Metal binding to dissolved organic matter and adsorption to ferrihydrite in shallow peat groundwaters: Application to diamond exploration in the James Bay Lowlands,Canada

The speciation and solubility of kimberlite pathfinder metals (Ni, Nd, Ba and K) in shallow peat groundwaters is investigated over the Yankee, Zulu and Golf kimberlites in the Attawapiskat region, James Bay Lowlands, Canada. The purpose of this study is to examine the relationship between dissolved organic matter (DOM) complexation with kimberlite pathfinder metals and determine the spatial distribution of those metals in shallow peat groundwaters along sampling transects over subcropping kimberlites. Nickel, Nd, Ba and K complexation with DOM and the adsorption of these metals onto ferrihydrite were calculated using Visual MINTEQ 3.0 and the NICA-Donnan database. Calculations predict almost 100% of soluble Nd, Ni and Ba form complexes with DOM at sampling sites with little to no contribution from upwelling groundwater (i.e., dissolved organic C (DOC) concentrations = 40–132 mg/L, pH = 3.9–5.5, and log ionic strength ??3). In only the most ombrotrophic peat groundwater conditions does a majority fraction of K bind to DOM. By contrast, under conditions with large contributions from upwelling groundwaters (i.e., DOC concentrations ?40 mg/L, pH = 5.5–6.5, and log ionic strength = ?3 to ?2), as little as 10% of Nd and Ni, and 0% K and Ba are predicted to complex with DOM. The modeling calculations suggest the dominant control on metal–DOM complexation, particularly with respect to Ni and Nd, is competitive effects for DOM binding sites due to elevated ionic strength where there is evidence of strong groundwater upwelling. Visual MINTEQ modeling of metal adsorption on ferrihydrite surfaces predicts that under strong upwelling conditions, Ni and Nd are scavenged from solution due to increased ferrihydrite precipitation and decreased fractions of metals complexed with DOM. Analytical geochemical data are consistent with model predictions of metal adsorption on ferrihydrite. Total dissolved Ni and Nd concentrations at sites of strong upwelling are up to five times lower than waters with little to no upwelling and log ferrihydrite saturation indices (logSI_ferr) indicate precipitation (values up to 5) at sites of strong groundwater upwelling. Where the majority of Ni and Nd complex with DOM and ferrihydrite is highly under saturated (logSI_ferr = ?18 to ?5), the concentrations of total Ni and Nd are elevated compared to other sites along sampling transects. Metal complexation with DOM effectively inhibits metal scavenging from solution via adsorption and/or from forming secondary mineral precipitates. Also, because alkaline earth metals do not compete strongly with Ni and Nd for adsorption sites on ferrihydrite surfaces, but do compete strongly for insoluble organic sites, Ni and Nd are more likely to adsorb onto ferrihydrite.     

Normal modes of the viscoelastic earth

Summary A uniformly valid linear viscoelastic rheology is described which takes the form of a 'generalized' Burgers' body and which appears capable of reconciling the behaviour of the Earth's mantle across the complete spectrum of geodynamic time-scales. This spectrum is bracketed by the short time-scales of body wave and free oscillation seismology on which anelastic effects are dominant, and the long time-scale of mantle convection on which the Earth behaves viscously. The parameters of the model which control the viscous response are fixed by post-glacial rebound data whereas those which govern the anelasticity are to be determined by fitting the model to observations of seismic Q. The paper is concerned primarily with a discussion of the normal mode spectrum of the Earth as a generalized Burgers' body. Focusing upon the homogeneous model, it includes an initial analysis of the accuracy of first-order perturbation theory as a method of calculating the respective Q s of the elastic gravitational free oscillations. Also considered are the quasi-static modes of relaxation which only exact eigenanalysis can reveal. The importance of these modes is assessed within the context of a discussion of the effect of viscoelasticity upon the efficiency of Chandler wobble excitation.     

Sequence stratigraphy of the Dakota Formation (Cenomanian), southern Utah: interplay of eustasy and tectonics in a foreland basin

The Dakota Formation in southern Utah (Kaiparowits Plateau region) is a succession of fluvial through shallow-marine facies formed during the initial phase of filling of the Cretaceous foreland basin of the Sevier orogen. It records a number of relative sea-level fluctuations of different frequency and magnitude, controlled by both tectonic and eustatic processes during the Early to Late Cenomanian. The Dakota Formation is divided into eight units separated by regionally correlatable surfaces that formed in response to relative sea-level fluctuations. Units 1–6B represent, from bottom to top, valley-filling deposits of braided streams (unit 1), alluvial plain with anastomosed to meandering streams (2), tide-influenced fluvial and tide-dominated estuarine systems (3A and 3B), offshore to wave-dominated shoreface (4, 5 and 6A) and an estuarine incised valley fill (6A and 6B). The onset of flexural subsidence and deposition in the foredeep was preceded by eastward tilting of the basement strata, probably caused by forebulge migration during the Early Cretaceous, which resulted in the incision of a westward-deepening predepositional relief. The basal fluvial deposits of the Dakota Formation, filling the relief, reflect the onset of flexural subsidence and, possibly, a eustatic sea-level rise. Throughout the deposition of the Dakota Formation, flexure controlled the long-term, regional subsidence rate. Locally, reactivation of basement faults caused additional subsidence or minor uplift. Owing to a generally low subsidence rate, differential compaction locally influenced the degree of preservation of the Dakota units. Eustasy is believed to have been the main control on the high-frequency relative sea-level changes recorded in the Dakota. All surfaces that separate individual Dakota units are flooding surfaces, most of which are superimposed on sequence boundaries. Therefore, with the exception of unit 6B and, possibly, 3B, most of the Dakota units are interpreted as depositional sequences. Fluvial strata of units 1 and 2 are interpreted as low-frequency sequences; the coal zones at the base and within unit 2 may represent a response to higher frequency flooding events. Units 3A to 6B are interpreted as having formed in response to high-frequency relative sea-level fluctuations. Shallow-marine units 4, 5 and 6A, interpreted as parasequences by earlier authors, can be divided into facies-based systems tracts and show signs of subaerial exposure at their boundaries, which allows interpretation as high-frequency sequences. In general, the Dakota units are good examples of high-frequency sequences that can be misinterpreted as parasequences, especially in distal facies or in places where signs of subaerial erosion are missing or have been removed by subsequent transgressive erosion. Both low- and high-frequency sequences represented by the Dakota units are stacked in an overall retrogradational pattern, which reflects a long-term relative sea-level rise, punctuated by brief periods of relative sea-level fall. There is a relatively major fall near the end of the M. mosbyense Zone, whereas the base of the Tropic shale is characterized by a major flooding event at the base of the S. gracile Zone. A similar record of Cenomanian relative sea-level change in other regions, e.g. Europe or northern Africa, suggests that both high- and low-frequency relative sea-level changes were governed by eustasy. The high-frequency relative sea-level fluctuations of ≈100 kyr periodicity and ≈10–20 m magnitude, similar to those recorded in other Cenomanian successions in North America and Central Europe, were probably related to Milankovitch-band, climate-driven eustasy. Either minor glacioeustatic fluctuations, superimposed on the overall greenhouse climate of the mid-Cretaceous, or mechanisms, such as the fluctuations in groundwater volume on continents or thermal expansion and contraction of sea water, could have controlled the high-frequency eustatic fluctuations.     

The petroleum evaluation of a tectonically complex area: The western margin of the Southeast Basin (France)

The Southeast Basin of France is the thickest onshore French sedimentary basin which contains locally as much as 10 km of Mesozoic-Cenozoic sediment. Basin development occurred in several stages between late Carboniferous and late Cretaceous times. Partial tectonic inversion took place during two compressive events, the so-called ‘Pyrenean’ and ‘Alpine’ phases of late Cretaceous-early Tertiary and late Tertiary ages respectively. They are separated by an intervening stretching event of Oligocene age, which further south resulted in the opening of the western Mediterranean oceanic basin. As a result of this complex tectonic history, structural traps were difficult to image on the seismic data shot during the first phase of exploration prior to 1980. Oil and gas natural seeps, and shows in several wells, indicate that some petroleum systems are, or have been active, at least in some places.The present erosional western margin of the basin is more or less superimposed on the initial Triassic-Jurassic margin. Margin subsidence and Tertiary inversion are discussed using regional sections on which the polyphase history of the entire basin is well shown. These sections are located on three major segments where the Mesozoic margin is either partly preserved (Ardèche), or has been partly inverted in late Tertiary times (Vercors-Chartreuse), or has been completely inverted in early Tertiary times (Corbières-eastern Pyrenees). 1-D ‘Genex’ basin modelling on the Ardèche segment, and 2-D ‘Thrustpack’ structural-maturity modelling in the Vercors-Chartreuse segment are used to further assess the remaining petroleum plays.     

The almost constant-speed two-body problem with resistance

The almost constant-speed motion of a mass acted upon by a Newtonian attraction and a resisting force is treated. The equation of orbit is derived for a specific type of resistance which covers the familiar case of Danby's drag(=r ^–2) whilst the vector invariants are obtained by direct operation on the vector form of the equation of motion.     

Optimizing interpolation of shoot density data from a Posidonia oceanica seagrass bed

A case study on the optimization of Posidonia oceanica density interpolation, using a data set from a large meadow at Porto Conte Bay (NW Sardinia, Italy), is presented. Ordinary point kriging, cokriging and a weighted average based on inverse square distance were used to interpolate density data measured in 36 sampling stations. The results obtained from different methods were then compared by means of a leave‐one‐out cross‐validation procedure. The scale at which interpolation was carried out was defined on the basis of the Hausdorff dimension of the variogram. Optimizing spatial scale and data points search strategy allowed obtaining more accurate density estimates independently of the interpolation method.     

Pulsar reflections within the Crab Nebula

Between 1997 August and October, the radio pulses from the Crab pulsar were followed by discrete moving echoes, which appear to be reflections from part of an ionized shell in the outer part of the Crab Nebula, crossing the line of sight to pulsar. Similar events have now been recognized in recordings from the past 30 yr, and it seems that the Nebula must contain a large number of ionized shell-like surfaces on a much finer scale than recognized hitherto.     

2009年意大利中部阿奎拉地震DInSAR同震位移的有限断层反演

根据环境卫星Envisat和COSMO—SkyMed模型（为同震位错研究而首次设计的X波段反演干涉图）的DInSAR干涉图,确定了2009年4月6日阿奎拉Mw=6．3级地震时激发的断层几何形状及运动特征。我们的主震最佳拟合解为一个约16km长、12km宽的正断层,存在小的右旋分量,向西南倾斜47°,最大滑动约90cm。虽然地震位错可能只有1km深,但是断层面的上倾投影与标绘的帕加尼卡-南德米特里奥断层的北段相符合,在现场观察到了该断层地表破裂的迹线。该断层在现有震源目录中的缺失表明,需要对具体的地表和地下进行进一步的地质和地球物理勘测,以便对局部规模的地震危险性做出更准确的评估。     

A Preliminary Analysis of Disturbance Tracksover the Mediterranean Basin

Summary  The Mediterranean basin experiences considerable cyclone activity mostly during fall, winter and spring and diminished activity during summer. In this study we present results of synoptic disturbance track analysis for two contrasting winter months and two, near average, summer months over the eastern Mediterranean. The surface and 500 hPa disturbance tracks were subjectively analyzed from two points of view. First, looking at tracks of conventionally defined cyclone centers (eddies) based on actual pressure and height distribution and second, looking at tracks of transient cyclonic disturbances (TRADs), defined as centers of negative deviations from the time mean. The second type of analysis demonstrated a considerable increase in the number of detectable tracks. Over the Mediterranean and vicinity the ratio between the number of surface TRAD tracks to cyclone tracks is, about 2, whereas at 500 hPa the ratio is much higher, about 5. However, the average life span of transient disturbances was only slightly longer than that of conventional cyclones (mainly at 500 hPa). At the surface and at 500 hPa about 50% of the cyclone tracks coincided to a certain extent with TRAD tracks. In summer, when conventional analysis over the eastern Mediterranean yields mostly quasi‐stationary low pressure centers associated with the Persian Gulf Trough, we detected clear signs of transient disturbances. Some interpretations of the differences between cyclones and TRADs in terms of weather in the eastern Mediterranean are also made. Received January 19, 1999Revised June 23, 1999     

Geodynamic setting,structure, and composition of continuous trachybasalt-trachyandesite-rhyolite series in the north of Altai-Sayan area: the role of crust-mantle interaction in continental magma formation

The geologic positions and geochemical and isotope parameters of the Ordovician-early Silurian and Early-Middle Devonian continuous volcanic series of the Minusa basin and its mountainous framing are compared. Both series are composed mostly of moderately alkaline rocks with variations in SiO₂ contents from 45 to 77 wt.%. The Ordovician-early Silurian series differs from the Early-Middle Devonian one in lower contents of TiO₂ (< 1.7 wt.%) and Fe₂O_3tot and higher contents of Al₂O₃ in all rock varieties and in the more fractionated REE patterns of trachybasalts. The compositions of both series reflect two simultaneous mechanisms of magma evolution. The main process was fractional crystallization leading to the formation of rocks from trachybasalts to trachyrhyodacites. The accessory mechanism was the contamination of fractionated melts by crustal material, anatectic melting of crust, and mixing of deep-seated magmas with crustal melts. These processes had specifics at each stage and were controlled by the composition of the sources of parental melts. Their geochemical and isotopic parameters (high alkalinity, high contents of lithophile elements, negative anomalies of Nb, Ta, and Ti, and enrichment in radiogenic Sr) point to the interaction of mantle plumes with the lithospheric mantle that was metasomatically transformed during the preceding Vendian-early Cambrian subduction processes.