Analyses of organic and inorganic contaminants in Salton Sea fish

Chemical contamination of fish from the Salton Sea, a quasi-marine lake in Southern California, could adversely impact millions of birds using the Pacific Flyway and thousands of humans using the lake for recreation. Bairdiella icistia (bairdiella), Cynoscion xanthulus (orangemouth corvina), and Oreochromis spp. (tilapia) were sampled from two river mouths and two nearshore areas of the Salton Sea. Muscle tissues were analyzed for a complete suite of 14 trace metals and 53 pesticides. Fish muscle tissues had concentrations of selenium ranging between 1.89 and 2.73 microg/g wet weight. 4,4'-DDE accounted for 94% of the total DDT metabolites. Total DDTs ranged between 17.1 and 239.0 and total PCBs between 2.5 and 18.6 ng/g wet weight. PCB congeners 132, 138, 153, 168, and 180 comprised over 50% of the total PCBs. Given the potential implementation of a commercial fishing at the Salton Sea in the future, the presence of persistent organic pollutants and selenium warrants further research into the effects of these mixtures on fish populations, and on wildlife and humans consuming fish.     

Multi-wavelength observations of the 1998 September 27 flare spray

We report on observations of a large eruptive event associated with a flare that occurred on 27 September 1998 made with the Richard B. Dunn Solar Telescope at Sacramento Peak Observatory (several wave bands including off-line-center H), in soft and hard X-rays (GOES and BATSE), and in several TRACE wave bands (including Feix/x 171 Å, Fexii 195 Å, and Civ 1550 Å). The flare initiation is signaled by two H foot-point brightenings which are closely followed by a hard X-ray burst and a subsequent gradual increase in other wavelengths. The flare light curves show a complicated, three-component structure which includes two minor maxima before the main GOES class C5.2 peak after which there is a characteristic exponential decline. During the initial stages, a large spray event is observed within seconds of the hard X-ray burst which can be directly associated with a two-ribbon flare in H. The emission returns to pre-flare levels after about 35 min, by which time a set of bright post-flare loops have begun to form at temperatures of about 1.0–1.5 MK. Part of the flare plasma also intrudes into the penumbra of a large sunspot, generally a characteristic of very powerful flares, but the flare importance in GOES soft X-rays is in fact relatively modest. Much of the energy appears to be in the form of a second ejection which is observed in optical and ultraviolet bands, traveling out via several magnetic flux tubes from the main flare site (about 60° from Sun center) to beyond the limb.     

Comparing the Correlative Holdridge Model to Mechanistic Biogeographical Models for Assessing Vegetation Distribution Response to Climatic Change

A well-established and widely used correlative climate-vegetation model (Holdridge Life Zone model) was compared to three mechanistic simulation models (BIOME2, Dynamic Global Phytogeography Model (DOLY), and Mapped Atmosphere-Plant-Soil System (MAPSS)) for the conterminous United States under contemporary climate and a set of future climates prescribed by three Global Circulation Model experiments. Output from the mechanistic models were from the Vegetation/Ecosystem Modeling and Analysis Project (VEMAP) intercomparison. Holdridge modeling approaches, using a Simple implementation (vegetation distribution based on biotemperature and precipitation alone) or a Full implementation (vegetation distribution based on biotemperature, precipitation, altitudinal region, latitudinal belt, and transitional vegetation zones), represented current potential natural U.S. vegetation poor to fair, respectively. The more sophisticated mechanistic models were superior at reproducing potential vegetation under current climate compared to Holdridge, although there was significant variability among these models. The Holdridge implementations generally showed similar or greater climate sensitivity with respect to spatial redistribution of vegetation compared to the mechanistic models run both with and without doubled CO₂ levels; however, the sensitivity of the Holdridge model depended on the implementation. Reduced sensitivity of the mechanistic models arises from direct (physiological) CO₂ effects and other compensating feedbacks not captured by the Holdridge model. The greater degree of physical realism in the mechanistic models makes them the model class of choice for climate impact assessment. However, under circumstances of limited data availability, computation resources, and access to mechanistic models and model expertise, simple correlational models such as Holdridge may be the only method that can be applied. The paper makes some recommendations on the use of the Holdridge model for impact assessment if it is the only available model.     

An empirical garnet (YAG) – xenotime thermometer

 A pronounced negative correlation between the yttrium concentration in garnet ([Y]_Grt) and temperature has been observed in xenotime (YPO₄)-bearing metapelites from central New England, USA. The [Y]_Grt decreases roughly two orders of magnitude (∼5500 to less than 100 ppm Y) over a 150 °C interval. A regression of ln([Y]_Grt) against estimated reciprocal temperature yields the following relationship:

Fish Remains from Homestead Cave and Lake Levels of the Past 13,000 Years in the Bonneville Basin

A late Quaternary ichthyofauna from Homestead Cave, Utah, provides a new source of information on lake history in the Bonneville basin. The fish, represented by 11 freshwater species, were accumulated between 11,200 and 1000 ¹⁴C yr B.P. by scavenging owls. The ⁸⁷Sr/⁸⁶Sr ratio of Lake Bonneville varied with its elevation; ⁸⁷Sr/⁸⁶Sr values of fish from the lowest stratum of the cave suggest they grew in a lake near the terminal Pleistocene Gilbert shoreline. In the lowest deposits, a decrease in fish size and an increase in species tolerant of higher salinities or temperatures suggest multiple die-offs associated with declining lake levels. An initial, catastrophic, post-Provo die-off occurred at 11,300–11,200 ¹⁴C yr B.P. and was followed by at least one rebound or recolonization of fish populations, but fish were gone from Lake Bonneville sometime before 10,400 ¹⁴C yr B.P. This evidence is inconsistent with previous inferences of a near desiccation of Lake Bonneville between 13,000 and 12,000 ¹⁴C yr B.P. Peaks in Gila atraria frequencies in the upper strata suggest the Great Salt Lake had highstands at 3400 and 1000 ¹⁴C yr B.P.     

Remineralization Ratios in the Subtropical North Pacific Gyre

Based on a new mixing model of two end-members, the water column remineralization ratios of P/N/C_org - O₂ = 1/13 ± 1/135 ± 18/170 ± 9 are obtained for the Hawaii Ocean Time-series (HOT) data set at station ALOHA. The traditional Redfield ratios of P/N/C_org/–O₂ = 1/16/106/138 have standard deviations of more than 50%, when they are based on the average composition of phytoplankton. Apparently, the remineralization processes in the water column have smoothed out the observed large variability of plankton compositions. A new molar formula for the remineralized plankton may be written as ₁₃₅H₂₈₀O₁₀₅N₁₃P or C₂₅(CH₂O)₁₀₁(CH₄)₉(NH₃)₁₃(H₃PO₄). Oxidation of this formula results inC₂₅(CH₂O)₁₀₁(CH₄)₉(NH₃)₁₃(H₃PO₄) + 170O₂ 135CO₂ + 132H₂O + 13NO₃ ^- + H₂PO₄ ^- + 14H⁺.For comparison, remineralization using Redfield's formula gives:(CH₂O)₁₀₆(NH₃)₁₆(H₃PO₄) + 138O₂ 106CO₂ + 122H₂O + 16NO₃ ^-+ H₂PO₄ ^- + 17H⁺     

Size Fractionation (Dissolved, Colloidal and Particulate) of Trace Metals in the Thur River, Switzerland

The distribution of some trace metals (Cu, Zn, Ni, Co,Fe, Mn) and of DOC over a particulate (> 1 m),a colloidal (size < 0.45 m and molecular weight > 10 kD) and an ultrafiltered fraction (< 10 kD)was determined at several sites on the Thur River,Switzerland, at various times of the year. Thecomplexation of Cu by strong ligands in theultrafiltrate and in the conventional filtrate (<0.45 m) was compared using a ligand-exchange/CSV method.The <0.45 m concentrations of Cu (from anaverage of 7 nM to 24 nM), Zn (<5–23 nM), Ni (5–13 nM),Co (1.5–3 nM) and Mn (7–92 nM)increased downstream. The major part of Cu, Zn, Niand Co usually occurred in the ultrafiltratefraction at all sites, whereas Fe and Mn were mostlyin the particulate fraction, under conditions of lowsuspended matter content (< 10 mg L^-1) in theriver. The percentage of metal in the colloidalfraction, with respect to the 0.45-m filtrate,decreased in the order: Cu (median 11%) > Zn Ni(median 5–6%) > Mn Co (median < 5%). DOCalso consisted mostly of molecules in the < 10 kDrange.Cu was strongly complexed by natural organic ligandsin all filtrate and ultrafiltrate samples. A largepart of the strong Cu binding ligands consisted ofcompounds in the < 10 kD range, but colloidalligands with similar properties also occurred. Cu wasdistributed among the dissolved and the colloidalligands, roughly in proportion to organic carbon.The colloidal fraction (as defined here) did notincrease in its proportional amount downstream and wasonly of limited significance in transporting traceelements in the Thur River under low discharge conditions.     

The Equation of State of Lakes

In recent years, a number of workers have studied the stability of deep lakes such as Lake Tanganyika, Lake Baikal and Lake Malawi. In this paper, the methods that can be used to determine the effect that the components of lakes have on the equation of state are examined. The PVT properties of Lakes have been determined by using apparent molal volume data for the major ionic components of the lake. The estimated PVT properties (densities, expansibility and compressibilities) of the lakes are found to be in good agreement with the PVT properties (P) of seawater diluted to the same salinity. This is similar to earlier work that showed that the PVT properties of rivers and estuarine waters could also be estimated from the properties of seawater.The measured densities of Lake Tanganyika were found to be in good agreement (± 2 × 10^-6 g cm^-3) with the values estimated from partial molal properties and the values of seawater at the same total salinity (S_T = 0.568). The increase in the densities of Lake Tanganyika waters increased due to changes in the composition of the waters. The measured increase in the measured density (45 × 10^-6 g cm^-3) is in good agreement (46 × 10^-6 g cm^-3) with the values calculated for the increase in Na⁺, HCO₃ ^-, Mg²⁺, Ca²⁺ and Si(OH)₄.Methods are described that can be used to determine the conductivity salinity of lakes using the equations developed for seawater. By combining these relationships with apparent molal volume data, one can relate the PVT properties of the lake to those of seawater.     

Modelling phosphorus transport in a surface irrigation drain

Understanding phosphorus (P) transport from agricultural land is essential to the development of effective management strategies that reduce the impact of agriculture on inland water quality. This paper describes the development and application of a process based model describing P transfer down a farm scale irrigation drain.     

Heavy metal inflow into the floodplains at the mouth of the river Weiße Elster (Central Germany)

From 1998 to 2002 investigations were carried out to estimate both the quantity and quality (heavy metal contents) of suspended matter loads discharged into a floodplain area measuring approx. 5 km² of the Central German river Weiße Elster, a tributary of the river Saale in the Elbe river basin. Flood sediments, suspended particulate matter, and floodplain soils were investigated especially for the main pollutants Cd, Zn, Cu, Pb, Cr, and Hg. Supplementary gamma spectroscopy examinations were performed to help to identify the age of deposits in order to estimate sedimentation rates for last decades. The recent flood sediments are contaminated by up to 33 times the geogenic background (Cd). Up to 55% of the total annual SPM load of the river Weiße Elster is relocated into the investigated retention area in the flood‐stricken year 2002. The sedimentation rates for the last 50 years vary between 0.5 mm/a and 1 mm/a in far away and rarely flooded parts and between 1 mm/a and 2 mm/a in the frequently flooded parts of the inflow of the retention area.