Impact processing of chondritic planetesimals: Siderophile and volatile element fractionation in the Chico L chondrite

Abstract— A large impact event 500 Ma ago shocked and melted portions of the L‐chondrite parent body. Chico is an impact melt breccia produced by this event. Sawn surfaces of this 105 kg meteorite reveal a dike of fine‐grained, clast‐poor impact melt cutting shocked host chondrite. Coarse (1–2 cm diameter) globules of FeNi metal + sulfide are concentrated along the axis of the dike from metal‐poor regions toward the margins. Refractory lithophile element abundance patterns in the melt rock are parallel to average L chondrites, demonstrating near‐total fusion of the L‐chondrite target by the impact and negligible crystal‐liquid fractionation during emplacement and cooling of the dike. Significant geochemical effects of the impact melting event include fractionation of siderophile and chalcophile elements with increasing metal‐silicate heterogeneity, and mobilization of moderately to highly volatile elements. Siderophile and chalcophile elements ratios such as Ni/Co, Cu/Ga, and Ir/Au vary systematically with decreasing metal content of the melt. Surprisingly small (?10²) effective metal/silicate‐melt distribution coefficients for highly siderophile elements probably reflect inefficient segregation of metal despite the large degrees of melting. Moderately volatile lithophile elements such K and Rb were mobilized and heterogeneously distributed in the L‐chondrite impact breccias whereas highly volatile elements such as Cs and Pb were profoundly depleted in the region of the parent body sampled by Chico. Volatile element variations in Chico and other L chondrites are more consistent with a mechanism related to impact heating rather than condensation from a solar nebula. Impact processing can significantly alter the primary distributions of siderophile and volatile elements in chondritic planetesimals.     

Results of Photometric and Polarimetric Observations of the Fuor V1057 Cyg from the Time of an Outburst to the Present

Observations of the brightness, color, and polarization of the fuor V1057 Cyg over more than 30 years are presented and briefly discussed. Variability of the linear polarization was found.     

SHRIMP U–Pb ages of diagenetic and hydrothermal xenotime from the Archaean Witwatersrand Supergroup of South Africa

SHRIMP dating of xenotime overgrowths on detrital zircon grains can constrain maximum durations since diagenesis and therefore provide minimum dates of sediment deposition. Thus, xenotime dating has significant economic application to Precambrian sediment-hosted ore deposits, such as Witwatersrand Au–U, for which there are no precise depositional ages. The growth history of xenotime in the Witwatersrand Supergroup is texturally complex, with several phases evident. The oldest authigenic xenotime ²⁰⁷Pb/²⁰⁶Pb age obtained in sandstone underlying the Vaal Reef is 2764 ± 5 Myr (1 σ), and most likely represents a mixture of diagenetic and hydrothermal growth. Nevertheless, this represents the oldest authigenic mineral age yet recorded in the sequence and provides a minimum age of deposition. Other xenotime data record a spread of ages that correspond to numerous post-diagenetic thermotectonic events (including a Ventersdorp event at ≈ 2720 Ma) up to the ≈2020 Ma Vredefort event.     

Near-Infrared Imaging Spectrophotometry Of Comet C/1995 O1 (Hale-Bopp) Near Perihelion

We present 1- to 5-μm broadband and CVF images of comet Hale-Bopp taken 1997 February 10.5 UT, 50 days before perihelion. All the images exhibit a nonspherical coma with a bright “ridge” in the direction of the dust tail approximately 10″ from the coma. Synthetic aperture spectrophotometry implies that the optically important grains are of a radius ≤0.4 μm; smallest radius for any comet seen to date. The variation of the integrated surface brightness with radial distance from the coma (ρ) in all the images closely follows the “steady state” ρ⁻¹ model for comet dust ablation (Gehrz and Ney, 1992). The near-infrared colors taken along the dust tail are not constant implying the dust grain properties vary with coma distance. This revised version was published online in July 2006 with corrections to the Cover Date.     

Evolutionary state of W UMa-type systems

The evolutionary status of a sample of 31 W UMa-type systems (20 of W, 9 of A, and 2 of A/W sub-class) is examined and discussed on the basis of their positions in the H-R, mass-radius and mass-luminosity diagrams. The absolute elements of these systems have been evaluated by use of their spectroscopic and photometric data as they were found in the literature. Since different analysis methods have been used by the various investigators this gives the opportunity to make different H-R, mass-radius and mass-luminosity diagrams, according to the method used, and compare the results.Moreover, from the spectral type-period diagram of those systems that have spectral types from O to G2 it was found that all of them lie in the evolved region. Finally, the log (L _l/L _s) log (M _l/M _s) diagrams are presented and discussed.     

Finite element formulation and algorithms for unsaturated soils. Part II: Verification and application

The finite‐element formulation and integration algorithms developed in Part I are used to analyse a number of practical problems involving unsaturated and saturated soils. The formulation and algorithms perform well for all the cases analysed, with the robustness of the latter being largely insensitive to user‐defined parameters such as the number of coarse time steps and error control tolerances. The efficiency of the algorithms, as measured by the CPU time consumed, does not depend on the number of coarse time steps, but may be influenced by the error control tolerances. Based on the analyses presented here, typical values for the error control tolerances are suggested. It is also shown that the constitutive modelling framework presented in Part I can, by adjusting one constitutive equation and one or two material parameters, be used to simulate soils that expand or collapse upon wetting. Treating the suction as a strain variable instead of a stress variable proves to be an efficient and robust way of solving suction‐dependent plastic yielding. Moreover, the concept of the constitutive stress is a particularly convenient way of handling the transition between saturation and unsaturation. Copyright © 2003 John Wiley & Sons, Ltd.     

Correcting systematic effects in a large set of photometric light curves

We suggest a new algorithm to remove systematic effects in a large set of light curves obtained by a photometric survey. The algorithm can remove systematic effects, such as those associated with atmospheric extinction, detector efficiency, or point spread function changes over the detector. The algorithm works without any prior knowledge of the effects, as long as they linearly appear in many stars of the sample. The approach, which was originally developed to remove atmospheric extinction effects, is based on a lower rank approximation of matrices, an approach which has already been suggested and used in chemometrics, for example. The proposed algorithm is especially useful in cases where the uncertainties of the measurements are unequal. For equal uncertainties, the algorithm reduces to the Principal Component Analysis (PCA) algorithm. We present a simulation to demonstrate the effectiveness of the proposed algorithm and we point out its potential, in the search for transit candidates in particular.     

Similarities between Circular Polarization in Galactic Jet Sources and AGN

We compare the observational properties of the circular polarization in Galactic jet sources with that observed in AGN, and outline the constraints they place on the mechanism responsible for the circular polarization. We also discuss the implications of the time scale of polarization variations on the mechanism responsible for the circular polarization.     

Evidence for the loss of snow-deposited MSA to the interstitial gaseous phase in central Antarctic firn

We have examined several MSA (methanesulfonic acid) records from the upper 200 m of the Antarctic ice sheet and in particular the new Dome F profile. At all the four sites studied, concentration profiles exhibit similar patterns as a function of depth. They suggest that snow metamorphism and solid phase migration are responsible for a marked release of gaseous MSA to interstitial firn air as well as probably to the free atmosphere, in particular at extremely low accumulation sites. Snow acidity can also modify MSA concentration. It is proposed that, below the upper few metres where the communication with the free atmosphere is possible, gaseous MSA may remain in the firn layers and be entrapped later in air bubbles at pore close-off, i.e. when firn is transformed into ice. Chemical measurements on the firn core do not take into account the MSA released to the gaseous phase, but this fraction is measurable in ice samples. In spite of these alterations occurring in the firn layers, relative changes of the atmospheric MSA concentration in the past are probably still there deep within the Antarctic ice sheet. However, for glacial periods, different processes have to be considered in relation to modified aerosol properties.