Next stop: the Moon

Andrew J Ball, Sarah K Dunkin and David J Heather report on optimistic and innovative ideas raised at the Fourth International Conference on Exploration and Utilisation of the Moon, which resulted in a declaration reviewing the current state of lunar exploration and setting targets for future work.     

Simulation of extensive air showers at ultra-high energy using the CORSIKA Monte Carlo code

Extensive simulations have been carried out with CORSIKA version 5.62 to investigate the general properties of giant cosmic air shower in the energy range 1–100 EeV. The comparison between protons, heavy nuclei and γ initiated showers exhibits unexpected and interesting features. The apparent muon electron ratio at great distances (1.5 km from axis) tends to be comparable at ultra-high energy in both photon-induced cascades and hadronic cascades (compensation between the enhancement versus energy of photo-production cross-section and of the decrease of both pair production cross-section and the bremsstrahlung cross-section, with Landau–Pomeranchuk–Migdal effect); for proton and nuclei primaries, a correlation with lateral electron profile suggests a new energy estimator, in complement to electrons size or density at 600 m, suitable for the determination of the total primary energy spectrum. Another tendency is the local contrast in the abundance of positive and negative muons (with a possible ellipticity in the lateral muon distribution) induced by the geomagnetic field, especially visible for some azimuthal and zenith angles. These distortions are more intense for heavy primaries; they can be exploited on the most favorable horizontal axis or areas, for the discrimination between nuclei and protons.     

Carbon isotopic fractionation between CO2 vapour,silicate and carbonate melts: an experimental study to 30 kbar

The carbon isotopic fractionation between CO₂ vapour and sodamelilite (NaCaAlSi₂O₇) melt over a range of pressures and temperatures has been investigated using solid-media piston-cylinder high pressure apparatus. Ag₂C₂O₄ was the source of CO₂ and experimental oxygen fugacity was buffered at hematite-magnetite by the double capsule technique. The abundance and isotopic composition of carbon dissolved in sodamelilite (SM) glass were determined by stepped heating and the ¹³C of coexisting vapour was determined directly by capsule piercing. CO₂ solubility in SM displays a complex behavior with temperature. At pressures up to 10 kbars CO₂ dissolves in SM to form carbonate ion complexes and the solubility data suggest slight negative temperature dependence. Above 20 kbars CO₂ reacts with SM to form immiscible Na-rich silicate and Ca-rich carbonate melts and CO₂ solubility in Na-enriched silicate melt rises with increasing temperature above the liquidus. Measured values for carbon isotopic fractionation between CO₂ vapour and carbonate ions dissoived in sodamelilite melt at 1200°–1400° C and 5–30 kbars average 2.4±0.2, favouring¹³C enrichment in CO₂ vapour. The results are maxima and are independent of pressure and temperature. Similar values of 2 are obtained for the carbon isotopic fractionation between CO₂ vapour and carbonate melts at 1300°–1400° C and 20–30 kbars.     

Cesstibtantite—a geologic introduction to the inverse pyrochlores

Summary The crystal structure of cesstibtantite has been solved from diffractometer data collected on samples from Leshaia, Russia and the Tanco pegmatite, Manitoba. Cesstibtantite from the Leshaia pegmatite (type locality) hasa 10.515(2) Å, space groupFd3m, composition Cs_0.31(Sb_0.57Na_0.31Pb_0.02Bi_0.01)_O.91(Ta_1.88Nb_0.12)₂(O_5.69[OH, F]_0.31)₆(OH, F)_0.69, Z 8; its structure was refined toR 3.8,wR 4.3% using 96 observed (F > 3[F]) reflections (MoK). Cesstibtantite from the Tanco pegmatite hasa 10.496(1) Å, space groupFd3m, composition (Cs_0.22K_0.01)_0.23(Na_0.45Sb_0.39Pb_0.14· Ca_0.06Bi_0.02)_1.06(Ta_1.95Nb_0.05)₂(O_5.78[OH,F]_0.22)₆(OH,F)_0.55,Z 8; its structure was refined toR 3.9w R 3.7% using 104 observed reflections. Cesstibtantite differs from the normal pyrochlores in that it contains significant amounts of very large cations such as Cs. As these cations are too large (^VIII[r] > 1.60 Å) for the conventional [8]-coordinated A site, they occupy the [18]-coordinated site, which normally contains monovalent anions. Natural cesstibtantite samples are non-ideal in that both Cs and monovalent anions occur at the site; thus cesstibtantite is intermediate to thenormal pyrochlores (with only monovalent anions at the site) and theinverse pyrochlores (with only large cations at the site).

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Cesstibtantit—eine geologische Einfiihrung in die inversen Pyrochlore

Zusammenfassung Die Kristallstruktur von Cesstibtantit wurde auf der Basis von Diffraktometerdaten von Proben von Leshaia, Russland and dem Tanco Pegmatit, Manitoba, gelöst. Cesstibtantit aus dem Leshaia Pegmatit (Typlokalität) hat a 10.515(2) Å, RaumgruppeFd3m, die Zusammensetzung CS_0.31(Sb_0.57Na_0.31Pb_0.02Bi_0.01)_0.91(Ta_1.88Nb_0.12)₂· (O_5.69OH, F_0.31)₆(OH, F)_0.69 Z 8; die Struktur wurde aufR 3.8,wR 4.3% verfeinert unter Benützung von 96 beobachteten Reflexen. Cesstibtantit vom Tanco Pegmatit hat a 10.496(1) Å, RaumgruppeFd3m, die Zusammensetzung (Cs_0.22K_0.01)_0.23(Na_0.45· Sb_0.39Pb_0.14Ca_0.06Bi_0.02)_1.06(Ta_1.95Nb_0.05)₂(O_5.78OH,F_0.22)₆(OH,F)_0.55,Z 8; seine Struktur wurde aufR 3.9wR 3.7% auf der Basis von 104 beobachteten Rettexen verfeinert. Cesstibtantit unterscheidet sich von normalen Pyrochloren insofern, als er signifikante Mengen von sehr großen Kationen, wie z.B. Cs enthält. Da these Kationen zu groß sind (^VIII r 1.60 Å) für eine konventionelle [8]-koordinierteA Stelle, nehmen she die [18]-koordinierten Positionen ein, welche normalerweise monovalente Anionen enthalten. Natürliche Cesstibtantitproben sind nicht ideal insofern als sowohl Cs als auch monovalente Anionen in der Position vorkommen. Somit ist Cesstibtantit intermediär zu den normalen Pyrochloren (mit nur monovalenten Anionen auf der Position) and den inversen Pyrochloren (mit ausschließlichen großen Kationen an der Position).

     

Effects of Hydrogel Amendment to Different Soils on Plant Available Water and Survival of Trees under Drought Conditions

The effect of super absorbent polyacrylate (SAP) hydrogel amendment to different soil types on plant available water (PAW), evapotranspiration and survival of Eucalyptus grandis, Eucalyptus citriodora, Pinus caribaea, Araucaria cunninghamii, Melia volkensii, Grevillea robusta, Azadirachta indica, Maesopsis eminii and Terminalia superba was investigated. The seedlings were potted in 3 kg size polythene bags filled with sand, loam, silt loam, sandy loam and clay soils, amended at 0 (control), 0.2 and 0.4% w/w hydrogel. The tree seedlings were allowed to grow normally with routine uniform watering in a glass house set up for a period of eight weeks, after which they were subjected to drought conditions by not watering any further. The 0.4% hydrogel amendment significantly (p < 0.05) increased the PAW by a factor of about three in sand, two fold in silt loam and one fold in sandy loam, loam and clay soils compared to the control. Similarly, the addition of either 0.2 or 0.4% hydrogel to the five soil types resulted in prolonged tree survival compared to the controls. Araucaria cunninghammi survived longest at 153 days, while Maesopsis eminii survived least (95 days) in sand amended at 0.4% after subjection to desiccation. Evapotranspiration was reduced in eight of the nine tree species grown in sandy loam, loam, silt loam and clay soils amended at 0.4% hydrogel. It is probable that soil amendment with SAP decreased the hydraulic soil conductivity that might reduce plant transpiration and soil evaporation.     

Hamilton Harbour, Ontario: 8300 years of limnological and environmental change inferred from microfossil and isotopic analyses

Limnological changes in Hamilton Harbour, Lake Ontario, over the Holocene were investigated by using proxy evidence from diatoms and other siliceous microfossils in a radiometrically dated sediment core (HH26comp), together with environmental data derived from sediment pollen and oxygen and carbon isotope analyses. The evidence demonstrates that the site of Hamilton Harbour has changed over the past 8300 y from a shallow, separate waterbody, to a deep embayment of Lake Ontario. The earliest evidence, from 8300 BP to 7000 BP, is of a mesotrophic pond of moderate alkalinity, warmer than present, and probably with an extensive marginal wetland. An initial transitory connection with the rising water level of Lake Ontario was established at c. 7000 BP, possibly via a deep outlet channel. This connection is 2000 y earlier then previously estimated. Permanent confluence with Lake Ontario was established at c. 6200 BP, causing a decline in inferred trophic level and water temperatures. Microfossils reach a minimum at 4400 BP coincident with the Nipissing Flood. Decreased mixing of Lake Ontario water from about 4000 BP following the Nipissing Flood highstand is evidenced in isotopic and diatom data. Three isolated shifts in the diatom spectrum at c. 4900 BP, 4500 BP, and 3500 BP may be associated with extreme turbidity or storm deposit events. Between 3200 BP and 280 BP, Hamilton Harbour was evidently a moderately alkaline embayment of Lake Ontario, oligotrophic to mesotrophic, and relatively cooler than present. The final 280 y sedimentary record reveals the magnitude of anthropogenically induced changes to the harbour, including eutrophication and organic pollution.