Crystallization conditions of Los Angeles, a basaltic Martian meteorite

The texture of Los Angeles (stone 1) is dominated by relatively large (0.5−2.0 mm) anhedral to subhedral grains of pyroxene, and generally subhedral to euhedral shocked plagioclase feldspar (maskelynite). Minor phases include subhedral titanomagnetite and ilmenite, Fe-rich olivine, olivine+augite-dominated symplectites [some of which include a Si-rich phase and some which do not], pyrrhotite, phosphate(s), and an impact shock-related alkali- and silica-rich glass closely associated with anhedral to euhedral silica grains. Observations and model calculations indicate that the initial crystallization of Mg-rich pigeonitic pyroxenes at ≤1150 °C, probably concomitantly with plagioclase, was followed by pigeonitic and augitic compositions between 1100 and 1050 °C whereas between 1050 and 920 to 905 °C pyroxene of single composition crystallized. Below 920 to 905 °C, single composition Fe-rich clinopyroxene exsolved to augite and pigeonite. Initial appearance of titanomagnetite probably occurred near 990 °C and FMQ-1.5 whereas at and below 990 °C and ≥FMQ-1.5 titanomagnetite and single composition Fe-rich clinopyroxene may have started to react, producing ilmenite and olivine. However, judging from the most common titanomagnetite compositions, we infer that most of this reaction likely occurred between 950 and 900 °C at FMQ-1.0±0.2 and nearly simultaneously with pyroxene exsolution, thus producing assemblages of pigeonite, titanomagnetite, olivine, ilmenite, and augite. We deem this reaction as the most plausible explanation for the formation of the olivine+augite-dominated symplectites in Los Angeles. But we cannot preclude possible contributions to the symplectites from the shock-related alkali- and silica-rich glass or shocked plagioclase, and the breakdown of Fe-rich pigeonite compositions to olivine+augite+silica below 900 °C. Reactions between Fe-Ti oxides and silicate minerals in Los Angeles and other similar basaltic Martian meteorites can control the T-fO₂ equilibration path during cooling, which may better explain the relative differences in fO₂ among the basaltic Martian meteorites.     

Flushing of dense, hypoxic water from a cavity of the Swan River estuary, Western Australia

Flushing of dense water from cavities of the upper reaches of the Swan River estuary in Western Australia was investigated using measured salinity and dissolved oxygen profiles and a two-dimensional, laterally averaged hydrodynamic model (TISAT). Seasonal flushing of dense, hypoxic bottom waters from a relatively deep site took place over ∼3 days at the onset of winter in 1994. Model simulations of the purging of this dense water did not correspond closely with changes in the densimetric Froude number. Purging, expressed as depth of the halocline as a fraction of the total cavity depth, occurred when the simulated mean horizontal velocity at 2 m depth (top of cavity) changed from negative to strongly positive, indicating arrest of upstream flow and continuous downstream flow. This corresponded to freshwater discharge of about 50 m³ s⁻¹. Oxygen depletion of bottom waters was closely related to stratification. Oxygen dynamics at the onset of winter river flow was analysed using an exponential decay model, assuning that there was no net inflow or outflow across the halocline and thus no vertical transport of oxygen during a period of strong stratification. The rate constant for oxygen decay at Ron Courtney Island (RCI) was estimated to be 0.232 d⁻¹ for this period. Bottom waters at RCI declined to less than 1 mg 1⁻¹ prior to complete flushing through increased river flows. This study provided in sights to how freshwater flows may be allocated to maintain suitable oxygen levels in the bottom waters of estuarine cavities.     

Enacting geographies

We conclude the editorial by glancing ahead to the individual papers. This overview seeks only to highlight motifs, themes, arcs and trajectories (since the papers will obviously exceed anything we might say about them).John Wylie's paper, An essay on ascending Glastonbury Tor, draws upon the work of Merleau Ponty and Heidegger to illustrate how the act of visualizing itself is always a making of seer and seen. The paper thus seeks to speak of a subjectivity produced and performed via practices of ascension and elevation, and, in doing so, to move towards a new understanding of visible landscape in terms of sensuous practices. Cataloguing his own ascent of Glastonbury Tor, Wylie seeks to enact the Tor for the reader, engendering its visibility, its cultural histories, and thus its sensuous reality through his narrative.Motifs of landscape and practice recur in Mitch Rose's paper, Landscape and Labyrinths, which seeks to sketch out a conceptual and methodological approach to cultural landscape beyond the structuralism of cultural geography, which, Rose argues, skewers landscape through stabilisations of meaning. An ontology of overdetermination and surplus, as elaborated by Althusser and Bataille, is offered by Rose as a possible means of becoming attentive to the excessiveness of landscape.Derek McCormack's A paper with an interest in rhythm moves from the false problematic of representing movement to become an exposition of movement within the folds of writing. In a virtuosic exploration of rhythm McCormack produces an animated space that moves, folds and achieves consistency via both non-subjectifying and subjectifying forces. Theoretical considerations are not side-stepped by this performance; rather, the particular rhythms of Deleuze, Guattari and Lefebvre are engaged and enfolded by the paper.Paul Harrison's paper The Caesura: Remarks on Wittgenstein's interruption of theory, or, why practices elude explanation, presents a precise and exacting philosophical exposition of the work of Ludwig Wittgenstein. Harrison uses the work of Wittgenstein to offer a diagnosis of idealism within much contemporary social analysis. Linking up with the special issue's concerns, Harrison suggests that it is the performative which occupies the space vacated by Idealism; a replacement of the Cartesian Ideals of certainty for 'infinitive', and distinctly geographic, understandings––taking -place, making -sense––which speak of the time of the present, not of all Time.     

An estuarine benthic index of biotic integrity for the Mid-Atlantic region of the United States. II. Index development

A benthic index of biotic integrity was developed for use in estuaries of the mid-Atlantic region of the United States (Delaware Bay estuary through Albemarle-Pamlico Sound). The index was developed for the Mid-Atlantic Integrated Assessment Program (MAIA) of the U.S. Environmental Protection Agency using procedures similar to those applied previously in Chesapeake Bay and southeastern estuaries, and was based on sampling in July through early October. Data from seven federal and state sampling programs were used to categorize sites as degraded or non-degraded based on dissolved oxygen, sediment contaminant, and sediment toxicity criteria. Various metrics of benthic community structure and function that distinguished between degraded and reference (non-degraded) sites were selected for each of five major habitat types defined by classification analysis of assemblages. Each metric was scored according to thresholds established on the distribution of values at reference sites, so that sites with low scoring metrics would be expected to show signs of degradation. For each habitat, metrics that correctly classified at least 50% of the degraded sites in the calibration data set were selected whenever possible to derive the index. The final index integrated the average score of the combination of metrics that performed best according to several criteria. Selected metrics included measures of productivity (abundance), diversity (number of taxa, Shannon-Wiener diversity, percent dominance), species composition and life history (percent abundance of pollution-indicative taxa, percent abundance of pollution-sensitive taxa, percent abundance of Bivalvia, Tanypodinae-Chironomidae abundance ratio), and trophic composition (percent abundance of deep-deposit feeders). The index correctly classified 82% of all sites in an independent data set. Classification efficiencies of sites were higher in the mesohaline and polyhaline habitats (81–92%) than in the oligohaline (71%) and the tidal freshwater (61%). Although application of the index to low salinity habitats should be done with caution, the MAIA index appeared to be quite reliable with a high likelihood of correctly identifying both degraded and non-degraded conditions. The index is expected to be of great utility in regional assessments as a tool for evaluating the integrity of benthic assemblages and tracking their condition over time.     

Investigating Landslides Caused by Earthquakes – A Historical Review

Post-earthquake field investigations of landslide occurrence have provided a basis for understanding, evaluating, and mapping the hazard and risk associated withearthquake-induced landslides. This paper traces thehistorical development of knowledge derived from these investigations. Before 1783, historical accounts of the occurrence of landslides in earthquakes are typically so incomplete and vague that conclusions based on these accounts are of limited usefulness. For example, the number of landslides triggered by a given event is almost always greatly underestimated. The first formal, scientific post-earthquake investigation that included systematic documentation of the landslides was undertaken in the Calabria region of Italy after the 1783 earthquake swarm. From then until the mid-twentieth century, the best information on earthquake-induced landslides came from a succession ofpost-earthquake investigations largely carried out by formal commissions that undertook extensive ground-based field studies. Beginning in the mid-twentieth century, when the use of aerial photography became widespread, comprehensive inventories of landslide occurrence have been made for several earthquakes in the United States, Peru, Guatemala, Italy, El Salvador, Japan, and Taiwan. Techniques have also been developed for performing ``retrospective' analyses years or decades after an earthquake that attempt to reconstruct the distribution of landslides triggered by the event. The additional use of Geographic Information System (GIS) processing and digital mapping since about 1989 has greatly facilitated the level of analysis that can applied to mapped distributions of landslides. Beginning in 1984, syntheses of worldwide and national data on earthquake-induced landslides have defined their general characteristics and relations between their occurrence and various geologic and seismic parameters. However, the number of comprehensive post-earthquake studies of landslides is still relatively small, and one of the most pressing needs in this area of research is for the complete documentation of landslides triggered by many more earthquakes in a wider variety of environments.     

The molecular universe

Helen J Fraser , Martin R S McCoustra and David A Williams present a simple guide to astrochemistry.
Molecules play a fundamental role in many regions of our universe. The science where chemistry and astronomy overlap is known as astrochemistry, a branch of astronomy that has risen in importance over recent years. In this article we review the significance of chemistry in several astronomical years. IN this article we review the significance of chemistry in several astronomical environments including the early universe, interstellar clouds, starforming regions and protoplanetary disks. We discuss theoretical models, laboratory experiments and observational data, and present several recent and exciting results that challenge our perception of the "molecular universe".     

Comet Ikeya-Zhang rises for the NAM

A possible naked-eye comet that may have been important in early cometary theory is announced by D J Asher , M E Bailey , A Christou , J McFarland , M F Muir and P P Rafferty .
Early indications sugest that Comet C/2002 (Ikeya-Zhang), discovered on 1 February 2002, may brighten to naked-eye visibility in late March 2002. It has also been suggested that it may be identical to one of the brighter comets of the 16th or 17th centuries, namely C/1532 R1 or C/1661 C1. The first of these, observed for more than 100 days towards the end of 1532, played an important role in the development of cometary theory. The second, although identified by Halley as having an orbit similar to that of the comet C/1532 R1, was not seen on its predicted return in 1788/1789 and so was presumably unrelated. Here we present long-term orbital integrations of C/2002 C1 which suggest that it orginated from the Oort cloud, and will be ejected again, within ˜0.3 Myr. There is a chance of 10–20% that it will end its life by falling into the Sun during a Halley-type phase of cometary evolution. The discovery of Ikeya-Zhang so closeto perigee by two amateur astonomers highlights the need for surveys covering both hemispheres to discover long-period and intermediate-period comets on Earth-crossing orbits.     

The CTBT and advances in earth science

David Booth and Peter Maguire report on a two-day meeting organized by the Royal Astronomical Society and the British Geophysical Association, that showed how scientific challenges generated by the Comprehensive Nuclear Test Ban Treaty have been addressed, and how they continue to stimulate advances in earth science.