Ecological criteria, participant preferences and location models: A GIS approach toward ATV trail planning

This paper presents a geographic information system (GIS)-based method for recreational trail location for all-terrain vehicles (ATVs) which considers environmental factors, as well as rider preferences for trail attributes. The method utilizes the Least-Cost Path algorithm within a GIS framework to optimize trail location. The trail location algorithm considered trail impacts and benefits associated with water bodies, slope, land ownership, noise, trail separation, views, and rider preferences for vegetation types and loop trails. Alternative trails were generated to highlight the influence of different preferences for trail attributes and to demonstrate the capabilities of the Least-Cost Path algorithm as applied to trail location. The method shows promise for use in generating ATV trails, as well as other types of recreational trails, for consideration in recreational planning and analysis.     

Effects of nitrate and phosphate on growth and C2 toxin productivity of Alexandrium tamarense CI01 in culture

Growth and C2 toxin productivity of a marine dinoflagellate, Alexandrium tamarense CI01 (ATCI01) which predominantly produces C2 toxin, were studied in unialgal batch cultures to optimize the concentrations of nitrate and phosphate for a maximal toxin yield. A range of start concentrations of the two major nutrients was determined in which algal growth was proportional to the nutrient concentrations used. The highest concentrations of nitrate and phosphate in this growth-enhancing range were 264 and 20 μM, respectively. In this concentration range, the C2 toxin yield (μg/l) and cellular toxin content (Qt, fmole per cell) reached a maximum at the lowest end of phosphate (5 μM) and the highest end of nitrate (264 μM). Further increase in the supply of nitrate continued to enhance the toxin yield. Our results indicated that the growth and toxin productivity of this algal strain in batch cultures had distinctly different optimal ranges of nitrate and phosphate concentrations. For a maximum toxin yield, a judicious use of phosphate under a nitrate-replete condition is called for.     

Use of a particle-tracking model for predicting entrainment at power plants on the Hudson River

A major assumption of the Empirical Transport Model (ETM), widely adopted by both electric utilities and regulatory agencies for estimating the effects of entrainment mortality on fish populations in estuaries, is that the fraction of ichthyoplankton entrained varies only in response to changes in water withdrawals, not to changes in freshwater flow. We evaluated this assumption using a particle-tracking model to estimmate the probability of entrainment at power plants on the Hudson River during low and high freshwater flow periods and comparing those probabilities with estimates calculated from the ETM. We found that freshwater flow had a profound effect on the probability of entrainment. Both the number of river regions from which particles were entrained and the probabilities of entrainment for particles in those river regions differed between low-flow and high-flow periods. During high flow, particles spent less time in the grid box next to the intakes, reducing the probability of entrainment for particles released in the river region of each power plant and the average probability of entrainment across all regions at three power plants. The reduced probability of entrainment for particles released in the river regions of two power plants was offset by higher entrainment for particles upriver of these power plants. Although the average probabilities of entrainment across all river regions estimated with the particle-tracking model and the ETM were relatively similar for some power plants at high flow, low flow, or both, the probabilities for each river region differed considerably between the models. The number of river regions from which particles were entrained using the ETM was consistently undersestimated, resulting in probabilities for regions where entrainment occurred that were biased high compared with the particle-tracking model.     

Distributed velocity method of solving the convective-dispersion equation: 1. Introduction,mathematical theory,and numerical implementation

This is the first part of a two-part paper presenting a new method for treating convective-dispersive transport. The motivation for developing this technique arises from the demands of performing a risk assessment for a nuclear waste repository. These demands include computational efficiency over a relatively large range of Peclet numbers, the ability to handle chains of decaying radionuclides with rather extreme contrasts in both solution velocities and half lives, and the ability to treat leach- or solubility-limited sources. To the extent it has been tested to date, the distributed velocity method (DVM) appears to satisfy these demands. This part contains an overall introduction and presents the mathematical theory, numerical implementation, and example results.     

FACTOR ANALYSIS OF ELEMENTAL ABUNDANCES IN CHONDRITIC AND ACHONDRITIC METEORITES

Another explorative study of the use of factor analysis in meteorite geochemistry has been made. Forty-two major and trace elements were sought from analyses of 80 stony meteorites in recent articles. Incomplete data reduced the matrix to 30 elements in 55 stones. Missing data were substituted by mean values in the groups CC, (E+H+L+LL) and ACH (13, 28, 14 individuals, respectively): the effect of these substitutions was tested empirically. R-mode analysis with varimax rotation was carried out on these three sub-sets and on the whole set: interpretation focused on factor loadings and scores. Results on the three sub-sets gave little information of geochemical value, although the largest achondrite factor (lithophile elements) permits discrimination of eucrites, aubrites, diogenites and howardites. Analysis of all 55 meteorites showed the variance to be dominated by 1, a refractory-lithophile(Al, Mg, Ca, Zr, Sc, U, Th, La, Eu, Yb) factor, and 2, a volatile-chalcophile (Zn, Te, Cd, Bi, Tl) factor. Factor (1) scores will discriminate chondrites from achondrites: factor (2) scores delineate the compositional trend CC1, CC2, CC3, (E+H+L+LL) except for enstatite chondrites Indarch, Abee which fall with CC1. Further progress would need metal, sulphide and other mineral percentages for each meteorite.     

Control of Fe(III) site occupancy on the rate and extent of microbial reduction of Fe(III) in nontronite

A quantitative study was performed to understand how Fe(III) site occupancy controls Fe(III) bioreduction in nontronite by Shewanella putrefaciens CN32. NAu-1 and NAu-2 were nontronites and contained Fe(III) in different structural sites with 16 and 23% total iron (w/w), respectively, with almost all iron as Fe(III). Mössbauer spectroscopy showed that Fe(III) was present in the octahedral site in NAu-1 (with a small amount of goethite), but in both the tetrahedral and the octahedral sites in NAu-2. Mössbauer data further showed that the octahedral Fe(III) in NAu-2 existed in at least two environments- trans (M1) and cis (M2) sites. The microbial Fe(III) reduction in NAu-1 and NAu-2 was studied in batch cultures at a nontronite concentration of 5 mg/mL in bicarbonate buffer with lactate as the electron donor. The unreduced and bioreduced nontronites were characterized by X-ray diffraction (XRD), Mössbauer spectroscopy, and transmission electron microscopy (TEM). In the presence of an electron shuttle, anthraquinone-2,6-disulfonate (AQDS), the extent of bioreduction was 11%-16% for NAu-1 but 28%-32% for NAu-2. The extent of reduction in the absence of AQDS was only 5%-7% for NAu-1 but 14%-18% for NAu-2. The control experiments with heat killed cells and without cells did not show any appreciable reduction (<2%). The extent of reduction in experiments performed with a dialysis membrane to separate cells from clays (without AQDS) was 2%-3% for NAu-1 but 5%-7% for NAu-2, suggesting that cells probably released an electron shuttling compound and/or Fe(III) chelator. The reduction rate was also faster in NAu-2 than that in NAu-1. Mössbauer data of the bioreduced nontronite materials indicated that the Fe(III) reduction in NAu-1 was mostly from the presence of goethite, whereas the reduction in NAu-2 was due to the presence of the tetrahedral and trans-octahedral Fe(III) in the structure. The measured aqueous Fe(II) was negligible. As a result of bioreduction, the average nontronite particle thickness remained nearly the same (from 2.1 to 2.5 nm) for NAu-1, but decreased significantly from 6 to 3.5 nm for NAu-2 with a concomitant change in crystal size distribution. The decrease in crystal size suggests reductive dissolution of nontronite NAu-2, which was supported by aqueous solution chemistry (i.e., aqueous Si). These data suggest that the more extensive Fe(III) bioreduction in NAu-2 was due to the presence of the tetrahedral and the trans-octahedral Fe(III), which was presumed to be more reducible. The biogenic Fe(II) was not associated with biogenic solids or in the aqueous solution. We infer that it may be either adsorbed onto surfaces of nontronite particles/bacteria or in the structure of nontronite. Furthermore, we have demonstrated that natural nontronite clays were capable of supporting cell growth even in medium without added nutrients, possibly due to presence of naturally existing nutrients in the nontronite clays. These results suggest that crystal chemical environment of Fe(III) is an important determinant in controlling the rate and extent of microbial reduction of Fe(III) in nontronite.     

Correlation of the Hakkoda–Kokumoto Tephra, a widespread Middle Pleistocene tephra erupted from the Hakkoda Caldera, northeast Japan

Abstract A Middle Pleistocene widespread tephra referred to here as Hakkoda–Kokumoto Tephra (Hkd–Ku) has been newly recognized. Hkd–Ku, derived from the Hakkoda Caldera located in northernmost Honshu Is. of northeast Japan, covers much of Honshu Is. At the type locality in the proximal area, Hkd–Ku comprises Plinian pumice deposits and an immediately overlying ignimbrite. The fine vitric ash nature of the distal ash‐fall deposits of Hkd–Ku suggests that they are coignimbrite ash‐fall deposits. Hkd–Ku was identified using a combination of refractive indices and chemical compositions of major, trace and rare earth elements of glass shards, heavy mineral content, refractive indices of orthopyroxene and paleomagnetic polarity. On the basis of these properties, Hkd–Ku was identified in Oga and Boso Peninsulas and Osaka Plain, 830 km southwest of the source. Stratigraphic positions in Boso Peninsula and Osaka Plain within marine sediments that have a reliable chronology based on oxygen‐isotope, and litho‐, bio‐, magneto‐ and tephrostratigraphy indicate that the age of Hkd–Ku is ca 760 ka, positioned in the transition between marine oxygen‐isotope stages 19.1 and 18.4. The widespread occurrence of Hkd–Ku providing a tie line between many different Pleistocene sections over a distance of 800 km is a key marker horizon in the early part of the Middle Pleistocene. This tephra gives a time control point of ca 760 ka to marine sediments in the Oga Peninsula – where no datum plane exists between the Brunhes–Matuyama chron boundary and oxygen‐isotope stage 12 – and to the volcanostratigraphy of the Hakkoda Caldera. The distribution of Hkd–Ku showing emplacement of coignimbrite ash‐fall deposits in the area 830 km southwest of the source emphasizes the upwind transport direction, relative to the prevailing westerly winds, typical of other coignimbrite ash‐fall deposits in the Japanese islands.