Electron paramagnetic resonance spectroscopy: A suggested approach to trace metal analysis in marine environments

Electron paramagnetic resonance (EPR) spectroscopy analysis of marine samples from different environments appears to differentiate between adsorbed and structural Mn (II) and Fe (III) sites in the sediment. This suggests that EPR may provide a means of distinguishing different environmental influences on sediment. Acid extract solutions from sediment samples exhibit clearly defined EPR spectra due to Mn(II), Ti(III), Fe(III), and VO(IV), which are amenable to qualitative and quantitative analysis at concentrations below one part per million. Spectra of several shellfish vary considerably, both between species, and within a species, depending on sampling localities. Resonances from Mn(II), Mo(V), and Fe(III) can be obtained. Mn(II) is substituted for Ca(II) in the calcite structure of some shells. The low detection limits, small sample size, required and identification of oxidation states by EPR complement other analytical techniques and may prove useful in marine systems.     

双核结构模式形成的自然基础

The dual-nuclei spatial structurs is composed of a regional central city,a port city and their spatial relations in certain regions.In general,this spatial structure could be found in most of the coastal regions or regions along big rivers.In terms of the mechanism,the dual-nuclei structure is the result of the spatial interaction and the complementary characteristics of the center city and the port city.The “marginal function” of the port city and its relationship with the central city has long been discussed in the literature.On the one hand,drainage area is the main natural grographical background of the formation of the dual-nuclei spatial structure;therefore,we can build a theoretical geographic structure that is based on the drainage area.On the other hand,vicissitude of the coastline also has important influence on the formation of the dual-nuclei spatial structure.It is especially meaningful if we can notice this when we examine deeply the research on the spatial structure of delta.     

Basement structural architecture and hydrocarbon conduit potential of polygonal faults in the Cooper‐Eromanga Basin,Australia

A thorough and complete understanding of the structural geology and evolution of the Cooper‐Eromanga Basin has been hampered by low‐resolution seismic data that becomes particularly difficult to interpret below the thick Permian coal measures. As a result, researchers are tentative to interpret the basement fault architecture within the basin, which is largely undefined. To provide a better understanding of the basement fault geometry, all available two‐dimensional seismic lines together with 12 three‐dimensional seismic surveys were structurally interpreted with assistance from seismic attribute analysis. The Upper Cretaceous Cadna‐owie Formation and top Permian reflectors were analysed using a common seismic attribute technique (incoherency) that was used to infer the presence of faults that may have otherwise been overlooked. Detailed basement fault maps for each seismic survey were constructed and used in conjunction with two‐dimensional seismic data interpretation to produce a regional basement fault map. Large north‐northeast–south‐southwest‐striking sinistral strike–slip faults were identified within the Patchawarra Trough appearing to splay from the main northeast–southwest‐striking ridge. These sinistral north‐northeast–south‐southwest‐striking faults, together with field‐scale southeast–northwest‐striking dextral strike–slip faults, are optimally oriented to have potentially developed as a conjugated fault set under a south‐southeast–north‐northwest‐oriented strike–slip stress regime. Geomechanical modelling for a regionally extensive system of Cretaceous polygonal faults was performed to calculate the Leakage Factor and Dilation Tendency of individual faults. Faults that extend into Lower Cretaceous oil‐rich reservoirs with strikes of between 060°N and 140°N and a high to near‐vertical dip angle were identified to most likely be acting as conduits for the tertiary migration of hydrocarbons from known Lower Cretaceous hydrocarbon reservoirs into shallow Cretaceous sediments. This research provides valuable information on the regional basement fault architecture and a more detailed exploration target for the Cooper‐Eromanga Basin, which were previously not available in literature.     

Local co-operation, ethnic diversity and state territoriality – The case of Haparanda and Tornio on the Sweden – Finland border

The neighbouring towns of Haparanda and Tornio, separated only by a narrow strip of grass and wetland, are divided by the only inhabited land boundary between Finland and Sweden in the southern part of the Torne River. The population represents four different groups in relation to linguistic and cultural backgrounds. In the daily lives of the inhabitants, the state boundary is probably of less significance than linguistic, social and ‘ethnic’ differences. On the local government level there is a strong will to unite forces to make the total area a viable region in spite of its peripheral location, but state legislation makes co-ordination difficult. This may be seen as a necessity, but in the daily lives of the populations, the state boundary defines an area of unequal access, sometimes working in favour of and sometimes barring contacts and co-operation. The media consumption reflects a clear ‘national’ interest with a strong local bias. In their attitudes, Finnish speakers and bilinguals show a greater appreciation of ‘the other’ than unilingual Swedes. This may reflect the actual possibility space (reach) in the local area. This revised version was published online in July 2006 with corrections to the Cover Date.     

苏州市区信息通讯企业空间集聚与新企业选址

高科技产业是全球化背景下城市发展与区域竞争的关键,但是高科技产业发展空间极不平衡,空间要素显著影响高科技企业区位选择及空间集聚。针对现有研究主要集中在国家、省等大尺度单元,本文引入空间点模式分析方法,探讨了1996-2006年间苏州市区不同空间尺度上信息通讯企业的时空集聚特征。研究发现:在0~6km的尺度上,信息通讯企业表现出明显的集聚特征,并随着尺度的增加呈现出倒U型集聚趋势;随着时间的推移,企业空间集聚的热点地区逐渐从老城区向外围推移,但是集聚峰区依然主要分布在老城区及其外围的国家和省级开发区;同时,新企业的选址与原有企业的分布特征表现出很强的相关性。运用计数模型的计量结果也表明企业集聚特征对新企业区位选择具有显著影响,同时起作用的还有地方政府政策影响下的开发区建设、城市内外交通条件、自然环境条件等因素。     

大都市区建设用地空间扩展机理研究——以南京市区为例

大都市区建设用地微观空间扩展机理的研究是有效调控城市土地利用布局的科学基础。以南京市市区为例,以经济学的收益最大化理论为基础,构建研究建设用地扩展的成本——收益分析框架。以1 km×1 km为基本研究单元,利用遥感等数据研究1995~2001年、2001~2007年建设用地扩展的微观机理。研究表明,基期建设用地比重、到CBD、到开发区、到高速公路互通口的可达性、邻域建设用地主导单元的数量等收益要素以及耕地面积比重、水域面积比重、地质灾害区比重、坡度、重要生态功能区比重、城市规划建设用地区比重等成本要素是影响建设用地扩展的重要指标。两期比较分析表明,收益要素作用力大于成本要素,其更深层次的作用力则是全球化和市场化。空间政策对于建设用地扩展的约束作用越来越大。基于微观空间机理的研究提出了大都市区基本农田布局的政策建议。     

Acoustic core logging in blast-damaged rock

Thill, R.E. and D' Andrea, D. V., 1975. Acoustic core logging in blast-damaged rock. Eng. Geol., 10: 13–36.The Bureau of Mines, in cooperation with the Duval Corp., conducted a blast-fragmentation experiment to determine the feasibility of preparing a porphyry copper-molybdenum deposit for in-situ leaching. The blast was designed with ten 9-inch-diameter blastholes to depths of 110 feet in an equilateral triangle configuration; spacings between blastholes were 15, 20, and 25 ft. One of the major problems in the experiment was in assessing blast damage. Acoustic core-logging equipment and methods were devised and used as one approach in solving this problem. Ultrasonic pulse travel-times were determined in four diametral directions at 2-ft intervals of depth to a final depth of 120 ft in three preblast and six postblast drill cores at the Duval test site. The acoustic logging program provided compressional wave travel-time at 0°, 45°, 90°, and 135° around the core circumference, maximum travel-time difference, mean compressional-wave velocity, and an anisotropy factor. Other acoustic parameters introduced in the analyses were stiffness modulus, seismic quality designation (SQD), and a compensated velocity to account for portions of the core that were nonrecoverable or too highly fractured to permit diametral travel-time measurements.The acoustic parameters all indicated the deterioration in structural quality from the preblast condition, in which the rock already was badly fractured and weathered, to the more highly fractured postblast condition. Because of the highly fragmented, poor structural condition of the rock after blasting, the rock was indicated to be suitable for in-situ leaching, at least at the 20- and 15-ft blasthole spacings, and even in some zones in the rock at the 25-ft blasthole spacing.     

Intra-field variability of scalar flux densities across a transition between a desert and an irrigated potato field

This paper reports on measurements of sensible and latent heat and CO₂ fluxes made over an irrigated potato field, growing next to a patch of desert. The study was conducted using two eddy correlation systems. One measurement system was located within the equilibrium boundary layer 800 m downwind from the edge of the potato field. The other measurement system was mobile and was placed at various downwind positions to probe the horizontal transition of vertical scalar fluxes. Latent (LE) and sensible (H) heat fluxes, measured at 4 m above the surface, exhibited marked variations with downwind distance over the field. Only after the fetch to height ratio exceeded 75 to 1 didLE andH become invariant with downwind distance. When latent and sensible heat fluxes were measured upwind of this threshold, significant advection of humidity-deficit occurred, causing a vertical flux divergence ofH andLE.The measured fluxes of momentum, heat, and moisture were compared with predictions from a second-order closure two-dimensional atmospheric boundary layer model. There is good agreement between measurements and model predictions. A soil-plant-atmosphere model was used to examine nonlinear feedbacks between humidity-deficits, stomatal conductance and evaporation. Data interpretation with this model revealed that the advection of hot dry air did not enhance surface evaporation rates near the upwind edge of the potato field, because of negative feedbacks among stomatal conductance, humidity-deficits, andLE. This finding is consistent with results from several recent studies.