Fracture in Westerly Granite under AE Feedback and Constant Strain Rate Loading: Nucleation, Quasi-static Propagation, and the Transition to Unstable Fracture Propagation

New observations of fracture nucleation are presented from three triaxial compression experiments on intact samples of Westerly granite, using Acoustic Emission (AE) monitoring. By conducting the tests under different loading conditions, the fracture process is demonstrated for quasi-static fracture (under AE Feedback load), a slowly developing unstable fracture (loaded at a `slow' constant strain rate of 2.5 × 10<sup>−6</sup> /s) and an unstable fracture that develops near instantaneously (loaded at a `fast' constant strain rate of 5 × 10⁻⁵ /s). By recording a continuous ultrasonic waveform during the critical period of fracture, the entire AE catalogue can be captured and the exact time of fracture defined. Under constant strain loading, three stages are observed: (1) An initial nucleation or stable growth phase at a rate of ~ 1.3 mm/s, (2) a sudden increase to a constant or slowly accelerating propagation speed of ~ 18 mm/s, and (3) unstable, accelerating propagation. In the ~ 100 ms before rupture, the high level of AE activity (as seen on the continuous record) prevented the location of discrete AE events. A lower bound estimate of the average propagation velocity (using the time-to-rupture and the existing fracture length) suggests values of a few m/s. However from a low gain acoustic record, we infer that in the final few ms, the fracture propagation speed increased to 175 m/s. These results demonstrate similarities between fracture nucleation in intact rock and the nucleation of dynamic instabilities in stick slip experiments. It is suggested that the ability to constrain the size of an evolving fracture provides a crucial tool in further understanding the controls on fracture nucleation.     

Site Response in Las Vegas Valley, Nevada from NTS Explosions and Earthquake Data

We report site response in Las Vegas Valley (LVV) from historical recordings of Nevada Test Site (NTS) nuclear explosions and earthquake recordings from permanent and temporary seismic stations. Our data set significantly improves the spatial coverage of LVV over previous studies, especially in the northern, deeper parts of the basin. Site response at stations in LVV was measured for frequencies in the range 0.2–5.0 Hz using Standard Spectral Ratios (SSR) and Horizontal-Vertical Spectral Ratios (HVR). For the SSR measurements we used a reference site (approximately NEHRP B ``rock' classification) located on Frenchman Mountain outside the basin. Site response at sedimentary sites is variable in LVV with average amplifications approaching a factor of 10 at some frequencies. We observed peaks in the site response curves at frequencies clustered near 0.6, 1.2 and 2.0 Hz, with some sites showing additional lower amplitude peaks at higher frequencies. The spatial pattern of site response is strongly correlated with the reported depth to basement for frequencies between 0.2 and 3.0 Hz, although the frequency of peak amplification does not show a similar correlation. For a few sites where we have geotechnical shear velocities, the amplification shows a correlation with the average upper 30-meter shear velocities, V₃₀. We performed two-dimensional finite difference simulations and reproduced the observed peak site amplifications at 0.6 and 1.2 Hz with a low velocity near-surface layer with shear velocities 600–750 m/s and a thickness of 100–200 m. These modeling results indicate that the amplitude and frequencies of site response peaks in LVV are strongly controlled by shallow velocity structure.     

R&D Subsidies and Climate Policy: Is There a “Free Lunch”?

Because of the long-term nature of the climate problem, technological advances are often seen as an important component of any solution. However, when considering the potential for technology to help solve the climate problem, two market failures exist which lead to underinvestment in climate-friendly R&D: environmental externalities and the public goods nature of new knowledge. As a result, government subsidies to climate-friendly R&D projects are often proposed as part of a policy solution. Using the ENTICE model, I analyze the effectiveness of such subsidies, both with and without other climate policies, such as a carbon tax. While R&D subsidies do lead to significant increases in climate-friendly R&D, this R&D has little impact on the climate itself. Subsidies address the problem of knowledge as a public good, but they do not address the environmental externality, and thus offer no additional incentive to adopt new technologies. Moreover, high opportunity costs to R&D limit the potential role that subsidies can play. While R&D subsidies can improve efficiency, policies that directly affect the environmental externality have a much larger impact on both atmospheric temperature and economic welfare.     

A Demonstration of the Uncertainty in Projections of UK Climate Change Resulting from Regional Model Formulation

Regional climate models (RCMs) are now commonly used to downscale climate change projections provided by global coupled models to resolutions that can be utilised at national and finer scales. Although this extra tier of complexity adds significant value, it inevitably contributes a further source of uncertainty, due to the regional modelling uncertainties involved. Here, an initial attempt is made to estimate the uncertainty that arises from typical variations in RCM formulation, focussing on changes in UK surface air temperature (SAT) and precipitation projected for the late twenty-first century. Data are provided by a relatively large suite of RCM and global model integrations with widely varying formulations. It is found that uncertainty in the formulation of the RCM has a relatively small, but non-negligible, impact on the range of possible outcomes of future UK seasonal mean climate. This uncertainty is largest in the summer season. It is also similar in magnitude to that of large-scale internal variations of the coupled climate system, and for SAT, it is less than the uncertainty due to the emissions scenario, whereas for precipitation it is probably larger. The largest source of uncertainty, for both variables and in all seasons, is the formulation of the global coupled model. The scale-dependency of uncertainty due to RCM formulation is also explored by considering its impact on projections of the difference in climate change between the north and south of the UK. Finally, the implications for the reliability of UK seasonal mean climate change projections are discussed.     

The Reconstruction of Paleovegetation and Paleoclimate in the Late Pliocene of West Yunnan, China

The Eryuan palynoflora from the Late Pliocene of western Yunnan, China is described in this paper, and is compared with two contemporary palynofloras from Yangyi and Longling. The palynological data of the three locations are analyzed to reconstruct the climatic parameters of these areas at that time by using the Coexistence Approach. The Late Pliocene climatic parameters of Eryuan are estimated, i.e., the mean annual temperature ranged from 13.3 to 18.6^∘C, the mean temperature of the warmest month from 24.6 to 27.5^∘C, the mean temperature of the coldest month from 1.9 to 12.1^∘C, the difference in temperatures of coldest and warmest month from 14.2 to 16.6^∘C, the mean annual precipitation from 619.9 to 1484.3 mm, the mean maximum monthly precipitation from 143.8 to 245.6 mm, and the mean minimum monthly precipitation from 12.7 to 16.4 mm. Both paleovegetation and paleoclimate of the three localities are compared with the modern data at each location. The present study suggests a MAT decrease accompanied by a doubling of the MAP in the Longling area between the Late Pliocene and the present. This seems to be related to the uplift of Gaoligong Mountain in Longling which is now part of the eastern portion (Western Yunnan) of the Tibetan Plateau.     

Snow cover variability across central Canada (1978–2002) derived from satellite passive microwave data

Twenty-four winter seasons (1978–2002) of mean February snow water equivalent (SWE) values were analyzed in an exploration of the spatial pattern of temporal variability in snow cover across the non-mountainous interior of Canada. The SWE data were derived from space-borne passive microwave brightness temperatures processed with a land cover-sensitive suite of algorithms. Spatial patterns in the frequency and amount of variability were investigated on an annual basis through comparisons with average trends over all 24 years. Changes in temporal variability through time were also investigated by comparing three eight year time periods to general trends. Analyses were synthesized at the ecozone scale in order to link results both to potential land cover influences on algorithm performance and climatological variability in SWE. Prairie and northern ecozones were typically found to be the most variable in terms of SWE magnitude. Analyses indicate that non-treed land cover classes are generally more variable than treed classes. The results also indicate that extreme weather events appear to be occurring with increasing consistency in the Prairie and Arctic regions. Discerning climatologically significant variability in the time series, compared to algorithm-related issues can be a challenge, but in an era of eroding surface observing networks the passive microwave time series represents an important resource for monitoring and detecting trends and variability in terrestrial snow cover.     

Equilibrium interface segregation in the diopside-forsterite system I: Analytical techniques, thermodynamics, and segregation characteristics

After syntheses of partially molten diopside-forsterite polycrystalline aggregates doped with various solutes, we analyzed the equilibrium segregation of Ni, Mn, Sr, Al, Yb, Y, Nd, La, and Ti at interfaces between diopside/diopside, diopside/forsterite and, forsterite/forsterite grains based on STEM/EDX (scanning transmission electron microscopy/energy dispersive X-ray spectrometry) to examine the effects of ionic size, valence state, co-segregation, and interface type on interface chemistry. We derive relationships between two quantities describing interface segregation and X-ray intensities acquired both from areas that include an interface and from areas that do not. These segregation quantities are (i) interface excess density and (ii) interface enrichment factor, which rely on Gibbsian thermodynamics and the Langmuir-McLean segregation model, respectively. Interface excess densities, which vary from −0.5 to 10 atoms/nm², indicate that the level of interface excess density depends on solutes and sample assemblage. Interface enrichment factors, which range from almost 1 to 130, reveal that the ionic size of the solutes affects their segregation via production of misfit lattice strain due to the difference between the size of a solute ion and that of the ideal strain-free lattice site. The ionic sizes of Yb and Y are almost identical to the size of the strain-free site; however, their segregation is significant indicating that a difference in valence state between the host elements (i.e., Ca and Mg) and the solutes also drives segregation. In contrast to other solutes, segregation characteristics of Al differ from these simple segregation rules. Segregation quantities do not change with interface type, indicating that the number of sites available for segregants and the driving force for segregation are similar among type of interfaces. We compare the element partitioning between diopside-melt and diopside-interfaces within the same sample assemblages. These two partition coefficients coincide if we approximate the number of segregation sites at interfaces as equivalent to 2 mono-atomic layers. Examination of the energetics in crystal-melt partitioning reveals that the interface segregation energy is essentially equal to the solute solution energy in a crystal.     

The effects of soil type and chemical treatment on nickel speciation in refinery enriched soils: A multi-technique investigation

Aerial deposition of Ni from a refinery in Port Colborne, Ontario, Canada has resulted in the enrichment of 29 km² of land with Ni concentrations exceeding the Canadian Ministry of the Environment’s remedial action level of 200 mg kg⁻¹. Several studies on these soils have shown that making the soils calcareous was effective at reducing chemically extractable Ni, as well as alleviating Ni phytotoxicity symptoms in vegetable crops grown in the vicinity of the refinery. Conversely, dolomitic limestone additions resulted in increased uptake of Ni in the Ni hyperaccumulator Alyssum murale ‘Kotodesh’, a plant whose use was proposed as a remediation strategy for this area. In this paper we use multiple techniques to directly assess the role soil type and lime treatments play in altering the speciation of Ni in the Welland loam and Quarry muck soils around the refinery and relate these findings to Ni mobility and bioavailability.Stirred-flow dissolution experiments using pH 4 HNO₃ showed that Ni release from the limed Quarry muck and Welland loam soils was reduced (∼0.10%) relative to the unlimed soils (∼2.0%). Electron microprobe analysis (EMPA) identified approximately spherical NiO and Ni metal particles, which are associated with no other metals, and range from 5 to 50 μm in diameter. Synchrotron micro-X-ray absorption fine structure and X-ray fluorescence spectroscopies showed that Ni and Al layered double hydroxide (Ni-Al LDH) phases were present in both the limed and unlimed mineral soils, with a tendency towards more stable (e.g., aged-LDH and phyllosilicate) Ni species in the limed soil, possibly aided by the solubilization of Si with increasing pH. In the muck soils, Ni-organic complexes (namely fulvic acid) dominated the speciation in both limed and unlimed soils.The results reported herein show that both soil type and treatment have a pronounced effect on the speciation of Ni in the soils surrounding the Port Colborne refinery. We provide the first evidence that Ni-Al LDH phases can form in anthropogenically enriched mineral field soils at circumneutral pH, and can lead to a reduction in Ni mobility. In the organic soils Ni is strongly complexed by soil organic matter; a property enhanced with liming. Interestingly, increased accumulation of Ni by A. murale grown in the limed muck and loam soils indicates that the plant may be capable of removing Ni from those fractions typically considered unavailable to most plants.     

Superoxide-mediated reduction of organically complexed iron(III): Impact of pH and competing cations (Ca)

The mechanism and kinetics of superoxide-mediated reduction of a variety of organic iron(III) complexes has been investigated over the pH range 7-9. Our experimental results show that the rate of iron(II) formation is a function of pH, ligand type and ligand concentration with the measured rate varying between 0.44 ± 0.07 and 39.25 ± 1.77 pM s⁻¹ in the systems investigated. Additionally, our results show that the presence of competing cations such as Ca²⁺ have a significant impact on iron(II) formation if the organic ligand is strongly complexed by Ca²⁺. Formation of iron(II) occurs by either (or, in some instances, both) reaction of superoxide with inorganic iron(III) after its dissociation from the complex (dissociative reduction) or by direct reaction of superoxide with the complex (non-dissociative reduction). In the presence of weak ligands, dissociative reduction (DR) dominates; however non-dissociative reduction (NDR) becomes important in the presence of either strongly binding ligands or high concentrations of weakly binding ligands. The major factors contributing to the pH dependence of the iron(II) formation rate are the complexation kinetics of inorganic iron(III) (which controls the DR contribution) and the reduction kinetics of the iron(III) complex (which controls the NDR contribution). The relative NDR contribution increases with increasing superoxide and ligand concentration and decreasing pH for all ligands examined. Since iron(II) formation occurring via NDR results in a significantly larger increase in the proportion of iron in free aquated form than does DR, this non-dissociative pathway of superoxide-mediated iron(III) reduction is particularly effective in increasing the lability of iron in aquatic systems.