Biogeochemical impacts due to mesoscale eddy activity in the Sargasso Sea as measured at the Bermuda Atlantic Time-series Study (BATS)

A comparison of monthly biogeochemical measurements made from 1993 to 1995, combined with hydrography and satellite altimetry, was used to assess the impacts of nine eddy events on primary productivity and particle flux in the Sargasso Sea. Measurements of primary production, thorium-234 flux, nitrate+nitrite, and photosynthetic pigments made at the US JGOFS Bermuda Atlantic Time-series Study (BATS) site were used. During the 3 years of this study, four out of six high thorium-234 flux events occurred during the passage of an eddy. Primary production nearly as high as the spring bloom maximum was observed in two mode-water eddies (May 1993 and July 1995). The 1994 spring bloom at BATS was suppressed by the passage of an anticyclone. Distinct phytoplankton community shifts were observed in mode-water eddies, which had an increased percentage of diatoms and dinoflagellates, and in cyclones, which had an increased percentage of Synechococcus. These variations in species composition within mode-water eddies and cyclones may be associated with the ages of the sampled eddies, and/or differences in physical, chemical, and biological factors in these two distinct eddy types. In general, eddies that were 1–2 months old elicited a large biological response; eddies that were 3 months old may show a biological response and were accompanied by high thorium flux; eddies that were 4 months old or older did not show a biological response or high thorium flux. A conceptual model depicting temporal changes during eddy upwelling, maturation, and decay can explain the observations in all seven upwelling eddies present in the time-series investigated herein.     

Orthodoxy and creativity in theories of mountain building before 1922

In the 1870s, theories of mountain building emerged from little more than speculation to inference based on a growing body of observation and documentation. This coincided with abandonment of models stressing uplift, and their replacement, in the new orthodoxy, by models in which earth contraction led to lateral compression in its outer shell. Nevertheless, perceived weaknesses in this model gave impetus to new theories, some emphasizing primary vertical movement, and others continental displacement or subcrustal flow. The rebel theories added to the understanding of earth processes in important ways, by drawing attention to the weaknesses in the prevailing orthodoxy. But, in 1922, the complete answer remained out of reach.

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Zusammenfassung Die siebziger Jahre des vorigen Jahrhunderts brachten den Anfang von wissenschaftlich fundierten Theorien der Gebirgsbildung. Diese Zeit sah auch den Übergang von Erhebungstheorien zur neuen Lehrmeinung, nach welcher Erdkontraktion zu lateralen Drucken in der Außenhülle der Erde führte. Erkannte Schwächen dieses Modells führten jedoch zu neuen Gegentheorien, von denen einige primäre Vertikalbewegungen in den Vordergrund stellten, während andere Kontinentalverschiebung oder Unterströmungen als den Motor der Gebirgsbildung sahen. Diese Gegentheorien haben den Fortschritt der Erdwissenschaften gefördert, indem sie auf Schwächen der herrschenden Lehrmeinung aufmerksam machten. Aber selbst zu Argands Zeit war ein völlig befriedigendes Modell noch gar nicht erreichbar.

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Résumé C'est dans les années 1870–1880 que commençaient à s'établir les premières théories vraiment scientifiques de l'orogenèse. C'était la décade qui marqua l'abandon des théories à base de soulèvement et le début du règne de la nouvelle orthodoxie d'après laquelle la contraction de la terre mène à la compression latérale d'une pellicule extérieure. Néansmoins, certaines faiblesses du nouveau modèle servaient d'élan à des théories rebelles dont quelques-unes soulignaient l'importance des soulèvements primaires, tandisque d'autres cherchaient le moteur de l'orogenèse dans la dérive des continents ou dans des courants dans une masse quasi-fluide subcrustale. Ces théories rebelles ont avancé la science en soulignant les faiblesses de l'orthodoxie. En fin de compte, une solution complètement satisfaisante ne paraissait pas encore pouvoir être atteinte à l'époque d'Argand.

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Drawdown Distribution in the Vicinity of Nonvertical Wells

Recent developments in subsurface intake systems for ocean desalination plants are considering use of angled wells (slant wells) completed in permeable materials beneath the ocean floor. Conventional drawdown equations for vertical or horizontal wells are inadequate to properly describe the drawdown distribution in the vicinity of slant wells. Using the principle of superposition combined with standard well hydraulics, universal drawdown equations (UDE) are presented which calculate the drawdown distribution in the vicinity of production wells with inclination angles ranging from 0° (horizontal wells) to 90° (vertical wells). The method is computationally simple and other than the normal assumptions for standard well equations, it only requires that the calculated drawdown represent the drawdown which would be measured in a fully penetrating observation well. Solutions using the UDE are developed for confined, unconfined and semi‐confined (leaky) aquifers and compared with analytical equations for vertical and horizontal wells, and with a numerical model for slant wells. The UDE is also applied to pumping test data from the Dana Point slant well project in Southern California.     

Chemical studies of copper-organic complexes isolated from estuarine waters using C18 reverse-phase liquid chromatography

Dissolved organic matter (DOM) and dissolved copper-organic complexes were isolated from the estuarine waters of Narragansett Bay, RI, using reverse-phase liquid chromatography employing C₁₈ Sep-Pak cartridges (Waters Associates). The cartridges were found to have a constant retention efficiency for processing ? 1-l volumes of seawater. Fractionation of the isolated material, by sequential elution of the Sep-Pak with water: methanol mixtures of increasing organic solvent concentration, yielded a fraction of the organic matter with a specific copper activity six times greater than the overall activity for the isolated DOM. Analysis of this fraction by high performance liquid chromatography suggested that the organic components are of intermediate polarity and have appreciable aromatic character.An investigation of the protonation characteristics of the isolated complexes indicated that most of the copper is associated with a broad range of acidic sites on the DOM. Analysis by electron paramagnetic resonance spectroscopy confirmed the organic association of the isolated copper and also suggested the presence of several types of binding sites which probably involve oxygen donor ligands.Studies of the exchange of ⁶⁴Cu with these binding sites on the isolated DOM indicated that 70% of the sites undergo rapid exchange with copper in seawater while 20% of these sites did not exchange in a 24-h time period.     

Exact formulas for approximating variogram function integrals

The application of regionalized variables requires the estimation of the variogram function and the evaluation of its integral. By representing the variogram by a polygonal function the integral may be easily approximated by closed form representations of polygonal integrals. This approach provides a basis for more extensive statistical evaluation not evident in existing approximation methods. This paper provides the closed form representations for two-dimensional variogram functions whose domain is represented by a finite collection of rectangles.     

Scaling Properties of Biologically Active Scalar Concentration Fluctuations in the Atmospheric Surface Layer over a Managed Peatland

The higher-order scalar concentration fluctuation properties are examined in the context of Monin–Obukhov similarity theory for a variety of greenhouse gases that have distinct and separate source/sink locations along an otherwise ideal micrometeorological field site. Air temperature and concentrations of water vapour, carbon dioxide and methane were measured at high frequency (10 Hz) above a flat and extensive peat-land soil in the San Joaquin–Sacramento Delta (California, USA) area, subjected to year-round grazing by beef cattle. Because of the heterogeneous distribution of the sources and sinks of CO₂ and especially CH₄ emitted by cattle, the scaling behaviour of the higher-order statistical properties diverged from predictions based on a balance between their production and dissipation rate terms, which can obtained for temperature and H₂O during stationary conditions. We identify and label these departures as ‘exogenous’ because they depend on heterogeneities and non-stationarities induced by boundary conditions on the flow. Spectral analysis revealed that the exogenous effects show their signatures in regions with frequencies lower than those associated with scalar vertical transport by turbulence, though the two regions may partially overlap in some cases. Cospectra of vertical fluxes appear less influenced by these exogenous effects because of the modulating role of the vertical velocity at low frequencies. Finally, under certain conditions, the presence of such exogenous factors in higher-order scalar fluctuation statistics may be ‘fingerprinted’ by a large storage term in the mean scalar budget.     

The meteorological framework and the cultural memory of three severe winter-storms in early eighteenth-century Europe

Three violent eighteenth-century storms that ravaged the North Sea area (1703), western central Europe (1739) and Portugal (1739) are investigated from the point of view of their meteorological setting, their socio-economic impact, and whether and by what means they secured an enduring place in the cultural memory. The evidence draws on individual narrative sources such as chronicles and poems, and institutional sources such as ship’s logbooks and state-organised ‘windthrow’ inventories of tree loss. Each of the three storms had socio-economic impacts that could be described as ‘war-like’ in the damage caused to buildings and the destruction of forests. The “Great Storm” of December 1703 jeopardized English naval supremacy in the War of the Spanish Succession by sinking a number of Royal Navy ships and taking the life of more than 8000 seamen. In January 1739 two similarly destructive storms swept over mainland Europe. The cultural memory of the three events here considered was however strikingly different. The sequence of storms in January 1739 though being the most protracted of the last centuries, and well-chroniceled, did not persist in the collective memories of those in France, Switzerland and elsewhere who experienced them. Likewise, the “Great Storm” was quickly forgotten on the continent, whereas its memory remained deeply rooted in England through the writings of Defoe (1704). In Portugal the 1739 storm won a lasting place in the country’s cultural memory owing to two poems that it inspired. Furthermore, it was recorded in the Kingdom’s official newspaper, in the astronomical prognoses and in written records of the Old Regime’s cultural elite.