The evolution of the Parece Vela Basin,eastern Philippine Sea

The Parece Vela Basin is a back-arc basin. It is approximately 5000 m deep and is divided into two topographic provinces by the north-trending Parece Vela Rift. The western province is thinly sedimented and topographically rough. The eastern province is blanketed by a thick apron of volcaniclastic sediments which were derived from the West Mariana Ridge. The Parece Vela Rift is composed of a series of discrete deeps and troughs with depths commonly of 6 km and locally exceeding 7 km.Petrologic and seismic refraction data indicate that the Parece Vela Basin is of oceanic character.Low-amplitude, nort-trending, lineated magnetic anomalies are present in the basin and appear symmetric about a line near the Parece Vela Rift. In the central latitudes of the basin seafloor spreading anomalies 10 (30 m.y. B.P.) to 5E or 5D (18 or 17 m.y. B.P.) can be identified. The uncertainty in identifying the youngest anomaly may be due to ridge jumps near the end of spreading. Spreading may have started slightly later in the northern end of the basin. Anomalies in the eastern province are disrupted and are difficult to correlate. DSDP results indicate post-spreading volcanism on the eastern side of the basin and this may have degraded the anomalies. The age obtained in the western province of the basin at DSDP Site 449 (～25m.y. B.P.) is in close agreement with that obtained from the magnetic data (～26m.y. B.P.).It is hypothesized that subduction was occurring at a west-dipping subduction zone east of the Palau-Kyushu Ridge in the Early Oligocene. This volcanic arc split about 31 or 32 m.y. ago and interarc spreading was initiated between the Palau-Kyushu Ridge (which then became a remnant arc) and the West Mariana Ridge. The Parece Vela Basin formed between the ridges by two-limb seafloor spreading. Spreading stopped about 17 or 18 m.y. ago.Like certain other marginal basins, the Parece Vela Basin is deeper than predicted from depth vs. age curves. The average heat flow for the Parece Vela Basin is in agreement with that predicted from heat flow vs. age curves.The origin of the Parece Vela Rift is unclear. It may represent the extinct spreading center or may be a postspreading feature.     

Impacts of land use and fire on the loss and degradation of lowland forest in 1983–2000 in East Kutai District, East Kalimantan, Indonesia

Deforestation and forest degradation are proceeding rapidly in the lowland forests of Indonesian Borneo. Time series analysis of satellite imagery provides an ideal means of quantifying landscape change and identifying the pathways which lead to the changes. This study investigates the forest and land cover changes by classifying Landsat MSS (Multispectral Scanner), TM (Thematic Mapper) and ETM+ (Enhanced Thematic Mapper Plus) images over three time periods (1983–90, 1990–98, and 1998–2000), creating land cover maps for each year and change trajectories for each year-pair. The study area chosen covers an area of 2160 km² of undulating topography and alluvial plains in the East Kutai District of East Kalimantan Province, which in the 1980s was covered mostly with lowland dipterocarp forest; today the landscape is a patchwork dominated by oil palm and timber plantations and degraded forest. We relate land cover change data to land use allocation and to fire impacts based on fire hotspot distribution and fire damage information. The multidate land cover change trajectories provide an insight into the forest loss and degradation pathways over the 17-year period spanning the first entry of commercial logging concessionaires, followed by a government-sponsored transmigration scheme, government-licensed timber and oil palm plantations and, finally, the devastating fires of 1998. The results show a mean deforestation rate of 42 km² or 6 per cent per year for 1983–2000, rising to 10 per cent per year for 1990–98; by 2000, 70 per cent of forest initially damaged by fire and drought during the 1982–83 El Niño event was classified as non-forest. Although our study area is perhaps a worst-case scenario in terms of land use planning outcomes, the lessons from this research are directly applicable to scenario prediction for informed forest and land use planning and monitoring.     

A preliminary methods comparison for measurement of dissolved organic nitrogen in seawater

Routine determination of dissolved organic nitrogen (DON) is performed in numerous laboratories around the world using one of three families of methods: UV oxidation (UV), persulfate oxidation (PO), or high temperature combustion (HTC). Essentially all routine methods measure total dissolved nitrogen (TDN) and calculate DON by subtracting the dissolved inorganic nitrogen (DIN). While there is currently no strong suggestion that any of these methods is inadequate, there are continuing suspicions of slight inaccuracy by UV methods.This is a report of a broad community methods comparison where 29 sets (7 UV, 13 PO, and 9 HTC) of TDN analyses were performed on five samples with varying TDN and DIN concentrations. Analyses were done in a “blind” procedure with results sent to the first author. With editing out one set of extreme outliers (representing 5 out of 145 ampoules analyzed), the community comparability for analyzing the TDN samples was in the 8–28% range (coefficient of variation representing one standard deviation for the five individual samples by 28 analyses). When DIN concentrations were subtracted uniformly (single DIN value for each sample), the comparability was obviously worse (19–46% cv). This comparison represents a larger and more diverse set of analyses, but the overall comparability is only marginally better than that of the Seattle workshop of a decade ago. Grouping methods, little difference was seen other than inconclusive evidence that the UV methods gave TDN values for several of the samples higher than HTC methods. Since there was much scatter for each of the groups of methods and for all analyses when grouped, it is thought that more uniformity in procedures is probably needed. An important unplanned observation is that variability in DIN analyses (used in determining the final analyte in most UV and PO methods) is essentially as large as the variability in the TDN analyses.This exercise should not be viewed as a qualification exercise for the analysts, but should instead be considered a broad preliminary test of the comparison of the families of methods being used in various laboratories around the world. Based on many independent analyses here, none of the routinely used methods appears to be grossly inaccurate, thus, most routine TDN analyses being reported in the literature are apparently accurate. However, it is not reassuring that the ability of the international community to determine DON in deep oceanic waters continues to be poor. It is suggested that as an outgrowth of this paper, analysts using UV and PO methods experiment and look more carefully at the completeness of DIN conversion to the final analyte and also at the accuracy of their analysis of the final analyte. HTC methods appear to be relatively easy and convenient and have potential for routine adoption. Several of the authors of this paper are currently working together on an interlaboratory comparison on HTC methodology.     

Aggregation of montmorillonite and organic matter in aqueous media containing artificial seawater

Background  

The dispersion-aggregation behaviors of suspended colloids in rivers and estuaries are affected by the compositions of suspended materials (i.e., clay minerals vs. organic macromolecules) and salinity. Laboratory experiments were conducted to investigate the dispersion and aggregation mechanisms of suspended particles under simulated river and estuarine conditions. The average hydrodynamic diameters of suspended particles (representing degree of aggregation) and zeta potential (representing the electrokinetic properties of suspended colloids and aggregates) were determined for systems containing suspended montmorillonite, humic acid, and/or chitin at the circumneutral pH over a range of salinity (0 – 7.2 psu).     

Evaluation of the snow‐covered area data product from MODIS

The Moderate Resolution Imaging Spectroradiometer (MODIS), flown on board the Terra Earth Observing System (EOS) platform launched in December 1999, produces a snow‐covered area (SCA) product. This product is expected to be of better quality than SCA products based on operational satellites (notably GOES and AVHRR), due both to improved spectral resolution and higher spatial resolution of the MODIS instrument. The gridded MODIS SCA product was compared with the SCA product produced and distributed by the National Weather Service National Operational Hydrologic Remote Sensing Center (NOHRSC) for 46 selected days over the Columbia River basin and 32 days over the Missouri River basin during winter and spring of 2000–01. Snow presence or absence was inferred from ground observations of snow depth at 1330 stations in the Missouri River basin and 762 stations in the Columbia River basin, and was compared with the presence/absence classification for the corresponding pixels in the MODIS and NOHRSC SCA products. On average, the MODIS SCA images classified fewer pixels as cloud than NOHRSC, the effect of which was that 15% more of the Columbia basin area could be classified as to presence–absence of snow, while overall there was a statistically insignificant difference over the Missouri basin. Of the pixels classified as cloud free, MODIS misclassified 4% and 5% fewer overall (for the Columbia and Missouri basins respectively) than did the NOHRSC product. When segregated by vegetation cover, forested areas had the greatest differences in fraction of cloud cover reported by the two SCA products, with MODIS classifying 13% and 17% less of the images as cloud for the Missouri and Columbia basins respectively. These differences are particularly important in the Columbia River basin, 39% of which is forested. The ability of MODIS to classify significantly greater amounts of snow in the presence of cloud in more topographically complex, forested, and snow‐dominated areas of these two basins provides valuable information for hydrologic prediction. Copyright © 2003 John Wiley & Sons, Ltd.     

Variability and trends in the annual snow‐cover cycle in Northern Hemisphere land areas, 1972–2000

This study investigated variability and trends in the annual snow‐cover cycle in regions covering high‐latitude and high‐elevation land areas in the Northern Hemisphere. The annual snow‐cover cycle was examined with respect to the week of the last‐observed snow cover in spring (WLS), the week of the first‐observed snow cover in autumn (WFS), and the duration of the snow‐free period (DSF). The analysis used a 29‐year time‐series (1972–2000) of weekly, visible‐band satellite observations of Northern Hemisphere snow cover from NOAA with corrections applied by D. Robinson of Rutgers University Climate Laboratory. Substantial interannual variability was observed in WLS, WFS and DSF (standard deviations of 0·8–1·1, 0·7–0·9 and 1·0–1·4 weeks, respectively), which is related directly to interannual variability in snow‐cover area in the regions and time periods of snow‐cover transition. Over the nearly three‐decade study period, WLS shifted earlier by 3–5 days/decade as determined by linear regression analysis. The observed shifts in the annual snow‐cover cycle underlie a significant trend toward a longer annual snow‐free period. The DSF increased by 5–6 days/decade over the study period, primarily as a result of earlier snow cover disappearance in spring. The observed trends are consistent with reported trends in the timing and length of the active growing season as determined from satellite observations of vegetation greenness and the atmospheric CO₂ record. Copyright © 2002 John Wiley & Sons, Ltd.     

Evaluation of extraction schemes for organic matter in anoxic estuarine sediments

A persistent criticism of studies of organic matter in sediments and soils has been that the extracted products used in these investigations may not resemble the original material, particularly if harsh extractants such as NaOH, Na₄P₂O₇ or HCl are employed. To minimize chemical changes, a mild separation procedure has been developed for obtaining soluble organic matter from anoxic estuarine sediments. The resulting complex mixture of organic compounds can be analyzed by reversed-phase liquid and size-exclusion chromatographic methods, which monitor the relative molecular polarity and size, respectively. The effects of the strong reagents NaOH, Na₄P₂O₇ and HCl, as well as exposure to the atmosphere and bacterial activity on this anoxic sedimentary extract has been investigated. In each instance, significant degradation of anoxic organic matter occurs, producing molecules of increased polarity and reduced molecular weight. These data indicate that extreme care is necessary to avoid artifacts in preparation and handling of samples.