Barium uptake into the shells of the common mussel (Mytilus edulis) and the potential for estuarine paleo-chemistry reconstruction

In this study we test if calcite shells of the common mussel, Mytilus edulis, contain barium in proportion to the water in which they grew. Similar to all bivalves analyzed to date, the [Ba/Ca]_shell profiles are characterized by a relatively flat background [Ba/Ca]_shell, interrupted by sharp [Ba/Ca]_shell peaks. Previous studies have focused on these [Ba/Ca]_shell peaks, but not on the background [Ba/Ca]_shell. We show that in both laboratory and field experiments, there is a direct relationship between the background [Ba/Ca]_shell and [Ba/Ca]_water in M. edulis shells. The laboratory and field data provided background Ba/Ca partition coefficients (D_Ba) of 0.10 ± 0.02 and 0.071 ± 0.001, respectively. This range is slightly higher than the D_Ba previously determined for inorganic calcite, and slightly lower than foraminiferal calcite. These data suggest that M. edulis shells can be used as an indicator of [Ba/Ca]_water, and therefore, fossil or archaeological M. edulis shells could be used to extend knowledge of estuarine dissolved Ba throughputs back in time. Moreover, considering the inverse relationship between [Ba/Ca]_water and salinity, background [Ba/Ca]_shell data could be used as an estuary specific indicator of salinity. The cause of the [Ba/Ca]_shell peaks is more confusing, both the laboratory and field experiments indicate that they cannot be used as a direct proxy of [Ba/Ca]_water or phytoplankton production, but may possibly be caused by barite ingestion.     

Comparative planetary mineralogy: Implications of martian and terrestrial jarosite. A crystal chemical perspective

The importance of the discovery of jarosite at the Meridiani Planum region of Mars is discussed. Terrestrial studies demonstrate that jarosite requires a unique environment for its formation, crystallizing from highly acidic (pH < 4) S-rich brines under highly oxidizing conditions. A likely scenario for jarosite formation on Mars is that degassing of shallow magmas likely released SO₂ that reacted with aqueous solutions in shallow aquifers or on the martian surface. This interaction forms both H₂SO₄ and H₂S. A martian oxidant must be identified to both oxidize H₂S to produce the required acidity of the fluid, and to oxidize Fe²⁺ to Fe³⁺. We suggest that reactions involving both sulfur and the reduction of CO₂ to CO may provide part of the answer. The jarosite crystal structure is truly remarkable in terms of its tolerance for the substitution of a large number of different cations with different ionic radii and charges. The structure accommodates hydrogen, oxygen, and sulfur, the stable isotope systematics of which are strong recorders of low-temperature fluid-rock-atmosphere interactions. Jarosite has been proven to be a robust chronometer for Ar-Ar and K-Ar dating techniques, and there is every reason to believe that U-Pb, Rb-Sr, and Nd-Sm techniques for older jarosite from Mars will also be robust. Although the discovery of jarosite on Mars alone, with no other analytical measurements on the phase, has given us insights to martian surficial processes, the true power of jarosite can not be exploited until jarosite is sampled and returned from Mars. Mars sample return is a long way off but, until then, we should be vigilant about examining martian meteorites for alteration assemblages that contain jarosite. A suite of jarosite samples representing a significant time span on Mars may hold the key to reading the record of martian atmospheric evolution.     

Modelling weathering processes at the catchment scale: The WITCH numerical model

A numerical model of chemical weathering in soil horizons and underlying bedrock (WITCH) has been coupled to a numerical model of water and carbon cycles in forest ecosystems (ASPECTS) to simulate the concentration of major species within the soil horizons and the stream of the Strengbach granitic watershed, located in the Vosges Mountains (France). For the first time, simulations of solute concentrations in soil layers and in the catchment river have been performed on a seasonal basis. The model is able to reproduce the concentrations of most major species within the soil horizons, as well as catching the first-order seasonal fluctuations of aqueous calcium, magnesium and silica concentrations. However, the WITCH model underestimates concentrations of Mg²⁺ and silica at the spring of the catchment stream, and significantly underestimates Ca²⁺ concentration. The deficit in calculated calcium can be compensated for by dissolution of trace apatite disseminated in the bedrock. However, the resulting increased Ca²⁺ release yields important smectite precipitation in the deepest model layer (in contact with the bedrock) and subsequent removal of large amount of silica and magnesium from solution. In contrast, the model accurately accounts for the concentrations of major species (Ca, Mg and silica) measured in the catchment stream when precipitation of clay minerals is not allowed. The model underestimation of Mg²⁺ and H₄SiO₄ concentrations when precipitation of well crystallized smectites is allowed strongly suggests that precipitation of well crystallized clay minerals is overestimated and that more soluble poorly crystallized and amorphous materials may be forming. In agreement with observations on other watersheds draining granitic rocks, this study indicates that highly soluble trace calcic phases control the aqueous calcium budget in the Strengbach watershed.     

Heat-producing elements in the lunar mantle: Insights from ion microprobe analyses of lunar pyroclastic glasses

We provide new estimates for the abundance of heat-producing elements in the lunar mantle by using SIMS techniques to measure the concentrations of thorium and samarium in lunar pyroclastic glasses. Lunar pyroclastic glasses are utilized in this study because they represent quenched products of near-primary melts from the lunar mantle and as such, they provide compositional information about the mantle itself. Thorium and samarium were measured because: (1) Th is not significantly fractionated from Sm during partial melting of the pyroclastic glass source regions, which are dominated by olivine and pyroxene. Therefore, the Th/Sm ratios that we measure in the pyroclastic glasses reflect the Th/Sm ratio of the pyroclastic glass source regions. (2) Strong correlations between Th, U, and K on the Moon allow us to use measured Th concentrations to estimate the concentrations of U and K in the pyroclastic glasses. (3) Th, Sm, U, and K are radioactive elements and as such, their concentrations can be used to investigate heat production in the lunar mantle.The results from this study show that the lunar mantle is heterogeneous with respect to heat-producing elements and that there is evidence for mixing of a KREEP component into the source regions of some of the pyroclastic glasses. Because the source regions for many of the glasses are deep (?400 km), we propose that a KREEP component was transported to the deep lunar mantle. KREEP enriched sources produce 138% more heat than sources that do not contain KREEP and therefore, could have provided a source of heat for extended periods of nearside basaltic magmatism. Data from this study, in conjunction with models for the fractional crystallization of a lunar magma ocean, are used to show that the average lunar mantle contains 0.15 ppm Th, 0.54 ppm Sm, 0.039 ppm U, and 212 ppm K. This is a greater enrichment in radiogenic elements than some earlier estimates, suggesting a more prolonged impact of radiogenic heat on nearside basaltic volcanism.     

Exposure ages from relict lateral moraines overridden by the Fennoscandian ice sheet

Lateral moraines constructed along west to east sloping outlet glaciers from mountain centred, pre-last glacial maximum (LGM) ice fields of limited extent remain largely preserved in the northern Swedish landscape despite overriding by continental ice sheets, most recently during the last glacial. From field evidence, including geomorphological relationships and a detailed weathering profile including a buried soil, we have identified seven such lateral moraines that were overridden by the expansion and growth of the Fennoscandian ice sheet. Cosmogenic ¹⁰Be and ²⁶Al exposure ages of 19 boulders from the crests of these moraines, combined with the field evidence, are correlated to episodes of moraine stabilisation, Pleistocene surface weathering, and glacial overriding. The last deglaciation event dominates the exposure ages, with ¹⁰Be and ²⁶Al data derived from 15 moraine boulders indicating regional deglaciation 9600 ± 200 yr ago. This is the most robust numerical age for the final deglaciation of the Fennoscandian ice sheet. The older apparent exposure ages of the remaining boulders (14,600-26,400 yr) can be explained by cosmogenic nuclide inheritance from previous exposure of the moraine crests during the last glacial cycle. Their potential exposure history, based on local glacial chronologies, indicates that the current moraine morphologies formed at the latest during marine oxygen isotope stage 5. Although numerous deglaciation ages were obtained, this study demonstrates that numerical ages need to be treated with caution and assessed in light of the geomorphological evidence indicating moraines are not necessarily formed by the event that dominates the cosmogenic nuclide data.     

Evaluation of twenty four new Gossypium hirsutum strains for growth, yield, fibre quality and ClCuV resistance under environment of Punjab, Pakistan

Twenty four new strains were tested for their yield, quality and Leaf Curl Virus (ClCuV) resistance. NIAB-111/S, NIAB-98 and NIAB-999 were significantly high fruit bearing varieties at 90 days completing 59.54, 48.26 and 46.00% fruiting respectively. Seed cotton yield of VH-142 was highest with 5417 kgha^?1 and 52 per plant boll bearing, DNH-57 and NIAB-999 remained second and third with 5234 and 5095 kg ha^?1 seed cotton yield, respectively. BH-160 and CRIS-467 were found to be second and third highest boll bearing varieties with 50.97 and 40.20 per plant average bolls respectively. Plant height in CRIS-467, MNH-642 and SLH-224 was significantly higher in comparison to other varieties.NIAB-98, CIM-499 and CIM-506 were found short stature varieties in comparison with other but out of these NIAB-98 and CIM-506 were in high yielding position and CIM-499 was found medium yielder variety. GOT% of MNH-642 remained highest having value of 45.00%. While GOT%. of NIBGE-1, CRIS-168 and CRIS-467 was at lowest position with 35.73, 35.89 and 36.62% respectively. NIAB-111, CIM-499 and BH-160 were at first position in terms of fibre fineness with micronaire values 3.98, 4.00 and 4.07 ìg/inch having fibre length 28.53, 31.38 and 30.23 mm respectively. Out of 26 varieties, 16 varieties resulted maturity index in the range of 85.03% and 90.30% with highest maturity index in case of NIBGE-1 (i.e. 90.30%) followed by NIAB-999 and MNH-642 with 89.55 and 85.5% respectively.CRIS-168, CRIS-468 and CRIS-467 were found viral susceptible.     

Determination of adsorption efficiency based on cation exchange capacity related to red earth, bone meal and pulverised fly ash as ameliorants to lead contaminated soils

Efficient treatment strategies to reduce the toxicity of metal contaminated soil using cost effective techniques such as naturally available ameliorants and industrial waste have emerged. Three easily available amendments were determined: Bone meal, red earth/mud and pulverised fly ash (PFA). The application of ameliorants offered a possible alternative in situ remediation of contaminated sites without disruption to the ecosystem profile. In comparison to other ameliorants Red earth/mud was found to be efficient in intercepting lead leaching from soil amended with different lead compounds based on CEC (Cmol/g). This was associated with the heterogeneous adsorbency principle in red mud which is associated with its ability to bind metal ions (M²⁺) onto one or two types of surface sites at pH< 6.0. However areas that need to be studied and assessed (for public health concerns) critically for wide spread application of all the ameliorants include off-site effects of the ameliorants.     

Removal of airborne hexavalent chromium mist using chitosan gel beads as a new control approach

Airborne hexavalent chromium is a known human respiratory carcinogen and allergen. Many workers are exposed to hexavalent chromium in various processes which chromium electroplating plants are the most common. In this study, the feasibility of a new control approach to remove this pollutant using chitosan beads as a biosorbent was investigated. Hexavalent chromium sorption was studied relative to pH, pollution concentration, sorbent concentration, temperature, and air velocity using one factor at a time approach and Taguchi experimental design. Polluted air with different chromium mist concentrations (10–5000 μg/m³) was contacted to chitosan beads (3.3–20 g/L), floating in distilled water with adjusted pH (3–7), using an impinger at different temperatures (20 and 35 °C), and various velocities (1.12 and 2.24 m/s). The ANOVA test result showed that, there were statistical significant differences between factor levels except optimized pH levels. The higher ions removal efficiencies were achieved at lower levels of air velocities, pollution concentrations, and higher levels of solution pH values, temperatures, and sorbent concentrations.     

Slow arsenic poisoning of the contaminated groundwater users

This paper gives impact of Arsenic contaminated water on human health as well as overview of the extent and severity of groundwater arsenic contamination in Bangladesh. Scalp hair is the most important part of the human body to monitor the accumulation of this type of poison. Therefore, an experiment has been carried out by Neutron Activation Analysis (NAA) at Atomic Energy Research Establishment (AERE), Savar, Dhaka, Bangladesh on human hair of corresponding tube well water users of these areas to determine the total accumulation of arsenic to their body. Hair samples collected from the region where the groundwater was found highly contaminated with arsenic. The obtained results of arsenic concentration in the lower age (Hb) categories of users (below 12 years of age users) is in the range of 0.33 to 3.29 /gmg/g (ppm) and that in the Hu categories (upper 12 years of age users) is 0.47 to 6.64 μg/g (ppm). Where as maximum permissible range is 1 ppm certified from WHO. Results show that the peoples are highly affected where the groundwater is highly contaminated with arsenic and acts as the primary source of arsenic poisoning among the peoples of those areas. The results indicate that human population is affected with arsenic locally using the contaminated water for a long time.     

Effect of trace metals on halophilic and mixed cultures in anaerobic treatment

Trace metals are known to stimulate the activity of anaerobic methanogenic bacteria involved in the degradation of organic matter. The objective of this research was to investigate the effect of three trace metals, iron, nickel and cobalt on the activity of halophilic methanogens, digester sludge and a mixed culture of halophilic bacteria and digester sludge, at various salt concentrations. Iron slightly stimulated both initial and maximum specific methanogenic activity (SMA) of halophilic methanogens at all salt concentrations. Iron addition was also able to increase both initial and maximum SMA of the mixed culture. Iron could not stimulate either initial or maximum SMA of digester sludge at salt concentrations of more than 10 g/L. Adding cobalt showed no benefit on the initial and maximum SMA of halophilic methanogens. A slight increase in the initial SMA was observed in mixed culture when cobalt was injected to the system containing sodium concentrations of 10–30 g/L. At salt concentrations above 40 g/L, cobalt could stimulate the maximum SMA of mixed culture. No benefits were found when cobalt was added to the digester sludge at sodium concentrations higher than 20 g/L. Nickel was observed to increase the initial SMA of digester sludge at all salt concentrations, and the maximum SMA of mixed culture at salt concentrations of 30–50 g/L.