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31.
32.
Summary ?A single-crystal X-ray investigation was performed on crystals of P21/c natural pigeonite with varying Ca and Fe* ( = Fe2+ + Mn2+) contents, in order to verify the effect of microtextural disorder on structure refinements and to constrain the crystal
chemistry of pigeonite. Antiphase domains and exsolution lamellae affect differently the refinement results. In a crystal
free of exsolution the structure obtained after refinement with all reflections is an average of that of the antiphase domains
and of their boundaries, whereas in an exsolved crystal it represents only the structure of the prevailing pigeonite lamellae.
The refinement using only h + k odd reflections seems to give the structure of the Ca-free pigeonite characteristic of the antiphase domains rather than
that of Ca-rich domain walls. The ratio of the scale factors in refinements with all reflections and with only h + k odd reflections allows the ratios of the exsolved augite and pigeonite phases to be estimated.
The crystal chemistry of the investigated samples follows the trends outlined by data on Ca-free and Fe-free synthetic samples.
In particular, it is shown that Ca and Fe* substitution for Mg induce similar changes in the average structure, i.e. both induce an expansion in the M1 polyhedron and
decrease the difference between the M2–O3 distances.
Received October 18, 2001; revised version accepted February 15, 2002 相似文献
33.
We report three new or updated techniques for probing the parameters of active galaxies based on the masses of their central
black holes MBH). First, we derived a near-IR analog of the bulge luminosity versus MBH relationship. The low scatter makes it a promising new tool to study the black hole demographics. Next, we present relations
between MBH and the10 μm and 2-10 keV nuclear luminosity. They may help to study the MBH evolution over wide redshift ranges. Finally, we measured MBH in quasars from z ∼ 3.4 to z ∼ 0.3 to search directly for MBH growth. Surprisingly, we found no evidence for growth implying that the majority of quasar host galaxies have undergone their
last major merger at z ≥ 3.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
34.
35.
36.
The Speckle camera of the 3.5 m Telescopio Nazionale Galileo (TNG) has been used to measure apparent sizes and shapes of a number of main belt asteroids. The average size measurements are in a generally good agreement with the results of indirect IRAS-based radiometric techniques. The measured shapes are compared with predictions based on previously derived spin axis directions and lightcurve photometry of some of the observed objects. Also in this case the agreement is reasonable and the speckle observations allow us to discriminate in some cases between the two pole solutions usually found for each object. No clear evidence of binaries was found. The results show that the TNG speckle camera can be a powerful tool to resolve relatively large main belt asteroids and to calibrate the results of the IRAS survey. 相似文献
37.
The frequent use of soils and earth materials for hydraulic capping and for geo‐environmental waste containment motivated our interest in detailed modelling of changes in size and shape of macro‐pores to establish links between soil mechanical behaviour and concurrent changes in hydraulic and transport properties. The objective of this study was to use finite element analysis (FEA) to test and extend previous analytical solutions proposed by the authors describing deformation of a single macro‐pore embedded in linear viscoplastic soil material subjected to anisotropic remote stress. The FEA enables to consider more complex pore geometries and provides a detailed picture of matrix yield behaviour to explain shortcomings of approximate analytical solutions. Finite element and analytical calculations agreed very well for linear viscous as well as for viscoplastic materials, only limited for the case of isotropic remote stress due to the simplifications of the analytical model related to patterns and onset of matrix‐yielding behaviour. FEA calculations were compared with experimental data obtained from a compaction experiment in which pore deformation within a uniform modelling clay sample was monitored using CAT scanning. FEA predictions based on independently measured material properties and initial pore geometry provided an excellent match with experimentally determined evolution of pore size and shape hence lending credence to the potential use of FEA for more complex pore geometries and eventually connect macro‐pore deformation with hydraulic properties. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
38.
Harold C. CONNOLLY D. S. BURNETT Kevin D. McKEEGAN 《Meteoritics & planetary science》2003,38(2):197-224
Abstract— Minor element variations in MgAl2O4 spinel from the type B1 calcium‐aluminum‐rich inclusion (CAI) Allende TS‐34 confirm earlier studies in showing correlations between the minor element chemistry of spinels with their location within the inclusion and with the chemistry of host silicate phases. These correlations result from a combination of crystallization of a liquid produced by re‐melting event(s) and local re‐equilibration during subsolidus reheating. The correlation of the Ti and V in spinel inclusions with the Ti and V in the adjacent host clinopyroxene can be qualitatively explained by spinel and clinopyroxene crystallization prior to melilite, following a partial melting event. There are, however, difficulties in quantitative modeling of the observed trends, and it is easier to explain the Ti correlation in terms of complete re‐equilibration. The correlation of V in spinel inclusions with that in the adjacent host clinopyroxene also cannot be quantitatively modeled by fractional crystallization of the liquid produced by re‐melting, but it can be explained by partial re‐equilibration. The distinct V and Ti concentrations in spinel inclusions in melilite from the edge regions of the CAI are best explained as being affected by only a minor degree of re‐equilibration. The center melilites and included spinels formed during crystallization of the liquid produced by re‐melting, while the edge melilites and included spinels are primary. The oxygen isotope compositions of TS‐34 spinels are uniformly 16O‐rich, regardless of the host silicate phase or its location within the inclusion. Similar to other type B1 CAIs, clinopyroxene is 16O‐rich, but melilite is relatively 16O‐poor. These data require that the oxygen isotope exchange in TS‐34 melilite occurred subsequent to the last re‐melting event. 相似文献
39.
D. H. Lumb A. Finoguenov R. Saxton B. Aschenbach P. Gondoin M. Kirsch I. M. Stewart 《Experimental Astronomy》2003,15(2):89-111
We describe measurements of the mirror vignetting in the XMM-Newton Observatory made in-orbit, using observations of SNR G21.5-09
and SNR 3C58 with the EPIC imaging cameras. The instrument features that complicate these measurements are briefly described.
We show the spatial and energy dependences of measured vignetting, outlining assumptions made in deriving the eventual agreement
between simulation and measurement. Alternate methods to confirm these are described, including an assessment of source elongation
with off-axis angle, the surface brightness distribution of the diffuse X-ray background, and the consistency of Coma cluster
emission at different position angles. A synthesis of these measurements leads to a change in the XMM calibration data base,
for the optical axis of two of the three telescopes, by in excess of 1 arcmin. This has a small but measureable effect on
the assumed spectral responses of the cameras for on-axis targets.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
40.
J. BERGER O. FEMENIAS J. C. C. MERCIER D. DEMAIFFE 《Journal of Metamorphic Geology》2005,23(9):795-812
The Limousin ophiolite is located at the suture zone between two major thrust sheets in the western French Massif Central. This ophiolitic section comprises mantle‐harzburgite, mantle‐dunite, wehrlites, troctolites and layered gabbros. It has recorded a static metamorphic event transforming the gabbros into undeformed amphibolites and the magmatic ultramafites into serpentinites and/or pargasite‐bearing chloritites. With various thermobarometric methods, it is possible to show that the different varieties of amphibole have registered low‐P (c. 0.2 GPa) conditions with temperature ranging from high‐T, late‐magmatic conditions to greenschist–zeolite metamorphic facies. The abundance of undeformed metamorphic rocks (which is typical of the lower oceanic crust), the occurrence of Ca–Al (–Mg) metasomatism illustrated by the growth of Ca–Al silicates in veins or replacing the primary magmatic minerals, the P–T conditions of the metamorphism and the numerous similarities with oceanic crustal rocks from Ocean Drilling Program and worldwide ophiolites are the main arguments for an ocean‐floor hydrothermal metamorphism in the vicinity of a palaeo‐ridge. Among the West‐European Variscan ophiolites, the Limousin ophiolites constitute an extremely rare occurrence that has not been involved in any HP (subduction‐related) or MP (orogenic) metamorphism as observed in other ophiolite occurrences (i.e. France, Spain and Germany). 相似文献