Coalification in Carboniferous sediments from the Lötschberg base tunnel

Vitrinite reflectance (Rr), proximate analysis and carbon isotope composition (δ¹³C) have been used to characterise coal samples from two zones of Late Carboniferous sediments (Gastern and Ferden) in the Aar massif where they are penetrated by the Lötschberg base tunnel (constructed between 1999 and 2005). Samples are characterised by variable ash yields (21.7–93.9%; dry basis); those with ash yields of less than ~50% and with volatile matter content (V;dry ash-free basis) within the limits 2 < V% ≤ 8 are anthracite. Values of Rr range from 3.89% to 5.17% and indicate coalification to the rank of anthracite and meta-anthracite in both Gastern and Ferden Carboniferous zones. Samples of anthracite and shale from the Gastern Carboniferous exhibit a relatively small range in δ¹³C values (–24.52‰ to –23.38‰; mean: –23.86‰) and are lighter than anthracite samples from the Ferden Carboniferous (mean: –22.20‰). The degree of coalification in the Gastern and Ferden Carboniferous zones primarily depends on the maximum rock temperature (T) attained as a result of burial heating. Vitrinite reflectance based estimates of T range from ~290° –360 °C. For a proposed palaeogeothemal gradient of 25 ° C/km at the time of maximum coalification the required overburden is attributable to relatively thin autochtonous Mesozoic/Cenozoic sedimentary cover of the Aar massif and Gastern granite and deep tectonic burial beneath advancing Helvetic, Ultrahelvetic and Prealpine (Penninic) nappes in Early Oligocene to Miocene.     

Recommended Values of 239Pu, 240Pu and 239+240Pu Concentrations in Reference Material IAEA-315 (Marine Sediment) Estimated by Thermal Ionisation Mass Spectrometry, Inductively Coupled Plasma-Mass Spectrometry and Alpha Spectrometry

The recommended concentrations of ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu in reference material IAEA‐315 (marine sediment) were estimated by three analytical methods: isotope dilution thermal ionisation mass spectrometry (TIMS), isotope dilution inductively coupled plasma‐mass spectrometry (ICP‐MS) and alpha spectrometry. The determination of ²³⁹Pu and ²⁴⁰Pu (^239+240Pu by alpha spectrometry) was carried out with samples from randomly selected bottles using each method. Plutonium‐238 was also measured by alpha spectrometry. A plutonium‐242 reference material was used as a spike for the quantitative analysis. The influence of ²⁴²Pu in the samples was therefore calculated; however, this contribution was less than the range of uncertainty and did not influence the final results. The obtained data were statistically analysed using variance component analysis and paired comparison. The combined standard uncertainties from “method/measurement”, “bottle” and “sub‐sample” were in the order of 3 to 6%. The main contributions to the uncertainty were from the material heterogeneity and from systematic differences between methods. Based on this study with twenty‐seven analyses using 10–14 g sample mass, concentrations of (38 ± 3) Bq kg^?1, (28 ± 3) Bq kg^?1 and (66 ± 4) Bq kg^?1 are proposed as recommended values for ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu, respectively, and (9.5 ± 0.4) Bq kg^?1 for ²³⁸Pu as an information value in reference material IAEA‐315. In mass concentration units, these amount to (16.4 ± 1.2) ng kg^?1, (3.3 ± 0.4) ng kg^?1 and (0.015 ± 0.003) ng kg^?1 for ²³⁹Pu, ²⁴⁰Pu and ²³⁸Pu, respectively. The certified reference materials NIST 4350B and NIST 4354 were also analysed by TIMS for quality assurance of the method used in this study.     

Changing grading of soil: effect on critical states

Examples of situations are presented where the grading of a soil changes during its lifetime either by crushing of particles leading to an increase of fine material or by slow transport of fine particles with seepage leading to a decrease of fine material. Such grading changes influence the basic constitutive properties of the soil, in particular properties such as critical states which are dependent on the available range of densities of packing. Discrete element modelling is used to show the dependence of critical state conditions on grading and the way in which the particle assembly seeks out new critical state conditions as the grading changes.     

Frequency modified fourier transform and its application to asteroids

Recently a method has been suggested to analyze the chaotic behaviour of a conservative dynamical system by numerical analysis of the fundamental frequencies. Frequencies and amplitudes are determined step by step. As the frequencies are not generally orthogonal, a Gramm-Schmidt orthogonalization is made and for each new frequency the old amplitudes of previously determined frequencies are corrected. For a chaotic trajectory variations of the frequencies and amplitudes determined over different time periods are expected. The change of frequencies in such a calculation is a measure of the chaoticity of the trajectory. While amplitudes are corrected, the frequencies (once determined) are constant. We suggest here simple linear corrections of frequencies for the effect of other close frequencies. The improvement of frequency determination is demonstrated on a model case. This method is applied to the first fifty numbered asteroids.     

Nd,Sr, and Pb isotopic characteristics of Cretaceous intrusive rocks from deep levels of the Sierra Nevada batholith,Tehachapi Mountains,California

The Cretaceous gabbroic to granitic intrusive rocks of the Tehachapi Mountains were emplaced at depths of 25–30 km and thus afford a view of deep processes in the Sierra Nevada batholith. They consist of the 115 Ma Tehachapi suite and the 100 Ma Bear Valley suite; new zircon U-Pb age data reveal the presence of the latter as far west as Grapevine Canyon. The Nd, Sr, Pb, and O isotopic whole-rock data and zircon Pb inheritance patterns for the bulk of the suites suggest an origin by mixing between depleted mantlederived magmas and metasedimentary material with a substantial component of old continental material. However, this mixing is not evident in variations between isotopic ratios and chemical and lithologic parameters. This implies that isotopic hybridization of magmas took place deeper than 30 km, and that fractionation processes are likely responsible for the bulk of the chemical variation in this part of the Sierra Nevada batholith. Consideration of the isotopic data in the context of the Sierra Nevada batholith as a whole suggests that the well-known east-to-west isotopic gradients in the batholith may reflect a change in the average isotopic character of the preintrusive frame-work rather than a change in amount of crustal component. On the other hand, the lack of areal gradients in Sr and Nd isotopic ratios in the main study area may indicate a lack of pronounced gradation at deep levels, at least within the western batholith.     

Retrograde fluid infiltration in the high-grade Modum Complex South Norway: evidence for age,source and REE mobility

The high-grade metamorphic basement of the Modum Complex, South Norway,exhibits retrogradation and alteration due to late stage fluid infiltration.Extensive alteration zones of albite-and calcite-rich veining occur especiallywithin and around numerous metagabbros. The gabbros, intruded at 1224±15Ma, are now partly altered to amphibolites due to the subsequent high-grade metamorphism.Two generations of albite-rich rocks have been recognized: (1) a fine-grained, foliated type;(2) a coarse-grained, crosscutting type. Both types show a typical greenschist facies mineralassemblage; albite ± actinolite ± chlorite ± talc. The calcite veins/dykesrepresent a younger generation of veins than both albite-rich types. U–Pb data for spheneof type (1) yielded an age of 1080±3 Ma, determining a point on the retrogradeP-T-t path of the Modum Complex. Increasing albitisation of themetagabbros leads to a decrease in(¹⁴³ND/¹⁴⁴Nd)_oand an increase in (⁸⁷Sr/⁸⁶)_o.Albite- and calcite-rich samples show negative _Nd and positive _Sr, suggesting that fluids which interacted with the metagabbros originated from a crustal reservoir. The Nd and Sr isotopic data show disequilibrium at the microscale as well as at the macroscale. Negative Sm–Nd model ages of the albite-rich rocks demonstrate that rare-earth elements (REEs) were mobile and fractionated during albitisation.     

A new titanium-bearing calcium aluminosilicate phase: II. Crystallography and crystal chemistry of grains formed in slowly cooled melts with bulk compositions of calcium- aluminum-rich inclusions

Abstract The crystallography and crystal chemistry of a new calcium-titanium-aluminosilicate mineral (UNK) observed in synthetic analogs to calcium-aluminum-rich inclusions (CAIs) from carbonaceous chondrites was studied by electron diffraction techniques. The unit cell is primitive hexagonal or trigonal, with a = 0.790 ± 0.002 nm and c = 0.492 ± 0.002 nm, similar to the lattice parameters of melilite and consistent with cell dimensions for crystals in a mixer furnace slag described by Barber and Agrell (1994). The phase frequently displays an epitactic relationship in which melilite acts as the host, with (0001)_UNK | (001)_mel and <10T0>_UNK | <100>_mel. If one of the two space groups determined by Barber and Agrell (1994) for their sample of UNK is applicable (P3ml or P31m), then the structure is probably characterized by puckered sheets of octahedra and tetrahedra perpendicular to the c-axis with successive sheets coordinated by planar arrays of Ca. In this likely structure, each unit cell contains three Ca sites located in mirror planes, one octahedrally coordinated cation located along a three-fold axis and five tetrahedrally coordinated cations, three in mirrors and two along triads. The octahedron contains Ti but, because there are 1.3–1.9 cations of Ti/formula unit, some of the Ti must also be in tetrahedral coordination, an unusual but not unprecedented situation for a silicate. Tetrahedral sites in mirror planes would contain mostly Si, with lesser amounts of Al while those along the triads correspondingly contain mostly Al with subordinate Ti. The structural formula, therefore, can be expressed as with Si + Ti = 4. Compositions of meteoritic and synthetic Ti-bearing samples of the phase can be described in terms of a binary solid solution between the end-members Ca₃TiAl₂Si₃O₁₄ and Ca₃Ti(AlTi)(AlSi₂)O₁₄. A Ti-free analog with a formula of Ca₃Al₂Si₄O₁₄ synthesized by Paque et al. (1994) is thought to be related structurally but with the octahedral site being occupied by Al, that is      

Particle acceleration and the decay of soft X-ray non-thermal line broadening in solar flares

The relationship between the production of -ray emitting particles and non-thermal soft X-ray line broadening is investigated. A model of particle acceleration via the stochastic interaction with MHD turbulence is assumed and the time development of the wave energy density derived under the condition of energy conservation between waves and particles. The inferred numbers and energy distribution of accelerated protons for four -ray flares are used to define the wave energy density and its temporal development. The presence of Alfvén wave turbulence is considered as the source of the non-thermal motions in the ambient plasma. These motions are observed as excess widths in the soft X-ray line emission from these events. The decay of the waves via the particle acceleration process is compared with the observed decays of this non-thermal line broadening. Our results show that both the -ray emission and excess soft X-ray line widths in these flares can be explained by the single physical phenomenon of Alfvén wave turbulence.     

Mechanisms of shrubland expansion: land use,climate or CO2?

Encroachment of trees and shrubs into grasslands and the thicketization of savannas has occurred worldwide over the past century. These changes in vegetation structure are potentially relevant to climatic change as they may be indicative of historical shifts in climate and as they may influence biophysical aspects of land surface-atmosphere interactions and alter carbon and nitrogen cycles. Traditional explanations offered to account for the historic displacement of grasses by woody plants in many arid and semi-arid ecosystems have centered around changes in climatic, livestock grazing and fire regimes. More recently, it has been suggested that the increase in atmospheric CO₂ since the industrial revolution has been the driving force. In this paper we evaluate the CO₂ enrichment hypotheses and argue that historic, positive correlations between woody plant expansion and atmospheric CO₂ are not cause and effect.Please direct all correspondence to the senior author.