On Factors Controlling Air–Water Gas Exchange in a Large Tidal River

Air–water gas exchange is an important process in aquatic systems, including tidal rivers and estuaries. While there are now reliable and routine methods for determining gas exchange over a range of temporal and spatial scales in the ocean and these measurements have resulted in widely used wind speed parameterizations to calculate air–sea gas exchange, the same has not been true for coastal inland waterways. Some studies have suggested that this difference is methodological, while others point to the existence of additional drivers for gas exchange besides wind in rivers and estuaries. Here, we present gas transfer velocities measured in the tidal Hudson River with a method widely used in oceanic studies, the ³He/SF₆ dual tracer technique. Airside and waterside forcings were determined with an anemometer and an acoustic Doppler current profiler, respectively. The results confirm that wind is the dominant driver of gas exchange in the tidal Hudson River, with negligible contribution from bottom-generated turbulence. Furthermore, a parameterization between wind speed and gas exchange developed for the ocean is able to predict gas exchange in this environment with high accuracy. It is hoped that by transferring methodology used in oceanic studies to rivers and estuaries, robust data can be obtained that will eventually allow development of widely applicable relationships between easily measured environmental variables and gas exchange in tidal inland waters.     

The Néel transition and magnetic properties of terrestrial,synthetic, and lunar ilmenites

The magnetic susceptibility of a terrestrial, synthetic and lunar ilmenite specimen has been measured from 4 to 300 K. All specimens had a single Néel temperature transition which ranged from 56 to 57.7 K. In one case the powdered specimen was partially aligned in the magnetic field prior to the susceptibility measurements and the Néel transition was observed to shift to 60 K indicating magnetic anisotropy. A study of several magnetic parameters calculated from the experimental data showed gross impurities in the terrestrial specimen, single-domain to multi-domain metallic iron in the synthetic specimen, and a small amount of superparamagnetic metallic iron in the lunar sample. No multidomain iron was observed in the lunar ilmenite. The results of electron spin resonance measurements were also in general agreement with these findings. Because of the absence of Fe³⁺ compared to most terrestrial samples it is suggested that the anisotropic magnetic parameters be determined on lunar ilmenite when a large enough single crystal becomes available.     

Crustal structure and temporal velocity change in southern California

Summary About twenty blasts are used to determine crustal structure and to monitor temporal seismic velocity changes in southern California. The shot time is determined up to 10 msec by using a disposable pick-up placed directly on the explosive. About 17 permanent stations and 20 temporary stations are used for the recordings. With a fast paper speed (typically 1 cm/sec) and the WWVB radio signals superposed on the seismic trace, absolute timing accuracy of up to 10 msec is achieved. A representative structure thus determined consists of a 4 km thick 5.5 km/sec layer underlain successively by 23.4 km thick 6.3 km/sec layer, 5.0 km thick 6.8 km/sec layer and 7.8 km/sec half space. The details of the lower crust are somewhat uncertain. This structure can explain the travel time data, corrected for the station and source elevations and for the station delays, to ±0.15 sec. Small but systematic temporal velocity changes up to 3% have been found for some of the profiles. If the effect of the migration of the shot point is small enough, these changes are larger than experimental errors and represent real temporal change in the material property between the shot point and the stations.Contribution No. 2530, Division of Geological Sciences, California Institute of Technology, Pasadena, California.     

Die Verölung der Oberflächengewässer durch die Kleinschiffahrt

Ohne Zusammenfassung     

Observed Spatial and Temporal Distributions of CVOCs at Colorado and New York Vapor Intrusion Sites

The vapor intrusion impacts associated with the presence of chlorinated volatile organic contaminant plumes in the ground water beneath residential areas in Colorado and New York have been the subject of extensive site investigations and structure sampling efforts. Large data sets of ground water and indoor air monitoring data collected over a decade-long monitoring program at the Redfield, Colorado, site and monthly ground water and structure monitoring data collected over a 19-month period from structures in New York State are analyzed to illustrate the temporal and spatial distributions in the concentration of volatile organic compounds that one may encounter when evaluating the potential for exposures due to vapor intrusion. The analysis of these data demonstrates that although the areal extent of structures impacted by vapor intrusion mirrors the areal extent of chlorinated volatile organic compounds in the ground water, not all structures above the plume will be impacted. It also highlights the fact that measured concentrations of volatile organic compounds in the indoor air and subslab vapor can vary considerably from month to month and season to season. Sampling results from any one location at any given point in time cannot be expected to represent the range of conditions that may exist at neighboring locations or at other times. Recognition of this variability is important when designing sampling plans and risk management programs to address the vapor intrusion pathway.     

Melt density and the average composition of basalt

Densities of residual liquids produced by low pressure fractionation of olivine-rich melts pass through a minimum when pyroxene and plagioclase joint the crystallization sequence. The observation that erupted basalt compositions cluster around the degree of fractionation from picritic liquids corresponding to the density minimum in the liquid line of descent may thus suggest that the earth's crust imposes a density filter on the liquids that pass through it, favoring the eruption of the light liquids at the density minimum over the eruption of denser more fractionated and less fractionated liquids.     

A rural development strategy for the Apuseni Mountains, Romania

The Apuseni Mountains, part of the Western Carpathians, are distinctive in cultural terms because of the highly dispersed settlement patterns that have developed on the high erosion surfaces where the Moti people cleared the forests to allow for an expansion of family farming in the eighteenth and nineteenth centuries. These small ‘crang’ settlements remain, but the population is declining in the face of limited employment opportunities and poor services. The question arises as to the most appropriate rural development strategy for the region, following the communist period which encouraged centralisation through the provision of housing and industry in key villages and new towns. The emphasis on private farming and the expansion of tourism could protect the inherited cultural landscape but money must be found to improve rural services. There is also a strong conservation movement which supports the establishment of a national park, but this could constrain development through controls on grazing and woodcutting. Hence the dialogue continues to find the best compromise and the concept of a ‘natural park’ is being discussed with such a reconciliation in mind. This revised version was published online in July 2006 with corrections to the Cover Date.     

Cleavage-fold relationships and their implications for transected folds: an example from southwest Virginia,U.S.A.

A non-coaxial deformation involving pre-folding initiation of cleavage perpendicular to bedding is proposed to explain non-axial planar cleavage associated with mesoscopic folds in part of the Appalachian foreland thrust-belt of southwest Virginia. Folds are gently plunging, asymmetric, upright to slightly inclined, sinusoidal forms with non-axial fanning cleavage. They show extreme local variations in type and degree of transection and the consistency of transection direction. These relations are further complicated by hinge migration.Cleavage-fan angles, bedding-cleavage angles and δ transection values appear influenced by fold tightness, and in part by fold flattening strain. Fold flattening increments are considered simultaneous with folding. Axial surface traces, and not cleavage traces, coincide with the principal extension direction in fold profiles. Geometric modelling of cleavage fanning and bedding-cleavage angle variations for various theoretical folding modes suggest that folding in limestone and sandstone layers was by tangential longitudinal strain. Significant shape modification and change in bedding-cleavage relations occurred after limb dips of 40 and 50° were attained in limestone and sandstone respectively. Mud-rock class 1C folds with convergent cleavage fans show features transitional between buckling and flexural flow. Initiation of ‘cleavage’ fabrics during layer-parallel shortening prior to significant folding may be important for cleavage evolution in some deformed rocks.