On low-frequency errors of uniformly modulated filtered white-noise models for ground motions

Low-frequency errors of a commonly used non-stationary stochastic model (uniformly modulated filtered white-noise model) for earthquake ground motions are investigated. It is shown both analytically and by numerical simulation that uniformly modulated filter white-noise-type models systematically overestimate the spectral response for periods longer than the effective duration of the earthquake, because of the built-in low-frequency errors in the model. The errors, which are significant for low-magnitude short-duration earthquakes, can be eliminated by using the filtered shot-noise-type models (i.e. white noise, modulated by the envelope first, and then filtered).     

The Sensitivity of Four Monitoring Well Sampling Systems to Low Concentrations of Three Volatile Organics

Four state-of-the-art ground water sampling systems were analyzed to determine their reliability in providing representative samples of the volatile chlorinated hydrocarbons trichloroethylene (TCE), perchloroethylene (PCE), and 1,1,1-trichloroethane (TCA) from a simulated monitoring well. The sampling systems studied represent four commonly used devices, including a stainless steel and Teflon® piston pump, a Teflon bailer, a Teflon bladder pump, and a PVC air-lift pump.
Controlled laboratory sampling experiments were conducted in a tank and well test chamber designed to approximate field conditions. A well purging and sampling procedure was used in the test apparatus to determine the accuracy and precision of each device for detecting low concentrations of the compounds in ground water. The compounds selected are some of the most ubiquitous hazardous contaminants found in shallow aquifers near hazardous waste sites throughout the United States.
No significant statistical difference was found among the four sampling systems in detecting the compounds.     

Distribution and migration of pesticide residues in mosquito control impoundments St. Lucie County, Florida, USA

This project was designed to: (1) document the distribution and migration of organochlorine pesticide residues within marsh substrates of 18 St. Lucie County mosquito control impoundments located along the Indian River Lagoon estuary, and (2) evaluate the impact of water management techniques on residue mobility. Our results indicate that detectible concentrations of organochlorine compounds, applied between the late 1940s and early 1950s, are present in 16 of the 18 St. Lucie County mosquito control impoundments. These compounds are primarily restricted to the surficial, organic-rich wetland sediment, which, based upon geotechnical analysis, was exposed to the atmosphere at a time when the impoundments were subjected to pesticide treatment. Contaminated sediments are present below the surficial, organic-rich layer, suggesting that some vertical migration of pesticides has occurred. It is unlikely that leaching associated with the downward percolation of impounded water was responsible for this migration as pesticide residues were never detected within thein situ pore waters. An alternative explanation is that biological processes (e.g., rooting, burrowing) facilitated the downward flux of organochlorine compounds into sediment horizons not subjected to direct treatment. Eighty-eight surface water samples obtained from two impoundments subjected to contrasting water management techniques were analyzed for pesticide content. None of the surficial water samples collected in association with these impoundments contained detectible concentrations of organochlorine compounds. These samples were unfiltered and contained as much as 25 mg/1 of particulate organic matter. This suggests that the currently preferred management technique (RIM), which is designed to maintain water quality, limit mosquito production, and provide for ecological continuity, does not hydraulically mobilize pesticide residues into the Indian River Lagoon estuary.     

Sub-critical fracture and associated retrogression of garnet during mylonitic deformation

Garnets from the Alpine Fault mylonites are fractured. Most fractures have a retrogressive fracture fill; a small number have garnet fill. A detailed SEM study has been carried out to elucidate the mechanisms of fracture and associated retrogression. Wide fracture zones contain free floating islands of garnet in a retrogressive matrix. Electron channelling patterns show that segments of garnet across such fracture zones rarely show any relative rotations. Where rotations are observed, they are small and systematic. Some large fractures show clearly that fracture and retrogression occurs by a replacement process. Fracture surface morphologies are indicative of surface dissolution. A model is established where crack tips advance by a process of dissolution at a high stress crack tip whilst precipitation occurs as the tip and its associated stress field advance. Precipitation of retrogressive fracture fill occurs if fracture occurs out of the field of stability of garnet.     

Infrared spectroscopic investigation of hydroxyl in β-(Mg,Fe)2SiO4 and coexisting olivine: Implications for mantle evolution and dynamics

Wadsleyite (β-(Mg,Fe)₂SiO₄) is a major constituent of the Earth's transition zone and is known to accommodate OH. The portion of the transition zone between 400–550 km could be an important source or sink for hydroxyl in plumes and slabs intersecting this region. Micro-infrared spectroscopy has been carried out on the β-phase and coexisting metastable olivine synthesized in a multianvil apparatus at 14 GPa and 1550–1650 K under hydrous conditions. Single-crystal and polycrystal specimens of both phases were analyzed in the 1800–8500 cm^?1 frequency region to determine the speciation, abundances, and partitioning behavior of the hydrous components in coexisting β-phase and olivine. β-phase spectra consistently show three distinct OH bands at 3329, 3580, and 3615 cm^?1. OH concentrations range from 10000–65000 H/10⁶ Si. A strong positive correlation of grain size and extent of transformation with OH concentration in the β-phase indicates that grain-growth and transformation rates are enhanced in a hydrous environment. Olivine spectra are variable, but consistently show a prominent broad-band absorbance representing molecular H₂O, consistent with the infrared signature of the starting material. OH concentrations in olivine range from <300–1400 H/10⁶ Si. The highest OH concentrations measured for olivine and the β-phase may represent solubility limits, in which case the OH solubility ratio between these two phases is approximately 1∶40. Where both phases coexist and are undersaturated with OH, the partitioning ratio of OH between them is about 1∶100. The large solubility contrast between olivine and the β-phase suggests a mechanism for hydrating the transition zone via olivine carried down in subducting slabs. Plumes impinging on an OH-rich upper transition region could cause H₂ or H₂O to be released upon transformation of the β-phase to olivine, resulting in initiation of secondary upwellings. If dissolution of OH weakens the β-phase, and if OH is present in the mantle, the region between 400–550 km could be a zone of low viscosity.     

AMS Radiocarbon Age of the Upper Mississippi Valley Roxana Silt

Accelerator mass spectrometer radiocarbon ages of the Roxana Silt (loess) along the Upper Mississippi Valley of Wisconsin and Minnesota indicate that loess sedimentation of the Roxana Silt occurred between about 55,000 and 27,000 ¹⁴ C yr B.P. However, due to local environmental controls, the basal age at any given site may range from 55,000 to 35,000 ¹⁴C yr B.P. The radiocarbon ages presented here are in agreement with previous radiocarbon ages for the Roxana Silt in its type area of west-central Illinois, but indicate that long-term sedimentation rates along the bluffline of the Upper Mississippi Valley were very slow (4-8 cm/1000 yr) compared to long-term sedimentation rates along the bluffline of the type area (40-70 cm/1000 yr). Comparison of radiocarbon ages for midcontinent middle Wisconsinan loess deposits indicates that sedimentation along the Mississippi River valley may have preceded loess sedimentation along the Missouri River valley by as much as 20,000 yr or that basal ages for middle Wisconsinan loess along the Missouri Valley are erroneously young. The bracketing ages for the Upper Mississippi Valley Roxana Silt indicate that the Mississippi River valley was receiving outwash sedimentation between 55,000 and 27,000 ¹⁴C yr B.P.     

A study of the geoelectrical properties of peatlands and their influence on ground-penetrating radar surveying1

Geophysical surveys and chemical analyses on cores were carried out in three Ontario peatlands, from which we have gained a better understanding of the peat properties that control the geophysical responses. The electrical conductivity depends linearly on the concentration of total dissolved solids in the peat pore waters and the pore waters in turn bear the ionic signatures of the underlying mineral sediments. The ionic concentration, and thus the electrical conductivity, increase linearly from the surface to basement. The average bulk electrical conductivity of peatlands at Ellice Marsh, near Stratford, and at Wally Creek Area Forest Drainage Project, near Cochrane, are of the order of 25 mS/m. The Mer Bleue peatland, near Ottawa, has extremely high electrical conductivity, reaching levels of up to 380 mS/m near the base of the peat. The Mer Bleue peatland water has correspondingly high values of total dissolved solids, which originate from the underlying Champlain Sea glaciomarine clays. The dielectric permittivity in peats is largely controlled by the bulk water content. Ground penetrating radar can detect changes in water content greater than 3%, occurring within a depth interval less than 15 cm. The principal peatland interfaces detected are the near-surface aerobic to anaerobic transition and the peat to mineral basement contact. The potential for the successful detection of the basement contact using the radar can be predicted using the radar instrument specifications, estimates of the peatland depth, and either the bulk peat or the peat pore water electrical conductivities. Predicted depths of penetration of up to 10 m for Ellice Marsh and Wally Creek exceed the observed depths of 1 to 2 m. At Mer Bleue, on the other hand, we observe that, as predicted, a 100 MHz signal will penetrate to the base of a 2 m thick peat but a 200 MHz signal will not.