An EPR study of native radiation-induced paramagnetic defects in sudoite (di–trioctahedral Al–Mg chlorite) from the alteration halo related to unconformity-type uranium deposits

Natural radiation-induced defects were identified in specimens of sudoite (Al–Mg di-trioctahedral chlorite) related to unconformity-type uranium deposits at the base of the Athabasca Group (Saskatchewan, Canada), using electron paramagnetic resonance (EPR) spectroscopy at X- and Q-band frequencies. X-band spectra indicate the presence of a main native defect, named the A_s-center, whose EPR signal is dominated by an axially distorted spectrum with apparent principal components as follows: g _// = 2,051 and g _⊥ = 2,005, and a secondary defect with apparent component g = 2,025. The study of oriented specimens shows that the main defect has its g _// component perpendicular to the (ab) plane of sudoite. The A_s-center corresponds to an electron hole located on oxygen atoms of the structure and is likely associated with Si, according to the lack of hyperfine structure. The A_s-center in sudoite has EPR parameters similar to the A-center in kaolinite and dickite, and the A_i-center in illite. The saturation behavior of EPR spectra as a function of power demonstrates that native defects of sudoite are different from those known in other clays, such as kaolinite, dickite or smectite, but are similar to those of illite. The isochronal annealing data suggest that the main defect in sudoite is stable to more than 300°C. The corresponding defects characterized in sudoite may have the potential for tracing past radionuclide migration around unconformity-type uranium deposits.     

TRENDS IN LATIN AMERICANIST GEOGRAPHY IN THE UNITED STATES AND CANADA

The question of what lies ahead is of particular concern for Latin Americanists. The last decade has witnessed a serious erosion of both the popularity of their specialty, and an equally troublesome reduction in employment opportunities. This paper uses Association of American Geographers (AAG) data bases to document the age-gender structure of contemporary Latin Americanist geographers, and projects likely compositional changes through the end of the century.     

The use of7LiOH-impregnated filters for the collection of acidic gases and analysis by instrumental neutron activation analysis

A simple system was designed using⁷LiOH-impregnated filters to collect acidic gases from ambient air and from highly concentrated volcanic plumes or gas streams. These filters were developed for analysis using instrumental neutron activation analysis, but other analytical techniques could be used as well. The sampling system was designed to use a series of 1–3 M⁷LiOH-impregnated filters to collect high concentrations of acidic gases found in gas plumes of active volcanoes. The filters are quantitative for SO₂ and the halide acids when sufficient base is present to neutralize the acidic species. Extremely high concentrations of SO₂ may not be collected quantitatively since SO₂ is a relatively weak Lewis acid compared to the halide acids. The acidic oxides of Sb, As, and Se were also collected quantitatively. A particle filter preceded the impregnated filters in order to remove particles from the fumes. This system has proven effective under difficult sampling conditions and, since it is portable and light weight, it could be used for many volcanological applications where high levels of acidic gaseous phase species need to be collected.     

Coma expansion and photometry of comet Bowell (1980b)

Optical and infrared observations of comet Bowell are presented. The optical observations indicate that the solid grain coma is expanding at only 0.9 ± 0.2 m sec^?1. This is two orders of magnitude slower than the local gas sound speed and may suggest that gas drag is not responsible for stripping the grains from the nucleus. The hypothesis of “electrostatic snap-off” is tentatively advanced to account for the ejection of the grains. Alternatively, the grains may have an unusual size distribution. The extrapolated motion of the grains suggests that the bulk of the coma was formed when the comet was at a heliocentric distance $\text{R ? 10}\text{AU}$. Any water ice in the nucleus would be too cold to give rise to the observed grain coma by equilibrium sublimation at this R. Further evidence against the production of the grain coma by equilibrium sublimation of the nucleus is provided by broadband (J) photometric observations. Almost all of the observed photometric variations of comet Bowell can be ascribed to geometric effects. Simple models indicate that the total grain cross section has been nearly constant since the time of the earliest observations. The present observations, which suggest that water ice sublimation does not control either the optical morphology or the near infrared photometric behavior of comet Bowell, are contrasted with reported high OH production rates. It is concluded that the grain coma may be largely a relic of activity occurring on the nucleus at $\text{R ? 10}\text{AU}$ while the OH may indicate sublimation from the nucleus near perihelion and from coma grains near $\text{R ? 4.6}\text{AU}$.     

The Pleistocene evolution of the East Antarctic Ice Sheet in the Prydz bay region: stable isotopic evidence from ODP Site 1167

Ocean Drilling Program Leg 188, Prydz Bay, East Antarctica is part of a larger initiative to explore the Cenozoic history of the Antarctic Ice Sheet through direct drilling and sampling of the continental margins. In this paper, we present stable isotopic results from Ocean Drilling Program (ODP) Site 1167 located on the Prydz Channel Trough Mouth Fan (TMF), the first Antarctic TMF to be drilled. The foraminifer-based δ¹⁸O record is interpreted along with sedimentary and downhole logging evidence to reconstruct the Quaternary glacial history of Prydz Bay and the adjacent Lambert Glacier Amery Ice Shelf System (LGAISS). We report an electron spin resonance age date of 36.9±3.3 ka at 0.45 m below sea floor and correlate suspected glacial–interglacial cycles with the global isotopic stratigraphy to improve the chronology for Site 1167. The δ¹⁸O record based on planktonic (Neogloboquadrina pachyderma (s.)) and limited benthic results (Globocassidulina crassa), indicates a trend of ice sheet expansion that was interrupted by a period of reduced ice volume and possibly warmer conditions during the early–mid-Pleistocene (0.9–1.38 Ma). An increase in δ¹⁸O values after 900 ka appears to coincide with the mid-Pleistocene climate transition and the expansion of the northern hemisphere ice sheet. The δ¹⁸O record in the upper 50 m of the stratigraphic section indicates as few as three glacial–interglacial cycles, tentatively assigned as marine isotopic stages (MIS) 16–21, are preserved since the Brunhes/Matuyama paleomagnetic reversal (780 ka). This suggests that there is a large unconformity near the top of the section and/or that there may have been few extreme advances of the ice sheet since the mid-Pleistocene climate transition resulting in lowered sedimentation rates on the Prydz Channel TMF. The stable isotopic record from Site 1167 is one of the few available from the area south of the Antarctic Polar Front that has been linked with the global isotopic stratigraphy. Our results suggest the potential for the recovery of useful stable isotopic records in other TMFs.     

Aviation-Contrail Impacts on Climate and Climate Change: A Ready-to-Wear Research Mantle for Geographers

Although geographers are highly visible in research into contemporary climate changes accompanying greenhouse gas increases (“global warming”), a relatively little explored component by them is the impact of aviation. This contrasts with the atmospheric science community of cloud physicists, chemists, and numerical modelers, who use geographic tools of trade. Geographers are well positioned to investigate aviation-climate impacts, especially related to contrail clouds, given geographic traditions of environment, spatial variation, regionalization, generalization, and the integrative approach to studying physical and human systems (here, climate, transportation, and energy). We highlight the role played by geographers in contrail-climate studies and advocate for a broader involvement in aviation policy formulation.