Seafloor spreading history of the Agulhas Basin

Data gathered by recent “Islas Orcadas” cruises reveal the seafloor spreading pattern for a region south of the Agulhas/Falkland fracture zone system. The presence of a magnetic anomaly bight about the Agulhas Plateau indicates that the Agulhas Plateau may have developed at the site of a tectonic plate triple junction during the Late Cretaceous. A westward jump in the seafloor spreading center during the Late Maestrichtian (anomaly 34?31) reduced the offset across the Falkland/Agulhas fracture zone system and resulted in the formation of two conjugate aseismic ridges here described as the Meteor and Islas Orcadas Rises. The magnetic lineation pattern in the Agulhas Basin suggests that a tectonic plate (Malvinas Plate) existed during Campanian to Maestrichtian times. Relative rates of motion are calculated for Antarctica, South America, and Africa for the Late Cretaceous.     

Megacryst-bulk rock isotopic disequilibrium as an indicator of contamination processes: The Edgecumbe Volcanic Field,SE Alaska

Sr and Nd isotopic ratios are reported from mineral separates and bulk rock samples from the Edgecumbe Volcanic Field in southeast Alaska, a suite of lavas that has developed by assimilation. Megacrysts in the basaltic unit and the rhyodacites are in isotopic equilibrium with their matrices. Because the rhyodacites developed as the result of assimilation, the assimilate must have been completely dissolved. In contrast, megacrysts in the two andesitic units are in isotopic disequilibrium with their matrix. These megacrysts must be a mixture of those inherited from the contaminant, crystals in equilibrium with the groundmass, and possibly crystals inherited from a mafic liquid.     

Geochemical constraints on magma processes in a peralkaline system: The Paisano volcano,west Texas

Major and trace element data for a sequence of peralkaline silicic lavas and pyroclastic flows, exposed in the caldera wall of the Paisano volcano, west Texas, document systematic fractional crystallization during magmatic evolution and an open system, magma mixing event in the upper parts of the sequence. Stratigraphically lowest flows are comendite and comenditic quartz trachyte lavas and ash flow tufts. Overlying these units is a trachyte with compositional, textural and mineralogical features indicating that it is the product of magma-mixing; similar flows occur in other parts of the volcano at the same stratigraphic level. This composite trachyte is considered to be a mixture of mugearitic or mafic trachytic magma, derived from a similar source region which yielded the earlier caldera wall flows. Trace element concentrations of the post-trachyte comenditic quartz trachyte lavas suggest they were erupted from a chamber whose magma was diluted by an influx of mugearitic or mafic trachytic magma during a magma mixing event.Rayleigh fractionation calculations show that the comendites and comenditic quartz trachytes can be derived from a parental mugearite magma by 88% to 93% fractionation of dominantly plagioclase and alkali feldspar, with lesser amounts of clinopyroxene, magnetite and apatite. Zircon was not a significant fractionating phase. The composition, mineralogy and depth of the source region(s) which generated these magmas cannot be constrained from the present data set.     

Isotopic and noble gas study of Chalk groundwater in the London Basin, England

The chemical and isotopic composition of groundwater from 52 sites in the London (U.K.) area was determined as part of a project aimed at assessing the spatial variation in the age of Chalk groundwater, and in determining the relationship between fracture and matrix groundwater in this dual porosity system.Systematic changes in groundwater chemistry take place in the downgradient direction in response to several chemical processes. These processes include early concentration by evaporation and congruent dissolution of calcite followed by widespread incongruent dissolution and ion exchange in addition to local oxidation-reduction reactions, gypsum dissolution and saline intrusion. As a result of the above processes, Chalk groundwater follows an evolutionary path from Ca bicarbonate type to Na bicarbonate type.The age of Chalk groundwater was modelled using¹⁴C, δ¹³C,³H, δ²H and δ¹⁸0. There is a general increase in the groundwater age in a downgradient direction with the oldest water found in N central areas of the basin. Groundwater in the unconfined zones and in areas S of the Greenwich fault is almost entirely of unevolved, modem composition. Carbon-14 modelling suggests that Chalk groundwater in the S basin is generally less than 10000 a old while that in the north is generally between 10000 and 25000 a old. The presence of³H in concentrations of up to 7 TU in groundwater which yields ages of several 1000 a, however, indicates that mechanisms exist for the rapid introduction of recent groundwater to the confined aquifer. Results of palaeorecharge temperature determinations using δ²H, δ¹⁸0 and noble gas analytical results suggest that significant Devensian recharge did indeed occur in the aquifer.A model of the development of the Chalk recognizes that it is a classic dual porosity aquifer in which groundwater flow occurs predominantly in the fracture system. The upper 50 m of the aquifer was flushed with fresh water during the 2–3 × 10⁶ a of the Quaternary and therefore meteoric water largely replaced the Tertiary and Cretaceous marine water that previously saturated the system. Most processes which control the chemistry of the groundwater occur in the matrix where the surface area is exceptionally high. Although fracture flow dominates the flow regime, diffusion from the matrix into the fracture porosity controls the chemistry of Chalk groundwater.     

Orthodoxy and creativity in theories of mountain building before 1922

In the 1870s, theories of mountain building emerged from little more than speculation to inference based on a growing body of observation and documentation. This coincided with abandonment of models stressing uplift, and their replacement, in the new orthodoxy, by models in which earth contraction led to lateral compression in its outer shell. Nevertheless, perceived weaknesses in this model gave impetus to new theories, some emphasizing primary vertical movement, and others continental displacement or subcrustal flow. The rebel theories added to the understanding of earth processes in important ways, by drawing attention to the weaknesses in the prevailing orthodoxy. But, in 1922, the complete answer remained out of reach.

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Zusammenfassung Die siebziger Jahre des vorigen Jahrhunderts brachten den Anfang von wissenschaftlich fundierten Theorien der Gebirgsbildung. Diese Zeit sah auch den Übergang von Erhebungstheorien zur neuen Lehrmeinung, nach welcher Erdkontraktion zu lateralen Drucken in der Außenhülle der Erde führte. Erkannte Schwächen dieses Modells führten jedoch zu neuen Gegentheorien, von denen einige primäre Vertikalbewegungen in den Vordergrund stellten, während andere Kontinentalverschiebung oder Unterströmungen als den Motor der Gebirgsbildung sahen. Diese Gegentheorien haben den Fortschritt der Erdwissenschaften gefördert, indem sie auf Schwächen der herrschenden Lehrmeinung aufmerksam machten. Aber selbst zu Argands Zeit war ein völlig befriedigendes Modell noch gar nicht erreichbar.

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Résumé C'est dans les années 1870–1880 que commençaient à s'établir les premières théories vraiment scientifiques de l'orogenèse. C'était la décade qui marqua l'abandon des théories à base de soulèvement et le début du règne de la nouvelle orthodoxie d'après laquelle la contraction de la terre mène à la compression latérale d'une pellicule extérieure. Néansmoins, certaines faiblesses du nouveau modèle servaient d'élan à des théories rebelles dont quelques-unes soulignaient l'importance des soulèvements primaires, tandisque d'autres cherchaient le moteur de l'orogenèse dans la dérive des continents ou dans des courants dans une masse quasi-fluide subcrustale. Ces théories rebelles ont avancé la science en soulignant les faiblesses de l'orthodoxie. En fin de compte, une solution complètement satisfaisante ne paraissait pas encore pouvoir être atteinte à l'époque d'Argand.

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Evaluation and comparison of spatial interpolators II

The performance of several variations on ordinary kriging and inverse distance estimators is evaluated. Mean squared errors (MSE) were calculated for estimates made on multiple resamplings from five exhaustive data bases representing two distinctly different types of estimation problem. Ordinary kriging, when performed with variograms estimated from the sample data, was more robust than inverse-distance methods to the type of estimation problem, and to the choice of estimation parameters such as number of neighbors.Notice: Although the research described in this article has been funded in part by the United States Environmental Protection Agency through Cooperative Agreement CR818526 to the Harry Reid Center for Environmental Studies, University of Nevada-Las Vegas, it has not been subjected to Agency review. Therefore it does not necessarily reflect the views of the Agency. Mention of trade names or commercial products does not constitute endorsement or recommendation for use.     

Hydrocarbons generated by hydropyrolysis of suspended marine particulate organic matter: Relationship to the oceanography of the Black Sea and the Rhodes Gyre

The suspended particulate organic matter, SPOM, in the autumnal Black Sea has been characterised using catalytic hydropyrolysis (HyPy) of the total (bound plus free) lipid material. The technique, which generates maximum yields of volatile products from sediments, kerogens and phytoplankton, was followed using gas chromatography and gas chromatography/mass spectrometry. The generated alkanes were dominated by n-C₁₈, hypothesised to arise predominantly from unsaturated C₁₈ fatty acids. Steranes were generated from reductive conversion of free and bound sterols. The generation of branched alkanes and especially of hopanes provided formal evidence for the participation of bacteria in the mineralisation of the SPOM. Whereas similar distributions of n-alkanes were generated from SPOM sampled from different depths of the comparatively well-stirred Rhodes Gyre (eastern Mediterranean), mineralisation of the SPOM at each depth of the central Black Sea produced characteristic changes in the composition and concentration of the HyPy products. Depth profiles of the n-alkanes generated from SPOM in the region of the Rim Current were affected by the local hydrography. Polynuclear aromatic hydrocarbons (PAHs) of anthropogenic origin were present in the surface waters of the central Black Sea. Some methyl benzenes, thiophenes and pyrroles were also generated.     

The emergence of a Galápagos shield volcano, Roca Redonda

Roca Redonda volcano is a mostly submarine shield volcano that rises nearly 3 km from the adjacent seafloor. Over twenty lava flows and palagonite tuff are exposed in a 60 meter high oblong outcrop above sea level, and several other flows are exposed in the shallow water surrounding the islet. Thick, slightly alkaline picritic flows form the base of the section. Thinner picrites interbedded with sparsely porphyritic alkali-olivine basaltic pahoehoe toes characterize the upper section. The subaerial section probably records the filling of a palagonite tuff cone with younger lavas. Numerous fumaroles that may have a magmatic component are present in the shallow (<30 m) submarine zone and indicate that the volcano is probably still active. Three lava types are exposed: the basal picrites with 19% > MgO > 14%, high-Mg basalts with MgO of about 9%, and low-Mg basalts with MgO of about 6%. The Sr and Nd isotopic ratios of the three lava types are within analytical uncertainty. Olivine compositions indicate that the picrites are basaltic liquids that have accumulated olivine whose composition is in equilibrium with the host basaltic liquid. Apparently, basaltic magmas percolated through dunite and troctolite that had crystallized from slightly older Roca Redonda basaltic magma. Lavas from Roca Redonda have enriched trace element contents and isotopic ratios relative to nearby Wolf volcano, but they are quite similar to lavas from Cerro Azul and Ecuador volcanoes. The common characteristic of these volcanoes is that they lie on the periphery of the archipelago and are in a stage of subaerial growth. This suggests that Galápagos volcanoes may go through a juvenile alkaline stage before a mature tholeiitic stage, analogous to the Loihi stage of Hawaiian volcanism. A low ³He/⁴He ratio in olivine from one of the picrites indicates a small contribution by the Galápagos mantle plume. Received: 15 December 1997 / Accepted: 6 May 1998     

Cadmium distribution in coastal sediments and mollusks of the US

Cadmium (Cd) concentrations in the coastal United States were assessed using the National Status and Trends (NS&T) Mussel Watch dataset, which is based on the analysis of sediments and bivalves collected from 280 sites since 1986. Using the 1997 sediment data, Pearson correlation (r = 0.44, p < 0.0001) suggested that Cd distributions in sediment can, be to some extent, explained by the proximity of sites to population centers. The 2003 tissue data indicated that “high” Cd concentrations (greater than 5.6 μg/g dry weights [dw] for mussel and 5.4 μg/g dw for oysters) were related to salinity along the East and Gulf coasts. Along the West coast, however, these “high” sites appeared to be related to upwelling phenomenon. Additionally, sedimentary diagenesis was found to be the most likely explanation of why sediment and mollusk Cd content were not well correlated.     

The pitfalls and potential of debt-for-nature swaps: A US-Indonesian case study

The vital role of forests in limiting the likelihood of dangerous climate change has precipitated renewed interest in debt-for-nature swaps. This article uses evidence on past debt-for-nature deals and similar debt mechanisms to assess a recent second wave of such swaps. It outlines five typical shortcomings of this form of financial transaction: that they often fail to deliver additional resources to the debtor country and/or debtor government budget; often fail to deliver more resources for conservation/climate purposes; often have a negligible effect on overall debt burdens (and, as such, do not generate more ‘indirect’ benefits); and are often in conflict with principles of alignment with government policy and alignment with government systems (these two last shortcomings being important elements within the new aid delivery paradigm). Our analysis is applied to a recent debt-for-nature swap between the United States and Indonesia. We show that this case, which we consider a litmus test for current swap practice, performs unevenly across the five shortcomings. First, although the US-Indonesian swap does increase available resources to Indonesia at the country level, it does not generate extra budgetary room for the Indonesian government. Second, the extent to which the resources provided by the swap are additional to other donor support and reserved domestic budget lines for conservation goals is unclear. Third, the swap is too insignificant to create indirect (positive) economic effects. Regarding alignment issues, fourth, the swap is very much in line with current national policy, but, fifth, appears at odds with the new aid delivery paradigm's insistence on system alignment. We argue that if a second generation of debt-for-nature swaps is to be pursued then they need to avoid the common pitfalls associated with this form of finance. Moreover, there is a need to debate broader ways of linking debt service repayments to climate mitigation and adaptation.