It becomes increasingly important and challenging for nitrogen pollution prevention to identify key controls for spatial variability of nitrogen in groundwater that could be affected by multiple factors, including anthropogenic input, groundwater flow, and local geochemistry. This study characterized spatial variability of both nitrate and ammonium in the Pleistocene aquifer of central Yangtze River Basin and assessed the effect of various factors in controlling nitrate and ammonium levels based on multiple statistical approaches (correlation, geostatistics, multiple liner regression). The results indicate that nitrate is mostly influenced by Cl− that represents anthropogenic input, while Eh representing local redox state is a secondary variable influencing nitrate concentrations. The groundwater with elevated nitrate concentrations are estimated to occur mainly in areas with higher-permeability near-surface sediments which can facilitate more anthropogenic nitrate transport and less nitrate removal owing to more oxidized state. Ammonium is mostly correlated to Eh, followed by dissolved organic carbon (DOC), but only DOC improves significantly the accuracy of co-kriging prediction model. The groundwater with elevated ammonium concentrations are estimated to occur mainly in areas with more organic-rich sediments within or around the aquifer which can facilitate more ammonium release owing to natural organic matter consumption accompanying strong reducing conditions. The regional groundwater flow is not a factor significantly controlling nitrate or ammonium levels owing to flat topography and sluggish lateral flow. 相似文献
Paleomagnetic samples were collected from four localities located in the southern rim of the Tarim basin. The samples were taken from volcanic rocks erupted between Jurassic and Quaternary. Detailed analysis of all samples has been carried out with progressive thermal demagnetization. A characteristic remanence (ChRM) with higher unblocking temperature has been isolated from all samples. The pole position from the middle Jurassic is at 52.5°N, 187.9°E(dp = 3.7°,dm =6.5°); the directions of the ChRM of Cretaceous correspond to a paleopole at 69.7°N, 211.6°E (dp = 9.8°,dm = 15.9°); the Quaternary pole from the Pulu site is at 79. 9°N, 183.1°E(dp = 1.6°.dm =2.4°). On the basis of these new paleomagnetic data, tectonic evolution of Tarim block is presented.
In this study, bench‐scale experiments were conducted to examine the UV/H2O2 oxidation of 17α‐ethynyestradiol (EE2) in water in a batch operation mode. The EE2 degradation exhibited pseudo‐first‐order kinetics, and the removal was ascribed to the production of hydroxyl radicals (?OH) by the UV/H2O2 system. Typically, the EE2 oxidation rate increased with increasing UV intensity and H2O2 dose, and with deceasing initial EE2 levels and solution pH. At EE20 = 650 µg/L, UV intensity = 154 µW/cm2, H2O2 = 5 mg/L, and neutral pH, the UV/H2O2 treatment was able to remove 90% of the EE2 content within 30 min. Four anions commonly present in water were found to inhibit EE2 degradation to varying degrees: > > Cl? > . Our results demonstrate that the described UV/H2O2 process is an effective method to control EE2 pollution in water. 相似文献