Silver and lead in high-altitude lake sediments: Proxies for climate changes and human activities

High-altitude lake sediments are often used as archives for environmental changes and their chemical and isotopic compositions provide significant constraints on natural and anthropogenic long-term changes that have occurred in their catchment area. Here, trace-element concentrations and Pb isotopes are presented for two sedimentary cores from Lake Blanc Huez in the French Alps, to trace the impact of climate changes and human activities over the Holocene. Lead and Ag contents are very high and clearly dominated by input from a Pb–Ag vein located a few meters from the lakeshore, a vein that also buffers the Pb isotopes. Mining of this vein in medieval times is recorded in the corresponding lake sediments with high Ag content coupled with high Pb/U ratio. These chemical characteristics can be used to constrain the major Holocene climate changes. Significant advances of glaciers next to the lake produced sediments with Ag and Pb concentration peaks and high Pb/U ratios due to accelerated erosion of the Pb–Ag vein, similar to the effects of the medieval mining. In contrast, reduced glacier activity led to the formation of organic-rich sediments with high U and As contents and low Pb/U ratios. More generally, the observed combination of chemical changes could be used elsewhere to decipher environmental changes over long periods of time.     

GIS derived synthetic rating curves and HAND model to support on-the-fly flood mapping

Natural Hazards - Acknowledging the devastating consequences of past earthquakes, current research efforts focus on the development of tools for assessing and controlling the risk and losses...     

Les vertébrés continentaux de l’Adrar Mgorn (Maroc,Paléocène); une dispersion de mammifères transtéthysienne aux environs de la limite mésozoïque/ cénozoïque ?

Résumé

— Le gisement paléocène sud-marocain de l’Adrar Mgorn recèle les plus anciens Mammifères placentaires africains, dont la plupart sont les premiers reconnus dans le domaine sud-téthysien. L’identification, parmi eux, d’« Insectivores » paléoryctidés, très proches des genres strictement nord-américains Cimolestes et Palaeoryctes (Crétacé supérieur et/ou Paléocène), suggère une liaison par voie continentale des domaines nord-américain et africain autour de la limite Crétacé supérieur/Tertiaire. Celle-ci suppose une traversée transtéthysienne dont nous discutons les possibilités à la lumière des données paléogéographiques.     

Interfacial energy effects and the evolution of pore size distributions during quartz precipitation in sandstone

Pore size is usually thought to control the rate of crystal growth in porous geological media by determining the ratio of mineral surface area to fluid volume. However, theory suggests that in micron-scale to nanometer scale pores, interfacial energy (surface energy) effects can also become important. Interfacial energy typically increases the solubility of very small crystals growing in tiny pores, and when the fluid is close to equilibrium - as is often the case in geological systems - mineral precipitation could occur in relatively large pores, while in very small adjacent pores crystal growth might be suppressed. Such a mechanism would effectively restrict the reactive surface area of the porous medium, thereby reducing the bulk reaction rate. We investigated the pore size distributions in naturally cemented sandstone adjacent to an isolated stylolite and found that quartz precipitation was inhibited in pores smaller than 10 μm in diameter. Furthermore, we demonstrate that kinetic formulations which assume constant solubility cannot reproduce the observed pore size patterns in mineralized samples; by contrast, excellent fits with the data are obtained when interfacial energy effects are taken into account. Reaction rates in geological media determined in field studies can be orders of magnitude lower than those measured in laboratory experiments, and we propose that reduced reaction rates in porous media with micron and submicron-scale porosity could account for much of the apparent paradox.     

Whiting-related sediment export along the Middle Miocene carbonate ramp of Great Bahama Bank

Modern aragonite needles are present all along the modern leeward margin of Great Bahama Bank (ODP Leg 166), while Middle Miocene sediments contain needles only in more distal areas (Sites 1006 and 1007). In contrast to the rimmed, flat-topped platform topography during the Plio-Pleistocene, the Miocene Great Bahama Bank morphology is a carbonate ramp profile. This might imply a different location and precipitation type for Miocene aragonite needles. In this study, aragonite needles in Miocene sediments were isolated using a granulometric separation method. Furthermore, the isolation of the various carbonate components enables the identification of primary versus diagenetic components. The Miocene aragonite needles are concentrated in the finest granulometric sediment fractions (<12 μm). The fraction-specific geochemical analyses (δ¹³C, δ¹⁸O and Sr elemental abundance) represent useful tools to assess the possible sources of the aragonite mud. The geochemical variation of the fractions, rich in pristine aragonite needles, and the characteristics of the needle morphology point to whiting phenomena as the main sediment source and algal fragmentation as a minor component. Both components indicate shallow-water environments as the main sediment source area. Ramp-top-related fine-grained particles now present at distal sites were likely exported as suspended material similar to present-day transport mechanisms. The scarcity of needles at proximal sites is probably linked to hydrodynamic processes but dissolution and recrystallization processes cannot be excluded. The granulometric separation approach applied here enables a better characterization of the finest carbonate particles representing an important step towards the discrimination between primary and diagenetic fine-grained components.     

Vulnerability of water resources in northern Cameroon in the context of climate change

Water resources in northern Cameroon have continuously been reducing over the past years. Many studies have suggested two principal causes: (1) human activities such as poor farming practices, unsustainable use of water resources, increased demand of water, deforestation, land-use change, etc., (2) human-induced climate change. Northern Cameroon in this study includes: the Adamawa, North and Far North regions located closer to the Sahel regions of Africa. These regions are already water stressed because of their location and any further change in climate with rising temperature would impact water resource either positively or negatively. Time series analysis and a 12-month standardized precipitation index (SPI12) with digital data between 1957 and 2006 were used to investigate the variation of water resources in northern Cameroon. Results obtained varies between the different regions with an increased annual trend in temperature and precipitation for Ngaoundere (Adamawa region) and Garoua (north region), whereas Maroua (far north region) had a decreased annual trend in both precipitation and temperature. Further variability results obtained from a SPI12 show that wetter period out number drought period in all three regions. The study concluded that water resources vary with the changing climatic condition and the severity of the impact varies from region to region. Furthermore, water deficiency in northern Cameroon might not be due to climate change. The reasons might be a combination of poor water management and other factors such population growth, the environmental condition, etc.     

Spatial Association of Mineral Occurrences and Curvilinear Geological Features

Qualitative and quantitative knowledge about the spatial association between mineral occurrences and geological features are important in mineral potential mapping. Two existing methods for quantifying spatial association between mineral occurrences and curvilinear geological features are applied to the Baguio district of the Philippines. An experimental method is described and applied to the study area as well. The results of the three methods are highly similar, which demonstrates the effectiveness of the experimental method presented here for quantifying spatial association between mineral occurrences and curvilinear geological features. It is shown that gold occurrence in the Baguio district are strongly spatially associated with northeasterly trending faults/fractures rather than with northwesterly trending faults/fractures. It is also shown that the spatial association between the gold occurrence and older batholithic intrusives is stronger than the spatial association between gold occurrence and younger porphyry intrusives. These spatial geoinformation characteristics can be used as evidential data layers in GIS-based mineral potential mapping.     

Incorporating fuzzy set methodologies in a DBMS repository for the application domain of GIS

It has been recently recognized that fuzzy set theory provides useful concepts and tools for both the representation and analysis of the uncertainty related to geographical data. Hence the incorporation of fuzzy set methodologies into a DBMS repository for the application domain of GIS should be beneficial and will improve its level of intelligence. Focusing in this area the paper addresses both a representation and a reasoning issue. Specifically, it extends a general spatial data model to deal with the uncertainty of geographical entities, and shows how the standard data interpretation operations available in GIS packages may be extended to support the fuzzy spatial reasoning. Representative geographical operations, suchas the fuzzy overlay, fuzzy distance and fuzzy select, are examined, while several real world examples are given.