Diatom quantification and their distribution with salinity brines in coastal sediments of Terra Nova Bay (Antarctica)

Benthic diatoms represent an important element of global nutritional productivity; to raise attention on their role, which is often neglected due to analytical difficulties, surface (1 cm top layer) coastal sediments from Gerlache inlet to Penguin Bay at Terra Nova Bay were collected and stored at -20 °C. DNA amplification by real-time PCR, based on diatom-specific oligonucleotide primers designed on small-subunit rRNA (SSU rRNA), was performed in addition to diatom conventional cell counting and spectrophotometric determination of photo-pigments. Moreover, cations and anions were determined in sediments with the aim to identify factors involved in the control of diatom abundance. Diatom distribution was found quite heterogeneous displaying significant differences from site to site. The salinity in sediments ranged from 45.1 at Gerlache inlet to 76.2 at Penguin Bay and it was correlated with cell abundance, biodiversity, amount of pigments and amplified DNA. The dominant species, Fragilariopsis curta, was associated to sediment salinity brines.     

The amphipod Talitrus saltator as a bioindicator of human trampling on sandy beaches

The present paper assesses the use of the supralittoral amphipod Talitrus saltator as a bioindicator of the effects of human trampling on the supralittoral sandy band. Samplings in delimited areas were carried out at sites subjected to different human impact. The results showed a strong negative correlation between the number of swimmers and the sandhopper population density, while there was no clear relationship between sandhopper abundance and the other factors considered: granulometry, compactness and organic carbon content of the sand, and trace metal contents in the sand and sandhoppers. A field test of trampling conducted in a confined space showed its direct negative effect on sandhopper survival. However, trace metal analysis confirmed the ability of T. saltator to bioaccumulate some elements (Hg, Zn, Cu, Cd). Our study demonstrates that T. saltator is a good bioindicator of human impact in the supralittoral zone of sandy shores.     

Mechanisms linking active rock glaciers and impounded surface water formation in high‐mountain areas

Rock glaciers are slowly flowing mixtures of debris and ice occurring in mountains. They can represent a reservoir of water, and melting ice inside them can affect surface water hydrochemistry. Investigating the interactions between rock glaciers and water bodies is therefore necessary to better understand these mechanisms. With this goal, we elucidate the hydrology and structural setting of a rock glacier–marginal pond system, providing new insights into the mechanisms linking active rock glaciers and impounded surface waters. This was achieved through the integration of waterborne geophysical techniques (ground penetrating radar, electrical resistivity tomography and self‐potentials) and heat tracing. Results of these surveys showed that rock glacier advance has progressively filled the valley depression where the pond is located, creating a dam that could have modified the level of impounded water. A sub‐surface hydrological window connecting the rock glacier to the pond was also detected, where an inflow of cold and mineralised underground waters from the rock glacier was observed. Here, greater water contribution from the rock glacier occurred following intense precipitation events during the ice‐free season, with concomitant increasing electrical conductivity values. The outflowing dynamic of the pond is dominated by a sub‐surface seepage where a minor fault zone in bedrock was found, characterised by altered and highly‐fractured rocks. The applied approach is evaluated here as a suitable technique for investigating logistically‐complex hydrological settings which could be possibly transferred to wider scales of investigation. Copyright © 2017 John Wiley & Sons, Ltd.     

Seismic design of floor–wall joints of multi-storey CLT buildings to comply with regularity in elevation

The effects of irregularity in elevation of cross-laminated timber buildings have not been fully analysed in literature to provide useful information for the design. In this work, a number of building configurations, regular or irregular in elevation, characterized by a different arrangement per storey of the floor–wall joints have been analysed by means of non-linear dynamic analyses. Comparative results in terms of ratio between the behaviour q-factor of the investigated irregular configurations and that of reference regular ones, show that less dissipative capacity can be expected if the building is irregular due to a disequilibrium among storeys between the actual and the required strength provided by the floor–wall joints. A correlation method to estimate the behaviour q-factor for perfectly regular cross-laminated timber buildings is here presented and extended to in-elevation irregular ones. A new empirical formulation to assess the reliable corrective factor accounting for the irregularity in elevation of cross-laminated timber buildings, according to Eurocode 8 provisions, is also proposed. A final discussion about the implications of in-elevation irregularity on the building design is reported.     

Deep tunnel fronts in cohesive soils under undrained conditions: a displacement-based approach for the design of fibreglass reinforcements

The fronts of tunnels excavated under particularly difficult ground conditions by employing conventional tunnelling methods are commonly supported: the stabilization is usually achieved either by improving the mechanical properties of the soil (injections, jet grouting, soil freezing, etc.) or by introducing linear inclusions. This last technique, consisting in the introduction of pipes (usually made of fibreglass reinforced polymers) in the front, is particularly popular since it is very simple to adapt the reinforcement geometry, length and number to the different conditions encountered during the excavation. The design of this reinforcement technique is nowadays based on very simplified approaches: on either empirical formula or the limit equilibrium method. In a previous paper, the authors numerically studied the mechanical response of unreinforced fronts in cohesive soils and defined a non-dimensional front characteristic curve. In this paper, the authors intend to take into consideration the role of reinforcements by following the same approach. A procedure allowing the definition of the reinforced non-dimensional front characteristic curve, once the reinforcement pattern is assigned, is introduced. The practical use of this curve is described.

     

Detection of Miocene saucer‐shaped sills (offshore Senegal) via integrated interpretation of seismic,magnetic and gravity data

The Atlantic margin offshore Senegal has been explored by seismic reflection and GRAV‐MAG surveys. High‐amplitude, laterally transgressive seismic reflectors are found to coincide with gravimetric and magnetic highs. Once seismic data are integrated with potential fields modelling, these reflectors can be safely interpreted as saucer‐shaped igneous sills, up to some hundreds of metres thick, some km wide. The occurrence of hydrothermal vent complexes and forced folds in the stratigraphic sequence above the sills constrain the intrusion age to the Miocene. Field observations and in‐situ magnetic susceptibility measurements of Oligocene–Miocene and Quaternary igneous rocks emplaced in coastal Senegal support this interpretation.     

A deformed alkaline igneous rock–carbonatite complex from the Western Sierras Pampeanas, Argentina: Evidence for late Neoproterozoic opening of the Clymene Ocean?

A deformed ca. 570 Ma syenite–carbonatite body is reported from a Grenville-age (1.0–1.2 Ga) terrane in the Sierra de Maz, one of the Western Sierras Pampeanas of Argentina. This is the first recognition of such a rock assemblage in the basement of the Central Andes. The two main lithologies are coarse-grained syenite (often nepheline-bearing) and enclave-rich fine-grained foliated biotite–calcite carbonatite. Samples of carbonatite and syenite yield an imprecise whole rock Rb–Sr isochron age of 582 ± 60 Ma (MSWD = 1.8; Sri = 0.7029); SHRIMP U–Pb spot analysis of syenite zircons shows a total range of ²⁰⁶Pb–²³⁸U ages between 433 and 612 Ma, with a prominent peak at 560–580 Ma defined by homogeneous zircon areas. Textural interpretation of the zircon data, combined with the constraint of the Rb–Sr data suggest that the carbonatite complex formed at ca. 570 Ma. Further disturbance of the U–Pb system took place at 525 ± 7 Ma (Pampean orogeny) and at ca. 430–440 Ma (Famatinian orogeny) and it is concluded that the Western Sierras Pampeanas basement was joined to Gondwana during both events. Highly unradiogenic ⁸⁷Sr/⁸⁶Sr values in calcites (0.70275–0.70305) provide a close estimate for the initial Sr isotope composition of the carbonatite magma. Sm–Nd data yield Nd₅₇₀ values of +3.3 to +4.8. The complex was probably formed during early opening of the Clymene Ocean from depleted mantle with a component from Meso/Neo-proterozoic lower continental crust.     

Seismic attenuation,normal moveout stretch,and low‐frequency shadows underlying bottom simulating reflector events

In many cases, the seismic response of bottom‐simulating reflectors is characterised by low frequencies called “low‐frequency shadow”. Generally, this phenomenon is interpreted as attenuation due to partial saturation with free gas. Actually, this frequency loss may have multiple causes, with a normal moveout stretch as a possible candidate. To analyse this phenomenon, we compute synthetic seismograms by assuming a lossy bottom‐simulating layer, with varying quality factor and thickness, bounded by the upper hydrate‐brine/gas‐brine and lower gas‐brine/brine interfaces. First, we estimate the shift of the centroid frequency of the power spectrum as a function of the travelled distance of the seismic pulse. Then, we perform one‐dimensional numerical experiments to quantify the loss of frequency of the seismic event below the bottom‐simulating reflector as a function of the quality factor of the bottom‐simulating layer and its thickness (due to wave interference). Then, we compute shot gathers to obtain the stacked section, with and without the normal moveout stretch correction and with and without the presence of wave attenuation in the bottom‐simulating layer. The results indicate that the low‐frequency shadow due to the normal moveout stretch is stronger than that due to attenuation and may constitute a false indicator of the presence of gas. In fact, often, the low‐frequency shadow overlies events with higher frequencies, in contradiction with the physics of wave propagation. This is particularly evident when the low‐frequency shadow is so extensive that the presence of high frequencies below cannot be justified by the acquisition geometry.     

The MgCr2O4–MgFe2O4 solid solution series: effects of octahedrally coordinated Fe3+ on T–O bond lengths

The influence on the spinel structure of Fe³⁺ → Cr substitution was studied in flux-grown synthetic single crystals of the magnesiochromite–magnesioferrite (MgCr₂O₄–MgFe₂O₄) solid solution series. Samples were analysed by single-crystal X-ray diffraction, electron microprobe analyses, optical absorption and Mössbauer spectroscopy. With the exception of iron-poor samples (3–12 mol-% MgFe₂O₄), optical absorption and Mössbauer spectra show that iron occurs almost exclusively as trivalent Fe in the present samples. A very intense and broad absorption band at ca 7,800 cm^?1 dominates the optical absorption spectra of samples with higher Fe-contents. The appearance of this band is related to a distinct structural disorder of Fe³⁺ and a development of magnetic ordering as demonstrated by Mössbauer spectra. Profound composition-related changes are observed in the Mössbauer spectra, which are magnetically unsplit in the range 2–41 mol-% magnesioferrite, but become magnetically split in the range 59–100 mol-% magnesioferrite. Structural parameters a ₀ and M–O increase with magnesioferrite content and inversion degree, while u and T–O decrease. Our study confirms the previously reported (Lavina et al. 2002) influence of Fe³⁺ at the M site on T–O bond lengths in the spinel structure.