Speciation of trace metals in sediments of a tropical estuary

Axial surveys were performed in the two river tributaries of the Cochin estuary, SW India during November 1988. Surficial sediments were subjected to sequential chemical extractions to delineate five metal fractions, namely, exchangeable, carbonate bound, easily reducible, organic/sulfide bound, and residual. The results indicated selective accumulation of Mn and Ni in carbonate bound and organic/sulfide forms, along with marginal amounts of Co in the exchangeable fraction. Large portions of Fe and Cr occurred in the residual fraction, whereas composite fractionation of Zn species was noticed. The exchangeable fractions of Fe and Cr as well as of easily reducible cobalt were below detection limits. The levels of Cr and Zn indicate anthropogenic inputs in this estuary, whereas Co and Ni show regional contamination exceeding natural levels. The analytical speciation procedure helps to deduce the sedimental diagenetic processes in the estuarine environment.     

The estimation of the shape of an array using a hidden Markov model

A hidden Markov model (HMM) technique for the estimation of the shape of a towed array is presented. It is assumed that there is a far-field source radiating sound containing possibly weak spectral lines. The technique uses either the Fourier coefficients at a given frequency computed from a single time block or the maximal eigenvector of a sample spectral covariance matrix. The technique is illustrated using several simulations. The results of these simulations indicate that the HMM technique yields shape and bearing estimates more accurate than those provided by a maximum-likelihood array shape estimation technique     

CONGRESS AND THE CHANGING DISTRIBUTION OF FEDERAL OUTLAYS,FY81-FY86*

Did Congressional influence play a role in the distribution of federal outlays between FY81 and FY86? This study hypothesizes that states with majority party House and Senate delegations and with seniority in the delegations experienced the largest increases in federal expenditures. These two hypotheses are tested for fifteen divisions of federal outlays using a stepwise regression model. The results provide only very modest evidence of any systematic Congressional influence over changes in the distribution of federal outlays during the study period.     

Transient response of a circular cavity in a poroelastic medium

This paper considers the transient response of a pressurized long cylindrical cavity in an infinite poroelastic medium. To obtain transient solutions, Biot's equations for poroelastodynamics are specialized for this problem. A set of exact general solutions for radial displacement, stresses, pore pressure and discharge are derived in the Laplace transform space by using analytical techniques. Solutions are presented for three different types of prescribed transient radial pressures acting on the surface of a permeable as well as an impermeable cavity surface. Time domain solutions are obtained by inverting Laplace domain solutions using a reliable numerical scheme. A detailed parametric study is presented to illustrate the influence of poroelastic material parameters and hydraulic boundary conditions on the response of the medium. Comparisons are also presented with the corresponding ideal elastic solutions to portray the poroelastic effects. It is noted that the maximum radial displacement and hoop stress at the cavity surface are substantially higher than the classical static solutions and differ considerably from the transient elastic solutions. Time histories and radial variations of displacement, hoop stress, pore pressure and fluid discharge corresponding to a cavity in two representative poroelastic materials are also presented.     

Shakedown in layered pavements under moving surface loads

Elastic–plastic deformations in pavements consisting of layers of different frictional materials are investigated. The upper bound, kinematic shakedown theorem is used to obtain estimates of the critical shakedown loads. Fully general three-dimensional deformations are considered. The influence of the loading distribution, interactions between loads, and the effect of varying the thickness, stiffness and strength of the layers are explored. Consequences of this investigation for particular existing designs of flexible pavements are investigated. In particular, it is found that the strength of the subgrade has no effect on the magnitude of the critical shakedown load.     

Preliminary organic petrography of Palaeozoic rocks from the Grand Banks,Newfoundland

Samples of lower Palaeozoic bedrock from the Grand Banks of Newfoundland were examined using reflected light microscopy and Rock-Eval pyrolysis. These samples contained organic material which included bitumen (structureless organic material), acritarchs, chitinozoa, scolecodonts and graptolites. The reflectance of the organic material increased from acritarchs towards graptolites with bitumen showing a wide range of reflectance. Multiple phases of oil migration through one sample were inferred by examination of the bitumens: the lowest reflecting being more recent than the highest reflecting bitumen. Combined reflectance and Rock-Eval analysis indicate that these samples are mature to overmature. The two oldest samples (Arenig-Llanvirn, Ordovician) are assessed as mature and as having potential for generation of liquid hydrocarbons, but must be considered as mainly gas prone.     

Cokriging nonstationary data

Universal cokriging is used to obtain predictions when dealing with multivariate random functions. An important type of nonstationarity is defined in terms of multivariate random functions with increments which are stationary of orderk. The covariance between increments of different variables is modeled by means of the pseudo-cross-covariance function. Criteria are formulated to which the parameters of pseudo-cross-covariance functions must comply so as to ensure positive-definiteness. Cokriging equations and the induced cokriging equations are given. The study is illustrated by an example from soil science.     

A viable mechanism for the production of energy in active galactic nuclei

It is suggested that a collapsing supermassive object, which acts as an ultra-high energy particle accelerator, is the precursor of an active galactic nucleus and that the gravitational energy released during the collapse of the object is locked in the quark-gluon plasma permeated by leptons into which the entire matter in the core of the object is converted as a result of the collapse. It is also pointed out that the collapse of the object to a space-time singularity is inhibited by Pauli's exclusion principle as well as by Heisenberg's uncertainty principle and that the object explodes, before it could collapse to a singularity, thereby releasing the enormous amount of energy locked in the quark-gluon plasma.     

Recharge and salinization in the Madrid Basin

The purpose of this work was to reinvestigate the existing hydrogeological conceptual model of the basin of Madrid, Spain. A cumulative chemical isotopic diagram which enabled the distinction between different groups of water as well as calculation of the mode of their blending was used for this investigation. It was found that the groups of discharge were lighter in their isotopic composition than that of recharge. The previous explanation of this fact, backed by carbon-14 dating, was the long residence time due to flow lines going down to depths of more than 1000 m. This flow model assumes homogenous conditions to these depths. This assumption can not be supported by evidence from deep wells. Thus a modified model is suggested which maintains homogenous conditions only to about 300 m and a deep confined aquifer below containing paleowater. The higher degree of depletion of this water has been explained by a colder climate on top of an altitude effect. Another interesting observation was the correlation between the isotopic composition of the rains, the month of the rain event and the composition of the recharge group groundwater. It could be seen that the winter rains resemble the groundwater composition, which shows that practically all the spring and summer rains were evapotranspirated.