Linking a linear pockmark train with a buried Palaeozoic structure: a case study from the St. Lawrence Estuary

The 15-km-long Matane pockmark train belongs to a series of NNE-striking alignments of pockmarks mapped on the seafloor of the St. Lawrence Estuary. It includes 109 pockmarks that show a complete transition from well-defined, relatively deep (up to 8.6 m), crater-like depressions to subtle, partly buried morphological features, suggesting that pockmarks have formed at different periods along the whole alignment and that the location of fluid release has changed through time. On seismic profiles, pockmarks are characterized by vertical seismic chimneys that root in the (fractured?) hinge zone of an open anticline within the autochthonous Palaeozoic rocks of the St. Lawrence Platform. In absence of a geochemical characterization of expelled gas, the relationship between the Matane pockmark train and the anticline in a domain characterized by mature source rocks is the strongest evidence for the genetic link between pockmarks and the release of gas from an active hydrocarbon system or a reservoir located in the Palaeozoic succession.

A coarse-scale compositional model

In subsurface flow modeling, compositional simulation is often required to model complex recovery processes, such as gas/CO ₂ injection. However, compositional simulation on fine-scale geological models is still computationally expensive and even prohibitive. Most existing upscaling techniques focus on black-oil models. In this paper, we present a general framework to upscale two-phase multicomponent flow in compositional simulation. Unlike previous studies, our approach explicitly considers the upscaling of flow and thermodynamics. In the flow part, we introduce a new set of upscaled flow functions that account for the effects of compressibility. This is often ignored in the upscaling of black-oil models. In the upscaling of thermodynamics, we show that the oil and gas phases within a coarse block are not at chemical equilibrium. This non-equilibrium behavior is modeled by upscaled thermodynamic functions, which measure the difference between component fugacities among the oil and gas phases. We apply the approach to various gas injection problems with different compositional features, permeability heterogeneity, and coarsening ratios. It is shown that the proposed method accurately reproduces the averaged fine-scale solutions, such as component overall compositions, gas saturation, and density solutions in the compositional flow.     

Stability of massive ground ice bodies in University Valley,McMurdo Dry Valleys of Antarctica: Using stable O–H isotope as tracers of sublimation in hyper-arid regions

To date, studies of the stability of subsurface ice in the McMurdo Dry Valleys of Antarctica have been mainly based on climate-based vapor diffusion models. In University Valley (1800 m), a small glacier is found at the base of the head of the valley, and adjacent to the glacier, a buried body of massive ice was uncovered beneath 20–40 cm of loose cryotic sediments and sandstone boulders. This study assesses the origin and stability of the buried body of massive ice by measuring the geochemistry and stable O–H isotope composition of the ice and applies a sublimation and molecular diffusion model that accounts for the observed trends. The results indicate that the buried massive ice body represents an extension of the adjacent glacier that was buried by a rock avalanche during a cold climate period. The contrasting δ¹⁸O profiles and regression slope values between the uppermost 6 cm of the buried massive ice (upward convex δ¹⁸O profile and S_D-18O = 5.1) and that below it (progressive increase in δ¹⁸O and S_D-18O = 6.4) suggest independent post-depositional processes affected the isotope composition of the ice. The upward convex δ¹⁸O profile in the uppermost 6 cm is consistent with the ice undergoing sublimation. Using a sublimation and molecular diffusion model, and assuming that diffusion occurred through solid ice, the sublimation rate needed to fit the measured δ¹⁸O profile is 0.2 ? 10^? 3 mm yr^? 1, a value that is more similar to net ice removal rates derived from ³He data from cobbles in Beacon Valley till (7.0 ? 10^? 3 mm yr^? 1) than sublimation rates computed based on current climate (0.1–0.2 mm yr^?1). We suggest that the climate-based sublimation rates are offset due to potential ice recharge mechanisms or to missing parameters, particularly the nature and thermo-physical properties of the overlying sediments (i.e., temperature, humidity, pore structure and ice content, grain size).     

Assessing the long-term impact of climatic variability and human activities on the water resources of a meso-scale Mediterranean catchment

Abstract

This article addresses the critical need for a better quantitative understanding of how water resources from the Hérault River catchment in France have been influenced by climate variability and the increasing pressure of human activity over the last 50 years. A method is proposed for assessing the relative impacts of climate and growing water demand on the decrease in discharge observed at various gauging stations in the periods 1961–1980 and 1981–2010. An annual water balance at the basin scale was calculated first, taking into account precipitation, actual evapotranspiration, water withdrawals and water discharge. Next, the evolution of the seasonal variability in hydroclimatic conditions and water withdrawals was studied. The catchment was then divided into zones according to the main geographical characteristics to investigate the heterogeneity of the climatic and human dynamics. This delimitation took into account the distribution of climate, topography, lithology, land cover and water uses, as well as the availability of discharge series. At the area scale, annual water balances were calculated to understand the internal changes that occurred in the catchment between both past periods. The decrease in runoff can be explained by the decrease in winter precipitation in the upstream areas and by the increase during summer in both water withdrawals and evapotranspiration in the downstream areas, mainly due to the increase in temperature. Thus, water stress increased in summer by 35%. This work is the first step of a larger research project to assess possible future changes in the capacity to satisfy water demand in the Hérault River catchment, using a model that combines hydrological processes and water demand.

Editor Z.W. Kundzewicz     

Cave bear occupation in Schwabenreith Cave,Austria, during the early last glacial: constraints from 230Th/U‐dated speleothems

The cave bear was a prominent member of the Upper Pleistocene fauna in Eurasia. While breakthroughs were recently achieved with respect to its phylogeny using ancient DNA techniques, it is still challenging to date cave bear fossils beyond the radiocarbon age range. Without an accurate and precise chronological framework, however, key questions regarding the palaeoecology cannot be addressed, such as the extent to which large climate swings during the last glacial affected the habitat and possibly even conditioned the final extinction of this mammal. Key to constraining the age of cave bear fossils older than the lower limit of radiocarbon dating is to date interlayered speleothems using ²³⁰Th/U. Here we report new results from one such site in the Eastern European Alps (Schwabenreith Cave), which yielded the highest density of bones of cave bear (Ursus spelaeus eremus). Although dating of the flowstones overlying this fossiliferous succession was partly compromised by diagenetic alteration, the ²³⁰Th/U dates indicate that the bear hibernated in this cave after about 113 ka and before about 109 ka. This time interval coincides with the equivalent of Greenland Stadial 25, suggesting possible climate control on the cave bear's habitat and behaviour. © 2019 The Authors. Journal of Quaternary Science Published by John Wiley & Sons Ltd     

Model simulations of the annual cycle of the landfast ice thickness in the East Siberian Sea

The annual cycle of the thickness and temperature of landfast sea ice in the East Siberian Sea has been examined using a one-dimensional thermodynamic model. The model was calibrated for the year Augus...     

OMEGA long wavelength channel: Data reduction during non-nominal stages

The Observatoire pour la Minéralogie, l’Eau, les Glaces et l’Activité (OMEGA) instrument is a visible and near-infrared imaging spectrometer on board the European Mars Express (MEx) mission. The on-board calibration (OBC) performed at the beginning of observations on each orbit reveals that the photometric response of the C channel (1.0–2.5 μm) has been very stable since orbit insertion in January 2004. On the contrary the L channel (2.5–5.1 μm) response has varied significantly during the mission, and only orbits for which the response is close to nominal could be used with confidence. The spatial coverage of ice-free surfaces in this wavelength range is consequently limited to only ～30%, mainly during northern spring and summer. This paper presents the empirical method used to derive new instrumental transfer functions (ITF) for the non-nominal orbits. This method consists of analyzing the variation of the signal between several observations of a same region acquired at nominal and non-nominal calibration states. In the cases where the mineralogy and the atmospheric conditions between the two observations are the same, the variation in reflectance spectra is only due to the ITF variation, which provides a new ITF. We then associate these new ITFs with their corresponding OBCs to model a relationship between both. The resulting model enables us to provide a new ITF for each orbit for which the OBC is available. The new ITFs derived for the entire dataset have been validated (1) through a comparison of the C and L channel global albedo trends and (2) through a comparison of the surface temperatures derived from the L channel with those calculated from the General Circulation Model (GCM) numerical simulation of the LMD released in the Martian Climate Database. The non-nominal data processed with adapted ITFs for orbits up to 3050 increase the non-icy surface coverage of Mars to ～70% including all seasons.     

Acid drainage generation and associated Ca-Fe-SO4 minerals in a periglacial environment, Eagle Plains, Northern Yukon, Canada: A potential analogue for low-temperature sulfate formation on Mars

Near Eagle Plains, northern Yukon, Canada, acidic Ca-Fe-Mg sulfate waters are discharging year-long from disturbed permafrosted sandstone bedrock overlying pyritiferous black shales. These acidic waters are precipitating gypsum with minor amounts of jarosite-K (Na), schwertmannite and hematite. This mineral assemblage is similar to that observed at Meridiani Planum (and other location on Mars), making this site a valuable analogue for low-temperature sulfate geochemistry and mineral formation on Mars. Stable O-S isotope analysis of the acidic waters near Eagle Plains revealed that the oxygen in the dissolved sulfate is mostly derived from water (ca. 70%), suggesting that the sulfide oxidation process could be in part biomediated (i.e., accelerated by acidophilic Fe-oxidizing bacteria). However, unlike the dissolved sulfate in the waters, the formation of the Ca-Fe-SO₄ minerals appears to be purely abiotic. The stable O-S isotope composition of the sulfate minerals is well within the predicted equilibrium range at low temperature, suggesting that they formed through physico-chemical processes (i.e., evaporation or freezing). Low-temperature geochemical modeling with FREZCHEM and PHREEQC suggests that the mineral assemblage at Eagle Plains precipitated mainly through the freezing of Ca-Fe-Mg-SO₄ acidic waters, rather than through evaporation during the dry summer season, although the latter is still possible. This suggests that the sulfate mineral assemblage observed on Mars could have also formed under a periglacial-type climate. Considering that the active layer in the zone affected by acid drainage does not freeze-over during winter, the residual talik offers a localized niche environment to support acidophilic microorganisms. Overall, the fact that acid drainage is presently active near Eagle Plains allows the direct observation of the low-temperature geochemical processes responsible for generating acid drainage conditions and precipitation of gypsum, schwertmannite, jarosite-K, jarosite-Na, goethite and hematite.