A Multiscale Assessment of Shallow Groundwater Salinization in Michigan

Managing nonpoint-source (NPS) pollution of groundwater systems is a significant challenge because of the heterogeneous nature of the subsurface, high costs of data collection, and the multitude of scales involved. In this study, we assessed a particularly complex NPS groundwater pollution problem in Michigan, namely, the salinization of shallow aquifer systems due to natural upwelling of deep brines. We applied a system-based approach to characterize, across multiple scales, the integrated groundwater quantity–quality dynamics associated with the brine upwelling process, assimilating a variety of modeling tools and data—including statewide water well datasets scarcely used for larger scientific analysis. Specifically, we combined (1) data-driven modeling of massive amounts of groundwater/geologic information across multiple spatial scales with (2) detailed analysis of groundwater salinity dynamics and process-based flow modeling at local scales. Statewide “hotspots” were delineated and county-level severity rankings were developed based on dissolved chloride (Cl⁻) concentration percentiles. Within local hotspots, the relative impact of upwelling was determined to be controlled by: (1) streams—which act as “natural pumps” that bring deeper (more mineralized) groundwater to the surface; (2) the occurrence of nearly impervious geologic material at the surface—which restricts fresh water dilution of deeper, saline groundwater; and (3) the space–time evolution of water well withdrawals—which induces slow migration of saline groundwater from its natural course. This multiscale, data-intensive approach significantly improved our understanding of the brine upwelling processes in Michigan, and has applicability elsewhere given the growing availability of statewide water well databases.     

Mechanisms of shrubland expansion: land use,climate or CO2?

Encroachment of trees and shrubs into grasslands and the thicketization of savannas has occurred worldwide over the past century. These changes in vegetation structure are potentially relevant to climatic change as they may be indicative of historical shifts in climate and as they may influence biophysical aspects of land surface-atmosphere interactions and alter carbon and nitrogen cycles. Traditional explanations offered to account for the historic displacement of grasses by woody plants in many arid and semi-arid ecosystems have centered around changes in climatic, livestock grazing and fire regimes. More recently, it has been suggested that the increase in atmospheric CO₂ since the industrial revolution has been the driving force. In this paper we evaluate the CO₂ enrichment hypotheses and argue that historic, positive correlations between woody plant expansion and atmospheric CO₂ are not cause and effect.Please direct all correspondence to the senior author.     

Distributions and removal fluxes of trace metals in the water column of the Hung-Tsai Trough off southwestern Taiwan

Vertical profiles of dissolved and particulate Mn, Fe, Ni, Cu, Zn, Cd, Pb, and (234)Th were determined in the Hung-Tsai Trough off southwestern Taiwan during 19-23 November, 2004. Except in the case of Cd, the distribution coefficient (K(d)) of the trace elements showed a negative correlation with the suspended particle concentration. Based on the average K(d) values, the general sequence of particle affinities for the eight trace elements is, from highest to lowest, Fe>Mn≈Pb>Zn≈Th>Cd≈Cu≈Ni. The trace metal data was coupled with the particle removal flux estimated from (234)Th/(238)U disequilibrium to investigate metal removal by particle sinking from the euphotic layer. The residence time of trace elements with respect to particle removal from the euphotic layer was estimated. A negative correlation between the residence time and the distribution coefficient for the trace metals was found.     

Effects of nonlinear model response on allocation of streamflow depletion: exemplified by the case of Beaver Creek,USA

Anomalies found when apportioning responsibility for streamflow depletion are examined. The anomalies arise when responsibility is assigned to the two states that contribute to depletion of Beaver Creek in the Republican River Basin in the United States. The apportioning procedure for this basin presumes that the sum of streamflow depletions, computed by comparing simulation model runs with and without groundwater pumping from individual states, approximates the streamflow depletion when both states are pumping. In the case study presented here, this presumed superposition fails dramatically. The stream drying and aquifer-storage depletion, as represented in the simulation model used for allocation, are examined in detail to understand the hydrologic and numerical basis for the severe nonlinear response. Users of apportioning procedures that rely on superposition should be aware of the presence and likely magnitude of nonlinear responses in modeling tools.     

Site fidelity and movements of gilthead sea bream (Sparus aurata) in a coastal lagoon (Ria Formosa, Portugal)

Short-time site fidelity and movements of gilthead sea bream (Sparus aurata) in a coastal lagoon were determined using passive acoustic telemetry. Nine fish, ranging from 20.1 to 32.5 cm total length, were surgically implanted with acoustic transmitters and monitored for up to 179 days. Minimum convex polygon areas ranged from 18,698.6 m² to 352,711.9 m². Home range sizes were small, with individuals using core areas on a daily basis. However, these core areas shifted within the study site over time towards the opening to the sea. Two different diel behaviors were recorded, with some individuals more active at night and others during day time. Some individuals also demonstrated homing abilities, returning to the capture site after being released more than 4 km away.     

Spherical harmonic analysis of steady photospheric flows

Steady photospheric flows can be represented by a spectrum of spherical harmonic modes. A technique is described in which full disc doppler velocity measurements are analysed using the spherical harmonic functions to determine the characteristics of this spectrum and the nature of these flows. Synthetic data is constructed for testing this technique. This data contains limb shift, rotation, differential rotation, meridional circulation, supergranules, giant cells and various levels of noise.The data is analysed in several steps. First, the limb shift is calculated by finding the average velocity in concentric rings about disc center. A polynomial representation of the limb shift is then removed from the data. Secondly, the rotation profile is calculated by finding an average slope in the velocity across the disc at each latitude position. This rotation profile is fit with Legendre polynomials and removed from the data. The third step is to find the meridional circulation by calculating the spherical harmonic transform for the axisymmetric poloidal modes and correcting for the effects of the limb shift analysis. The final step is to calculate the full spectrum of spherical harmonic components for the convective flows. Supergranules are separated from giant cells by spectral filtering for high (l >32) and low (l <32) wavenumbers, respectively.Some information about the spectrum is lost because only one hemisphere is seen, only the line-of-sight velocity is measured and the measurements contain noise. The lack of information about the motions on the backside of the Sun produces a broad smearing of the spectrum into nearby modes. The lack of information about the transverse velocity component produces a mixing between modes whose longitudinal wavenumbers differ by two and between the poloidal and toroidal components with the same wavenumber. In spite of this mode mixing much can be learned from this analysis. Solar rotation and differential rotation can be accurately measured and monitored for secular changes. Meridional circulations with small amplitudes can be measured and monitored and giant cells can be separated from supergranules.     

The Kaidun meteorite: Mineralogy of an unusual CM1 lithology

Abstract Kaidun is a breccia of disparate enstatite and carbonaceous chondrite clasts that continues to provide real surprises. Many Kaidun clasts have been intensely altered by aqueous fluids, as evidenced by the widespread occurrence of ferromagnesian phyllosilicates and by the presence of carbonate- and phyllo-silicate-filled veins. In this report, we describe an unusual CM lithology containing many mineralogical features not previously reported from any meteorite, including pyrrhotite, with exclusive needlelike morphologies and thick mantles of phyllosilicate, and complex aggregates of phyllosilicate, melanite garnet, crosscut by pentlandite veins. The latter features appear to be due in large part to extensive hydrothermal alteration at temperatures on the order of 450 °C, which is significantly higher than that attained during secondary processing from other known CM material.     

Developing coastal adaptation to climate change in the New York City infrastructure-shed: process, approach, tools, and strategies

While current rates of sea level rise and associated coastal flooding in the New York City region appear to be manageable by stakeholders responsible for communications, energy, transportation, and water infrastructure, projections for sea level rise and associated flooding in the future, especially those associated with rapid icemelt of the Greenland and West Antarctic Icesheets, may be outside the range of current capacity because extreme events might cause flooding beyond today??s planning and preparedness regimes. This paper describes the comprehensive process, approach, and tools for adaptation developed by the New York City Panel on Climate Change (NPCC) in conjunction with the region??s stakeholders who manage its critical infrastructure, much of which lies near the coast. It presents the adaptation framework and the sea-level rise and storm projections related to coastal risks developed through the stakeholder process. Climate change adaptation planning in New York City is characterized by a multi-jurisdictional stakeholder?Cscientist process, state-of-the-art scientific projections and mapping, and development of adaptation strategies based on a risk-management approach.     

Variability of organic δC and C/N in the Mersey Estuary, U.K. and its implications for sea-level reconstruction studies

Microfossil analysis (e.g. diatoms, foraminifera and pollen) represents the cornerstone of Holocene relative sea-level (RSL) reconstruction because their distribution in the contemporary inter-tidal zone is principally controlled by ground elevation within the tidal frame. A combination of poor microfossil preservation and a limited range in the sediment record may severely restrict the accuracy of resulting RSL reconstructions. Organic δ¹³C and C/N analysis of inter-tidal sediments have shown some potential as coastal palaeoenvironmental proxies. Here we assess their viability for reconstructing RSL change by examining patterns of organic δ¹³C and C/N values in a modern estuarine environment. δ¹³C and C/N analysis of bulk organic inter-tidal sediments and vegetation, as well as suspended and bedload organic sediments of the Mersey Estuary, U.K., demonstrate that the two main sources of organic carbon to surface saltmarsh sediments (terrestrial vegetation and tidal-derived particulate organic matter) have distinctive δ¹³C and C/N signatures. The resulting relationship between ground elevation within the tidal frame and surface sediment δ¹³C and C/N is unaffected by decompositional changes. The potential of this technique for RSL reconstruction is demonstrated by the analysis of part of an early Holocene sediment core from the Mersey Estuary. Organic δ¹³C and C/N analysis is less time consuming than microfossil analysis and is likely to provide continuous records of RSL change.     

Changes in the content and composition of pedogenic iron oxyhydroxides in a chronosequence of soils in southern California

Studies of the pedogenic iron oxyhydroxides in suites of latest Holocene to middle Pleistocene soils formed on fluvial deposits of the transverse ranges, southern California, indicate that the content and composition of iron oxyhydroxide change in a systematic manner. Analysis of total secondary free iron oxides (dithionite extractable, Fe₂O₃d) and ferrihydrite (oxalate extractable, Fe₂O₃o) shows that (1) a single-logarithmic model (Y = a + b log X) or double logarithmic model (log Y = a + b log X), where Y is the total mass of pedogenic Fe oxides (g/cm²-soil column) and X is soil age, describes the rate of increase in Fe₂O₃d with time; (2) the Fe₂O₃d content correlates linearly with soil reddening and clay content; (3) the $\text{Fe}{}_2\text{O}{}_3\text{o}\text{Fe}{}_2\text{O}{}_3\text{d}$ ratio, which indicates the degree of Fe oxide crystallinity, is moderately high to very high (0.22–0.58) in middle Holocene to latest Pleistocene soils and progressively decreases to less than 0.10 in older soils; (4) the value of the $\text{Fe}{}_2\text{O}{}_3\text{o}\text{Fe}{}_2\text{O}{}_3\text{d}$ ratio also appears to be infuenced by climate; and (5) temporal changes in Fe oxide content and mineralogy are accompanied by related, systematic changes in clay mineralogy and organic matter content. These relationships are attributed to a soil environment that must initially favor ferrihydrite precipitation and/or organic matter-Fe complexation. Subsequent transformation to hematite causes increasingly intense reddening and a concomitant decrease in the $\text{Fe}{}_2\text{O}{}_3\text{o}\text{Fe}{}_2\text{O}{}_3\text{d}$ ratio. The results demonstrate that iron oxide analysis is useful for numerical age studies of noncalcic soils and shows potential as an indicator of paleoclimates.