipitation (PEP), calculated as excess of precipitation (P) over potential evapotranspiration (PET), may be efficiently used for estimation of slope saturation condition.