40Ar-39Ar age determinations on the Owyhee basalt of the Columbia Plateau

⁴⁰Ar/³⁹Ar step-heating analyses have been performed on 11 samples of basalt from sites near Owyhee Reservoir of southeastern Oregon, U.S.A. These rocks were extruded during the great flood basalt episode of the Pacific Northwest. The whole-rock points are highly correlated on a plot of⁴⁰Ar/³⁶Ar versus³⁹Ar/³⁶Ar, corresponding to a common age of the samples of 14.3 ± 0.3 m.y. Inspite of this, individual “plateau” plots of the age versus fraction of³⁹Ar released do not give good plateaux. These age spectra exhibit to varying degrees a common structure in which lower age values are found at higher temperatures. This pattern may result from a closed-system redistribution of the argon isotopes. The usefulness of grinding the basalts in removing a loosely held atmospheric argon component is confirmed.     

An oceanic calcium problem?

Recent published data on dissolved calcium in seawater reveal an apparent excess of calcium over that predicted from the changes in alkalinity. In the South Pacific this excess calcium is approximately 40 μmoles/kg. We suggest that this arises from an in-situ titration of some of the alkalinity by protons derived from the redox changes associated with oxidative decomposition of organic matter. This postulates an effective flux of nitric and phosphoric acids into the deep water. Other redox changes, such as in the oxidation of reduced sulfur, may also contribute protons, but these are more difficult to evaluate. This concept changes current thinking on the oceanic CO₂-carbonate system. It increases the amount of calcium carbonate believed to have dissolved in the ocean by ca. 25%; and alters the proportions of abyssal CO₂ believed to be derived from respiration versus carbonate dissolution by about 10%.     

Rapid evolution of redox processes in a petroleum hydrocarbon-contaminated aquifer

Ground water chemistry data collected over a six-year period show that the distribution of contaminants and redox processes in a shallow petroleum hydrocarbon-contaminated aquifer has changed rapidly over time. Shortly after a gasoline release occurred in 1990, high concentrations of benzene were present near the contaminant source area. In this contaminated zone, dissolved oxygen in ground water was depleted, and by 1994 Fe(III) reduction and sulfate reduction were the predominant terminal electron accepting processes. Significantly, dissolved methane was below measurable levels in 1994, indicating the absence of significant methanogenesis. By 1996, however, depletion of solid-phase Fe(III)-oxyhydrox ides in aquifer sediments and depletion of dissolved sulfate in ground water resulted in the onset of methanogenesis. Between 1996 and 2000, water-chemistry data indicated that methanogenic metabolism became increasingly prevalent. Molecular analysis of 16S-rDNA extracted from sediments shows the presence of a more diverse methanogenic community inside as opposed to outside the plume core, and is consistent with water-chemistry data indicating a shift toward methanogenesis over time. This rapid evolution of redox processes reflects several factors including the large amounts of contaminants, relatively rapid ground water flow (approximately 0.3 m/day [approximately foot/day]), and low concentrations of microbially reducible Fe(III) oxyhydroxides ( approximately 1 micromol/g) initially present in aquifer sediments. These results illustrate that, under certain hydrologic conditions, redox conditions in petroleum hydrocarbon-contaminated aquifers can change rapidly in time and space, and that the availability of solid-phase Fe(III)-oxyhydroxides affects this rate of change.     

Identifying trends in groundwater quality using residence time indicators: an example from the Permian aquifer of Dumfries, Scotland

The Permian sandstone and breccia aquifer of Dumfries has an important role in supplying water to the principal town in southwest Scotland. The area comprises mainly pastoral farmland with some industry and fish farming. Ongoing development of the aquifer has revealed the existence of complex groundwater flow through fractures and increasing nitrate concentrations. To further investigate these issues, the age and quality of groundwater throughout the aquifer has now been assessed using standard hydrogeochemical techniques together with CFCs and SF₆ as residence time indicators. The aquifer consists of sandstone- and breccia-dominated units: the Locharbriggs Sandstone in the east and the Doweel Breccia in the west. Groundwater throughout the aquifer is of Ca–Mg–HCO₃ type and moderately mineralised; pH is near neutral. The observed groundwater chemistry is the product of maritime rainfall modified by the dissolution of carbonate material in the breccia, sandstone and surficial deposits. CFC and SF₆ concentrations are interpreted on the basis of mixing between older (>50 years) and recent (1990s) components. Although there is generally a higher proportion of older water within the Locharbriggs Sandstone compared to the Doweel Breccia, stable isotope evidence suggests that the older water component in the interbedded sandstones of the breccia is of much greater antiquity, possibly containing an element of palaeowater. Concentrations of nitrate across the aquifer can be directly related to the amount of recent recharge. Modern groundwater contains approximately 9 mg l^–1 NO₃-N and pre-1950s groundwater has approximately 2 mg l^–1 NO₃-N. Nitrate concentrations measured at individual boreholes are explained by the relative proportions of modern and pre-1950s groundwater. If current practices continue, the concentrations of nitrate measured across the Dumfries Basin will rise as the proportion of pre-1950s groundwater diminishes.

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Resumen El acuífero de areniscas y brechas Pérmicas de Dumfries desempeña un papel importante en el abastecimiento a la ciudad principal del Sudoeste de Escocia. El área comprende sobretodo tierras de pastoreo y granjas, junto con algunas industrias y piscifactorías. El desarrollo iniciado en el acuífero ha revelado la existencia de un complicado flujo subterráneo a través de las fracturas y de un aumento progresivo en la concentración de nitrato. Con el fin de profundizar en el conocimiento de estos temas, se ha determinado la edad y calidad de las aguas subterráneas en todo el acuífero por medio de técnicas hidrogeoquímicas estándar y de indicadores del tiempo de residencia como los clorofluorcarbonados (CFCs) y el fluoruro de azufre (SF₆). El acuífero está formado por las areniscas de Locharbriggs, al Este, y las brechas de Doweel, hacia el Oeste. Las aguas subterráneas son de tipo bicarbonatadas cálcico-magnésicas y presentan una mineralización moderada, mientras que el pH es prácticamente neutro. La química de las aguas subterráneas es el resultado del aerosol marino modificado por la disolución de materiales carbonatados en las brechas, areniscas y depósitos superficiales. Las concentraciones de CFCs y SF₆ se interpretan a partir de una mezcla de aguas entre una componente antigua (más de 50 años) y una reciente (de la década de 1990). Aunque en general se da una mayor proporción de aguas antiguas en las areniscas de Locharbriggs que en las Brechas de Doweel, los isótopos estables sugieren que la componente de aguas antiguas en las intercalaciones de areniscas que aparecen en la formación de brechas es mucho más antigua, y que, posiblemente, se trate de paleoaguas. Las concentraciones de nitrato en el acuífero pueden ser relacionadas directamente con la aportación de recarga reciente. Las aguas subterráneas modernas contienen aproximadamente 9 mg l^–1 de nitrato, mientras que las aguas subterráneas anteriores a 1950 tienen unos 2 mg l^–1. Se puede explicar las concentraciones de nitrato en pozos individuales por las proporciones relativas de aguas subterráneas modernas y anteriores a 1950. Si las prácticas actuales continúan, se producirá un aumento de las concentraciones de nitrato en la cuenca de Dumfries debido a la disminución de la proporción de aguas antiguas.

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Résumé L'aquifère des grès et brèches du Permien de Dumfries joue un rôle important dans l'alimentation en eau de la principale ville du sud-ouest de l'Écosse. La région est principalement soumise à de l'élevage pastoral avec quelques industries et des piscicultures. La progression de l'exploitation de cet aquifère a révélé l'existence d'un écoulement souterrain complexe en fractures et des concentrations en nitrate croissantes. Dans le but d'étudier ces deux points plus en détail, l'âge et la qualité de l'eau souterraine dans tout l'aquifère ont été évalués en utilisant des techniques hydrogéochimiques conventionnelles avec les CFC et SF₆ comme marqueurs du temps de séjour. L'aquifère est constitué par des unités dominées par des brèches et des grès: les grès de Locharbriggs à l'est et les brèches de Doweel à l'ouest. L'eau souterraine dans tout l'aquifère a un faciès bicarbonaté calcique et magnésien et est moyennement minéralisée; le pH est proche de la neutralité. Le chimisme observé de l'eau souterraine résulte des apports marins par la pluie modifiés par la dissolution du matériau carbonaté des brèches, des grès et des formations superficielles. Les concentrations en CFC et SF₆ sont interprétées sur la base d'un mélange entre des composantes ancienne (>50 ans) et récente (années 1990). Bien qu'il y ait en général une plus forte proportion d'eau ancienne dans les grès de Locharbriggs que dans la brèche de Doweel, les isotopes stables suggèrent que la composante d'eau ancienne dans les grès interstratifiés des brèches est beaucoup plus ancienne, contenant probablement un élément d'eau fossile. Les concentrations en nitrate dans l'aquifère peuvent être directement reliées au taux de recharge récente. L'eau souterraine moderne contient approximativement 9 mg l^–1 en NO₃-N et l'eau souterraine d'avant 1950 environ 2 mg l^–1 en NO₃-N. Les concentrations en nitrate mesurées dans des forages individuels sont expliquées par des proportions relatives d'eaux souterraines moderne et antérieure à 1950. Si les pratiques actuelles continuent, les concentrations en nitrate mesurées dans le bassin de Dumfries augmenteront alors que la part de l'eau souterraine d'avant 1950 diminuera.

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The Interpolation Problem in Gps-Supported Aerial Triangulation

This paper gives the results of an investigation into the use of different sampling rates and models for the interpolation of perspective-centre coordinates in GPS-assisted aerial triangulation. Industry-standard models and rigorous signal reconstruction filtering have been implemented for two largescale photogrammetric blocks. GPS sampling rate was found to have the most impact on bundle adjustment results in terms of the perspective-centre residuals. However, the accuracy of object-space point coordinates was found to be invariant to both GPS sampling rate and interpolation method     

A comet impact in AD 536?

Emma Rigby, Melissa Symonds and Derek Ward-Thompson review the evidence for the possibility that a comet may have impacted the Earth in historical times, and discuss the size of the putative comet.     

Theory of Volumetric Moving Dislocation in Poroelastic Halfspace and Characterization of Magma Intrusion Events

The undrained change in pore fluid pressure that accompanies dike intrusion may be conveniently represented as a moving volumetric dislocation. The concept of a dilation center was developed to represent the field of undrained pressure change in a saturated linear elastic medium. Since instantaneous pore fluid pressures can be developed to a considerable distance from the dislocation, monitoring the rate of pressure generation and subsequent pressure dissipation in a fully coupled manner enables certain characteristics of the resulting dislocation to be defined. The principal focus of this study is the application of dislocation-based methods to analyze the behavior of the fluid pressure response induced by intrusive dislocations in a semi-infinite space, such as dike intrusion, hydraulic fracturing and piezometar insertion. Partially drained pore pressures result from the isothermal introduction of volumetric moving pencil-like dislocations described as analogs to moving point dislocation within a semi-infinite saturated elastic medium. To represent behavior within the halfspace, an image dislocation is positioned under the moving coordinate frame fixed to the front of the primary moving dislocation, to yield an approximate solution for pore pressure for constant fluid pressure conditions. Induced pore pressures are concisely described under a minimum set of dimensionless parameter groupings representing propagation velocity, and relative geometry. Charts defining induced pore fluid pressure at a static measuring point provide a meaningful tool for determining unknown parameters in data reduction. Two intrusive events at Krafla, Iceland are examined using the type curve matching techniques. Predicted parameters agree favorably with field data.     

Drumlin Formation Time: Evidence from Northern and Central Sweden

Large‐scale drumlins occur abundantly throughout central and northern Sweden. Whereas many drumlins in the north are an integral part of a relict glacial landscape >100,000 years old, those to the south are generally interpreted as of last deglaciation age. Typically, the latter ones have not been overprinted by younger glacial landforms. Despite this apparent difference in formation history, drumlins in both regions have similar directional and morphological characteristics. A systematic analysis of >3000 drumlins in (i) areas within relict landscapes, (ii) areas with an ambiguous deglaciation age assignment, and (iii) areas within deglacial landscapes, indicates that these latter deglaciation drumlins differ clearly in both shape and size from drumlins in the other two types of landscapes. In addition, numerical modelling indicates that basal melting conditions, a prerequisite for drumlin formation, prevailed only for a very limited time over much of northern Sweden during the last deglaciation, but lasted for longer periods of time during earlier stages of the Weichselian. A reconnaissance radionuclide bedrock exposure date from the crag of a large drumlin in the relict landscape indicates that glacial erosion, and presumably drumlin formation, at this location predated Marine Isotope Stage 7. We conclude, therefore, that the large‐scale drumlins of central and northern Sweden did not form during the last deglaciation, or during any other specific ice flow event. Instead, we suggest that they were formed by successive phases of erosion and deposition by ice sheets of similar magnitude and configuration.     

Groundwater use by vegetation in a tropical savanna riparian zone (Daly River, Australia)

Soil water matric potentials (Ψ_m) and the deuterium (δ²H) composition at natural abundance levels of xylem water, soil water, river water and groundwater were used to evaluate whether trees use groundwater during the dry season in the riparian zone of the Daly River (Northern Territory, Australia). Groundwater was a significant source of water for plant transpiration, probably accounting for more than 50% of the water transpired during the dry season. Groundwater use occurred either when trees used water from the capillary fringe or when low Ψ_m induced by soil water uptake lifted groundwater in the vadose zone. Several water use strategies were inferred within the riparian plant community. Melaleuca argentea W. Fitzg and Barringtonia acutangula (L.) Gaertn. appeared to be obligate phreatophytes as they used groundwater almost exclusively and were associated with riverbanks and lower terraces with shallow (<5 m) water tables. Several species appeared to be facultative phreatophytes (including Cathorium umbellatum (Vahl.) Kosterm. and Acacia auriculiformis A. Cunn. ex Benth.) and tended to rely more heavily on soil water with increased elevation in the riparian zone. The levee-bound Corymbia bella K.D. Hill and L.A.S. Johnson mostly used soil water and is either a facultative phreatophyte or a non-phreatophyte. The temporal variability in groundwater utilisation by the trees is unclear because the study focused on the end of the dry season only. A decline in the regional water table as a result of groundwater pumping may affect the health of riparian zone vegetation in the Daly River because groundwater use is significant during the dry season.