Compaction of a Rock Fracture Moderated by Competing Roles of Stress Corrosion and Pressure Solution

Unusually rapid closure of stressed fractures, observed in the initial stages of loading and at low temperatures, is examined using models for subcritical crack growth and pressure solution. The model for stress corrosion examines tensile stress concentrations induced at the Hertzian contact of propping fracture asperities, and mediates fracture growth according to a kinetic rate law. Conversely, pressure solution is described by the rate-limiting process of dissolution, resulting from the elevated stresses realized at the propping asperity contact. Both models are capable of following the observed compaction of fractures in novaculite. However, closure rates predicted for stress corrosion cracking are orders of magnitudes faster than those predicted for pressure dissolution. For consistent kinetic parameters, predictions from stress corrosion better replicate experimental observations, especially in the short-term and at low temperature when mechanical effects are anticipated to dominate. Rates and magnitudes of both stress corrosion and pressure solution are dependent on stresses exerted over propping asperities. Rates of closure due to stress corrosion cracking are shown to be always higher than for pressure solution, except where stress corrosion ceases as contact areas grow, and local stresses drop below an activation threshold. A simple rate law is apparent for the progress of fracture closure, defined in terms of a constant and an exponent applied to the test duration. For current experimental observations, this rate law is shown to replicate early progress data, and shows promise to define the evolution of transport properties of fractures over extended durations.     

Erosive water level regime and climatic variability forcing of beach–dune systems on south‐western Vancouver Island,British Columbia,Canada

Increases in the frequency and magnitude of extreme water levels and storm surges are correlated with known indices of climatic variability (CV), including the El Niño Southern Oscillation (ENSO) and the Pacific Decadal Oscillation (PDO), along some areas of the British Columbia coast. Since a shift to a positive PDO regime in 1977, the effects of ENSO events have been more frequent, persistent, and intense. Teleconnected impacts include more frequent storms, higher surges, and enhanced coastal erosion. The response of oceanographic forcing mechanisms (i.e. tide, surge, wave height, wave period) to CV events and their role in coastal erosion remain unclear, particularly in western Canada. As a first step in exploring the interactions between ocean–atmosphere forcing and beach–dune responses, this paper assembles the historic erosive total water level (TWL) regime and explores relations with observed high magnitude storms that have occurred in the Tofino‐Ucluelet region (Wickaninnish Bay) on the west coast of Vancouver Island, British Columbia, Canada. Extreme events where TWL exceeded an erosional threshold (i.e. elevation of the beach–foredune junction) of 5·5 m aCD are examined to identify dominant forcing mechanisms and to classify a regime that describes erosive events driven principally by wave conditions (61·5%), followed by surge (21·8%), and tidal (16·7%) effects. Furthermore, teleconnections between regional CV phenomena, extreme storm events and, by association, coastal erosion, are explored. Despite regional sea level rise (eustatic and steric), rapid crustal uplift rates have resulted in a falling relative sea level and, in some sedimentary systems, shoreline progradation at rates approaching +1·5 m a^–1 over recent decades. Foredune erosion occurs locally with a recurrence interval of approximately 1·53 years followed by rapid rebuilding due to high onshore sand supply and often in the presence of large woody debris and rapidly colonizing vegetation in the backshore. Copyright © 2012 John Wiley & Sons, Ltd.     

The Zn abundance and isotopic composition of diatom frustules,a proxy for Zn availability in ocean surface seawater

We have developed cleaning methods for extracting diatomopal from bulk marine sediment samples, for measurement of both zinc (Zn) abundance and isotope composition. This cleaning technique was then applied to a set of Holocene core-top samples from the Southern Ocean. The measured δ⁶⁶Zn (reported relative to the JMC_Lyon standard) and Zn/Si ratios from the Southern Ocean diatom_opal samples range from 0.7 to 1.5‰, and from 14 to 0.9 μmol/mol, respectively. The Zn abundance and isotope composition data show a clear correlation with opal burial rates and other oceanographic parameters. In common with previous work, we interpret the systematic changes in the Zn/Si ratio to be linked to the variability in the concentrations of bioavailable Zn in the ambient surface seawater where the diatom opal is formed. This variability is likely to be primarily controlled by the degree to which Zn is taken up into phytoplankton biomass. The observed systematic pattern in the δ⁶⁶Zn compositions of the diatom_opal core-top samples is, similarly, likely to reflect changes in the δ⁶⁶Zn composition of the ambient Zn in the surface waters above the core-top sites, which is progressively driven towards isotopically heavier values by preferential incorporation of the lighter isotopes into phytoplankton organic material. Thus, the systematic relationship between Zn isotopes and abundance observed in the core-top diatom_opal samples suggests a potential tool for investigating the biogeochemical cycling of Zn in the past surface ocean for down-core diatom_opal material. In this respect, it may be possible to test hypotheses that attribute variations in atmospheric CO₂ on glacial–interglacial timescales to the degree to which trace metals limited primary productivity in HNLC zones.     

Patos Lagoon outflow within the Río de la Plata plume using an airborne salinity mapper: Observing an embedded plume

Major river systems discharging into continental shelf waters frequently form buoyant coastal currents that propagate along the continental shelf in the direction of coastal trapped wave propagation (with the coast on the right/left, in the northern/southern hemisphere). The combined flow of the Uruguay and Paraná Rivers, which discharges freshwater into the Río de la Plata estuary (Lat. ∼36°S), often gives rise to a buoyant coastal current (the ‘Plata plume’) that extends northward along the continental shelf off Uruguay and Southern Brazil. Depending upon the prevailing rainfall, wind and tidal conditions, the Patos/Mirim Lagoon complex (Lat. ∼32°S) may also produce a freshwater outflow plume that expands across the inner continental shelf. Under these circumstances the Patos outflow plume can be embedded in temperature, salinity and current fields that are strongly influenced by the larger Plata plume. The purpose of this paper is to present observations of such an embedded plume structure and to determine the dynamical characteristics of the ambient and embedded plumes.     

Comet Hale-Bopp and the Diffuse Interstellar Lines

As an illustration of the manner in whichserendipitous events can be used to obtain usefulscientific information, the reasons for observing,spectroscopically, the appulse of HD 12895 and CometHale-Bopp are discussed and the conclusions of thestudy are briefly presented.     

The metamorphic rocks of the southern part of the Mainland of Shetland

The paper presents a one mile to the inch geological map of the southern part of the Mainland of Shetland (excluding areas underlain by Old Red rocks) and an account of the metamorphic rocks occurring there. The metasediments mostly belong to the East Mainland Succession which is about 14 km thick. They dip vertically and strike north-south. The metasediments in the west were originally laminated sandstones devoid of current bedding and grading and composed of poorly weathered material. They include several limestones up to half a kilometer thick. In the east the metasediments were originally gritty quartzites and sandstones together with shales which are usually finer grained and composed of more weathered material than those to the west. On two occasions the deposition of these rocks was interrupted by outpourings of spilites. The rocks show signs of four metamorphisms. The first metamorphism was accompanied by a penetrative deformation causing elongation of the rocks in a north-south direction, shortening in an east-west direction and elongation and shortening in different areas in a vertical direction. As a result of this metamorphism the pelitic rocks over the whole area became schists containing such minerals as biotite, chlorite, muscovite, quartz and feldspar, and possibly garnet. In a later metamorphism a belt of these rocks a kilometer or so wide became gneissified, probably due to the passage of high temperature fluids. In various parts of the area such minerals as biotite, chlorite, garnet, staurolite, chloritoid, and kyanite grew as porphyroblasts in a series of episodes referred to collectively as the porphyroblast metamorphism. After these metamorphisms the area was intruded, 400 m.y. ago, by a number of granites. In places these have produced extensive thermal aureoles containing such minerals as staurolite, chloritoid, andalusite, kyanite, sillimanite, garnet, muscovite, biotite and chlorite in pelitic rocks. The emplacement of one of the granites was accompanied by large and small scale folding. Several major faults are described including the Nesting tear fault with a 16 km dextral displacement and a mélange zone beneath a nappe.     

Tafoni on coastal slopes,South Devon,U.K.

Cavernous weathering (tafoni development) occurs on coastal slopes in greenschist bedrock at elevations up to 40 m above sea level. The freshly weathered surfaces of the cavern interiors are irregular in morphology, discordant to major rock structure, formed by substantially weakened rock and associated with granular weathering debris. The weathering debris contains soluble elements in proportions similar to those present in seawater, and the penetration of elements associated with sea salts into the weathering surface to estimated depths of at least 0·1–0·2 m is indicated by the presence of chlorine. Scanning electron microscopy and microprobe analyses suggest that rock breakdown occurs principally through limited chemical weathering at grain boundaries. The mechanism for the emplacement of marine salts within sheltered rock surfaces in the tafoni is postulated to be a combination of dry deposition under turbulent atmospheric conditions and wetting by coastal fog.     

Terrestrial age measurements using natural thermoluminescence of a drained zone under the fusion crust of Antarctic ordinary chondrites

Abstract— Miono et al. (1990) and Miono and Nakanishi (1994) have proposed that the build‐up of natural thermoluminescence (TL) in a drained layer directly below the meteorite fusion crust can be used to determine terrestrial ages of meteorites in the 40 to 200 ka range. We have measured the natural TL of the drained layer of 15 meteorites. The data indicate that this technique could be used to determine terrestrial ages of meteorites with ages <200 ka, after which TL equilibrium is reached. Comparison of TL build‐up with terrestrial ages for a suite of Antarctic meteorites suggests that the meteorites have been exposed to temperatures of 0 to 5 °C. The close correspondence between natural TL levels and surface exposure TL growth curves suggest that Allan Hills meteorites with ages <200 ka have spent a significant portion of their terrestrial history exposed on the ice surface, rather than being buried in the ice sheet. The technique is, however, sensitive to thermal history; and, for Antarctic meteorites with terrestrial ages <200 ka, natural TL of the drained zone largely reflects exposure on the ice surface.     

Some responses of transplanted Mytilus edulis to metal-enriched sediments and sewage sludge

Approximately 25 % of the sewage sludge produced in the United Kingdom (about 10 million wet tonnes anually) is disposed of to British coastal waters at 15 sites. A series of tests is being evaluated in order to determine the effects of this practice in relation to the effects due to other polluting inputs, both natural and man-made, to the marine environment. The results presented here are for one site on the south-west coast of Britain. They indicate that the increased metal content of the tissue and the presence of sulphydryl-rich metal-binding proteins in the lysosomes of digestive cells in transplanted mussels can be correlated with exposure at sites overlying metal-rich sediments and to a lesser extent an area used for the disposal of sewage sludge containing metallic contaminants.