Bytran - |- spectral calculations for portable devices using the HITRAN database

We describe a user-friendly open-source cross-platform radiative transfer application called bytran targeting mobile devices we developed using Qt/C ++ for the calculation of molecular and atmospheric absorption of gases under user-defined meteorological conditions and for specified gas mixture concentrations. Bytran is based in part on the HITRAN Application Programming Interface (HAPI) source code and relies on data provided in the online version of the High-Resolution Transmission Molecular Absorption Database (HITRAN) for line-by-line calculations. The novelty of the implementation is the usage of the recently introduced HITRANonline database (HITRAN.org), native execution of the line-by-line calculations on portable electronics hardware, and the cross-platform open-source implementation which also allows compilation of the bytran source code for desktop operating systems and embedded development boards. The application has the potential of becoming useful for in-the-field scientific evaluations as well as an educational tool for students studying spectroscopy and related subjects. Additional availability of the application under desktop environments further expands the possible usability of the developed software for in-the-lab settings. Ongoing work includes optional usage of pressure, temperature and humidity sensors available in selected cell phone models and the Raspberry Pi Sense Hat add-on board to generate spectra based on detected ambient meteorological conditions.     

Data-Assimilative Hindcast and Climate Forecast of Storm Surges with an ASGF Regression Model

ABSTRACT

This study demonstrates that long-term climate model solutions can be efficiently converted to storm surge time series at points of interest (POIs) for the future. The all-source Green's function (ASGF) regression model is used for this conversion. In addition to being data assimilative, the ASGF regression model can also simulate storm surges at a POI faster than the traditional modelling approach by orders of magnitude. This is demonstrated using the tidal gauge at Sept-Îles (Quebec, Canada) in the Gulf of St. Lawrence as the POI. First the ASGF regression model is used to assimilate 32 years of tidal gauge data, producing a continuous hindcast of storm surges and a set of best-estimate regression parameters. Second, the ASGF regression model with the best-estimate parameters is used to convert a Canadian Regional Climate Model solution (CRCM/AHJ) to an hourly time series of storm surges from 1961 to 2100. Gumbel's extreme value analysis (EVA) is then applied to the time series as a whole and also to tri-decadal segments. The tri-decadal approach is used to investigate whether there is any progressive shortening or lengthening of storm surge return periods as a result of future climate change. A method for correcting for bias due to the forcing field at the EVA level is also demonstrated.     

情理整合视角下旅游者环境责任行为与 意愿悖离研究——基于Logistic-ISM模型

基于对岳麓山景区447位旅游者的实地调研,运用拓展的计划行为理论并结合Logistic回归模型,分析影响两者发生悖离的因素,并进一步利用ISM解释结构模型分析各因素之间的逻辑关系.从Logistic回归结果看,旅游者的行为态度、感知行为控制等相关理性认知越好,发生悖离的可能性越低;旅游者积极环境情感和消极环境情感对悖离...     

Length of the day and evolution of the Earth's core in the geological past

In this paper, we study quantitatively the effect of the Earth's core formation on the secular rate of change of the length of day (LOD). We find that for the present epoch, a growth rate of the core comprised between 1 and 10 mm/cy seems to be a plausible guess, leading to a relative de crease of LOD comprised roughly between 10 and 100 μs/cy. Such values do not affect significantly the observed secular in crease of LOD caused by tidal braking, which amounts to about 1.79 ms/cy. However, in the remote geological past, before the Phanerozoic, the effects of core growth may have been much more important, because the total change of LOD associated with core formation has been estimated by Birch in 1965 to be 2.4 hours for an initially undifferentiated cold Earth, and 3.1 hours for an initially undifferentiated hot Earth. We consider a number of scenarios, some of them corresponding to very early and/or very fast core formation, others corresponding to slow and/or late core formation. We show that palaeo‐LOD measurements seem to favour slow core formation during the Proterozoic, contrarily to the now largely prevailing hypothesis based on geochemical arguments that the iron core formed very early in the Earth's history and during a geologically short time interval (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Trace-element heterogeneity in rutile linked to dislocation structures: Implications for Zr-in-rutile geothermometry

The trace-element composition of rutile is commonly used to constrain P–T–t conditions for a wide range of metamorphic systems. However, recent studies have demonstrated the redistribution of trace elements in rutile via high-diffusivity pathways and dislocation-impurity associations related to the formation and evolution of microstructures. Here, we investigate trace-element migration in low-angle boundaries formed by dislocation creep in rutile within an omphacite vein of the Lago di Cignana unit (Western Alps, Italy). Zr-in-rutile thermometry and inclusions of quartz in rutile and of coesite in omphacite constrain the conditions of rutile deformation to around the prograde boundary from high pressure to ultra-high pressure (~2.7 GPa) at temperatures of 500–565°C. Crystal-plastic deformation of a large rutile grain results in low-angle boundaries that generate a total misorientation of ~25°. Dislocations constituting one of these low-angle boundaries are enriched in common and uncommon trace elements, including Fe and Ca, providing evidence for the diffusion and trapping of trace elements along the dislocation cores. The role of dislocation microstructures as fast-diffusion pathways must be evaluated when applying high-resolution analytical procedures as compositional disturbances might lead to erroneous interpretations for Ca and Fe. In contrast, our results indicate a trapping mechanism for Zr.