FACTOR ANALYSIS OF A SIMULATED DATA MATRIX INVOLVING AQUEOUS COMPLEX EQUILIBRIA

Abstract factor analyses were performed on databases consisting of simulated samples from aqueousequilbria.The program COMPLEX was used to generate equilibrium species in a system of three reactantmetals and five reactant bases.Reactant concentrations and pH were drawn from random-normaldistributions so that sample data vectors comprised a multivariate log-normal distribution of equilibriumconcentrations.In addition,sample groups were created containing different distributions for pH andreactant concentrations.Equilibrium species were shown to contain variance contributed by change in pH among samples aswell as change in reactant concentrations.Factor modelling revealed the qualitative relationships amongthe species and how the relationships change with pH.Factors also revealed those reactants containingvariance in the data matrix.In some cases,reactant variance obscured relationships between pH and theequilibrium species.Since factor modelling of a simulated data matrix revealed the expected chemical equilibriuminteractions,a potentially powerful tool exists for investigating the effects of outliers and error.     

Seasonal variability in Atlantic Water off Spitsbergen

A combination of 2-year-long mooring-based measurements and snapshot conductivity–temperature–depth (CTD) observations at the continental slope off Spitsbergen (81°30′N, 31°00′E) is used to demonstrate a significant hydrographic seasonal signal in Atlantic Water (AW) that propagates along the Eurasian continental slope in the Arctic Ocean. At the mooring position this seasonal signal dominates, contributing up to 50% of the total variance. Annual temperature maximum in the upper ocean (above 215 m) is reached in mid-November, when the ocean in the area is normally covered by ice. Distinct division into ‘summer’ (warmer and saltier) and ‘winter’ (colder and fresher) AW types is revealed there. Estimated temperature difference between the ‘summer’ and ‘winter’ waters is 1.2 °C, which implies that the range of seasonal heat content variations is of the same order of magnitude as the mean local AW heat content, suggesting an important role of seasonal changes in the intensity of the upward heat flux from AW. Although the current meter observations are only 1-year long, they hint at a persistent, highly barotropic current with little or no seasonal signal attached.     

A necessary voice: Climate change and lived experiences of youth in Rigolet,Nunatsiavut, Canada

Globally, youth voices and their experiences, observations, and perceptions about climatic and environmental change and variability are relatively absent in the published literature to date. To address this gap, the goal of this research was to explore the observations and perceptions of climate change held by youth (12–25 years old) in the Inuit community of Rigolet, Nunatsiavut, Canada. Twenty in-depth interviews were conducted with youth in Rigolet to gather data about climatic and environmental changes young people have observed, and the subsequent impacts of these changes on their lives, culture, and community. Youth reported observing and experiencing climatic and environmental changes throughout their lives, with reported impacts falling within five main themes: changing travel conditions and access to hunting; challenges to Inuit culture; a concern for Elder and senior well-being; strong climate-related emotional responses; and youth-identified potential adaptation strategies. More broadly, this research demonstrated that young people have valuable knowledge and perspectives to offer. In particular, researchers, community leaders, and policy makers are encouraged to meaningfully engage youth as crucial stakeholders in future climate change work, research, dialogue, and policy.     

Neoichnology and implications for stratigraphy of reworked Upper Oligocene oysters,Antigua, West Indies

The Late Oligocene oyster Hyotissa antiguensis (Brown) is locally common in the Antigua Formation of Hughes Point, eastern Antigua, Lesser Antilles; it was not commonly bored at that time. Its valves and shells are robust, and reworked into the shallow water near-shore environment in Antigua; it could potentially be incorporated into younger rocks. Its neoichnology includes clues that would facilitate identification of these oysters as reworked fossils. The suite of modern borings found in these specimens includes common Caulostrepsis taeniola Clarke, Gastrochaenolites isp. cf. G. turbinatus Kelly and Bromley and Entobia isp., and rare Oichnus simplex Bromley and Rogerella? isp. The latter three taxa are limited to oyster shell substrates. Of the common ichnotaxa, Caulostrepsis and Gastrochaenolites are particularly prominent in limestone clasts and limestone cemented to oyster shells, which would be an indicator of reworking if found in a post-Oligocene lithified deposit. Caulostrepsis and Gastrochaenolites are relatively less common in oyster shells and valves, and in many specimens are seen to terminate against the shell. Entobia is the only common boring limited to the shell substrate. The fidelity of preservation of modern borings is also superior in limestone clasts. This suite of borings is comparable with those found in the Neogene of the Antillean region.     

Modeling the dynamics of spring-driven oscillating-foil propulsion

In this paper we present a model for oscillating-foil propulsion in which springs are used to transmit forces from the actuators to the foil. The expressions for hydrodynamic force and moment on the foil come from classical, linear, unsteady aerodynamics, and these are coupled to linearized rigid-body mechanics to obtain the complete model for swimming. The model is presented as a low-order set of ordinary differential equations, which makes it suitable for the application of techniques from systems and control theory. The springs serve to reduce energy costs, and we derive explicit expressions for spring constants which are optimal in this sense. However, the use of springs can potentially lead to unstable dynamics. Therefore, we also derive a set of necessary and sufficient conditions for stability. A detailed example is presented in which energy costs for one actuator are reduced by 33%     

Performance and Sustainability of District-Scale Ground Coupled Heat Pump Systems

This study proposes a solution to the problem of maintaining the performance and sustainability of district-scale, cooling-dominated ground coupled heat pump (GCHP) systems. These systems tend to overheat because heat dissipates slowly in relation to the size of the borefields. To demonstrate this problem, a 2000-borehole field is considered at a district-scale GCHP system in the Upper Midwest, US. The borefield’s ground and fluid temperature responses to its design heating and cooling loads are simulated using computational fluid dynamics implemented by applying the finite volume method. The ground temperature is predicted by applying the thermal loads uniformly over the borefield and simulating heat dissipation to the surrounding geology through conduction coupled with advection due to groundwater flow. The results show that a significant energy imbalance will develop in the ground after the first few years of GCHP operation, even with high rates of groundwater flow. The model presented in this study predicts that the temperature at the center of the borefield will reach 18 °C after 5 years and approximately 50 °C after 20 years of operation in the absence of any mitigation strategies. The fluid temperature in the boreholes is then simulated using a single borehole model to estimate the heat pump coefficient of performance, which decreases as the modeled system heats up. To balance the energy inputs/outputs to the ground—thus maintaining the system’s performance—an operating scheme utilizing cold-water circulation during the winter is evaluated. Under the simulated conditions, this mitigation strategy carries the excess energy out of the borefield. Therefore, the proposed mitigation strategy may be a viable measure to sustaining the operating efficiency of cooling-dominated, district-scale borefields in climates with cold winters.     

Evaluation of fluidized bed asbestos segregator to determine erionite in soil

Three sets of soil samples were collected by the National Institute for Occupational Safety and Health and one set by South Dakota School of Mines & Technology from in and around the Slim Buttes Land Unit of the Sioux Ranger District of the Custer–Gallatin National Forest in the northwest of South Dakota. The rocks forming the Slim Buttes are sedimentary clays, sands and gravels including re-worked volcanic ash-falls in which the zeolite mineral erionite has crystallized during diagenesis in a fibrous form or morphology similar to that of asbestos. The samples were prepared using the fluidized bed asbestos segregator (FBAS) and analyzed by phase contrast microscopy (PCM) or transmission electron microscopy to detect the presence of mineral fibers. FBAS–PCM results compared to semi-quantitative polarized light microscopy (PLM) and X-ray diffraction analysis indicated a recovery of approximately 1% and a linear relationship that likely can be extrapolated to concentrations well below the 1% detection limit of PLM. There were small variations between a PCM count of 10 fibers to a count of 100 fibers (or a maximum of 200 microscopic fields of view), which indicates the possibility of rapid turnaround of results. Although the four sets of samples examined in this work were collected by slightly different techniques, some tentative conclusions can be drawn about the distribution of erionite in soils. Erionite was detected in almost every soil sample, even those taken several miles from the outcrop, but without any distribution indicating recent transportation from the current volcaniclastic sediment outcrops. Removal of more extensive volcaniclastic sediments through erosion may have resulted in remnant material in soils, including erionite crystals, but this possibility requires further study. Although we have demonstrated that erionite in soils can be detected through FBAS–PCM, we have not attempted to correlate those results with human inhalation exposure through activity-based sampling, and thus, any risk inherent in working these soils is unknown.