The Development of Laser Ablation ICP-MS and Calibration Strategies: Examples from the Analysis of Trace Elements in Volcanic Glass Shards and Sulfide Minerals

This contribution presents a review of the recent developments in laser ablation inductively coupled plasma-mass spectrometry. We describe the important developments which have occurred in the laser systems used, leading to a spatial resolution of around 20 (im, and give an overview of the major instrument developments which have affected the geological applications of laser ablation ICP-MS. We describe the calibration of laser ablation for the analysis of trace elements in two different matrices: volcanic glass shards and sulfide minerals. We show how single glass shards can be analysed using the National Institute of Standards and Technology (NIST) glass certified reference materials for calibration and demonstrate the effect of using single spot analyses compared to rastering of the calibration sample. We show the importance of inter-shard variation and demonstrate that averaged single shard analyses produce data which compare well with bulk analyses. The calibration of the laser system for sulfide mineral analysis is discussed and two different strategies are proposed, one using spiked pressed powder pellets of sulfides and the other metal reference materials. We present conclusions and recommendations for the calibration of laser ablation ICP-MS instruments.     

Potassium‐argon dates from the Arltunga Nappe complex,northern territory

Twenty‐four mineral separates from the Arunta Complex, four from the metamorphosed Heavitree Quartzite (White Range Quartzite), and one whole rock sample of metamorphosed Bitter Springs Formation, all from the western part of the White Range Nappe of the Arltunga Nappe Complex, and two samples from the autochthonous basement west of the nappe have been dated by the K‐Ar method. The samples from the basement rocks form two groups. Those in the southern or frontal part of the nappe are of Middle Proterozoic (Carpentarian) age (1660–1368 m.y.), determined on hornblende, biotite, and muscovite. In the northern or rear part of the nappe, all but one of the muscovite samples and two biotites are of Middle Silurian to Early Carboniferous age (431–345 m.y.); the remainder of the biotite dates range from 1775 to 548 m.y. (including the two samples from the autochthon), and two hornblendes gave dates of 1639 and 2132 m.y. respectively. All the muscovite samples from the Heavitree Quartzite, and the whole rock sample from the Bitter Springs Formation gave Early to Middle Carboniferous dates (358–322 m.y.). The findings support the identification of the White Range Quartzite as the metamorphosed part of the Heavitree Quartzite, which in turn supports the interpretation of the structure of the area as a large, basement‐cored fold nappe. In addition, they date the time of the Alice Springs Orogeny as pre‐Late Carboniferous, which agrees with fossil evidence from elsewhere in the area. The Alice Springs Orogeny was accompanied by widespread greenschist facies meta‐morphism that progressively metamorphosed the Heavitree Quartzite and Bitter Springs Formation, and retrogressively metamorphosed the Arunta Complex. However, the basement rocks in the southern part of the nappe escaped this metamorphism and retain a Middle Proterozoic age, thus dating the time of the Arunta Orogeny in this region as Carpentarian or older.     

An answer to an important controversy and the need for caution when using simple models to predict inelastic earthquake response of buildings with torsion

This paper presents evidence that the extension of conclusions based on the widely used simplified, one story, eccentric systems of the shear‐beam type, to actual, nonsymmetric buildings and consequent assessments of the pertinent code provisions, can be quite erroneous, unless special care is taken to match the basic properties of the simplified models to those of the real buildings. The evidence comes from comparisons of results obtained using three variants of simplified models, with results from the inelastic dynamic response of three‐ and five‐story eccentric buildings computed with detailed MDOF systems, where the members are idealized with the well‐known plastic hinge model. In addition, a convincing answer is provided on a pertinent hanging controversy: For frame‐type buildings, designed in accordance with the dynamic provisions of modern codes (such as EC8 or IBC2000), which allow reduced shears at the stiff edge due to torsion, the frames at the flexible sides are the critical elements in terms of ductility demands. Copyright © 2009 John Wiley & Sons, Ltd.     

Comparison of Brewer spectrophotometer ultraviolet data from similar latitudes in the Northern and Southern Hemisphere

This paper presents UV data recorded over 12 months in 2000/2001 at a southern hemisphere (Toowoomba) and similar latitude northern hemisphere (BigBend and Everglades) sites using Brewer Spectrophotometers. The peak daily erythemally weighted UV (DUV) at the Toowoomba site was 8.8% and 25% higher compared to that at the BigBend and Everglades sites, respectively. The Everglades site exposures are lower than the BigBend site exposures in summer and spring. This may be due to the higher cloud cover for the Everglades site. The summer DUV values between Toowoomba and BigBend are similar. In spring, the average DUV value is the greatest at BigBend compared to the other two sites. Results indicate that variability between the measurement sites is due to varying cloud and ozone, and possibly due to aerosol and airmass differences of each region. Of these different site-specific local atmospheric conditions, cloud was the main contributor to the differences in UV between the sites.     

A noble record

Alexander B Verchovsky and Mark A Sephton review the origins and significance of noble gases in meteorites, focusing on what this unique record reveals about the early solar system.     

Spatially explicit measures of production of young alewives in Lake Michigan: Linkage between essential fish habitat and recruitment

The identification and protection of essential habitats for early life stages of fishes are necessary to sustain fish stocks. Essential fish habitat for early life stages may be defined as areas where fish densities, growth, survival, or production rates are relatively high. To identify critical habitats for young-of-year (YOY) alewives (Alosa pseud oharengus) in Lake Michigan, we integrated bioenergetics models with GIS (Geographic Information Systems) to generate spatially explicit estimates of potential population production (an index of habitat quality). These estimates were based upon YOY alewife bioenergetic growth rate potential and their salmonine predators’ consumptive demand. We compared estimates of potential population production to YOY alewife yield (an index of habitat importance). Our analysis suggested that during 1994–1995, YOY alewife habitat quality and yield varied widely throughout Lake Michigan. Spatial patterns of alewife yield were not significantly correlated to habitat quality. Various mechanisms (e.g., predator migrations, lake circulation patterns, alternative strategies) may preclude YOY alewives from concentrating in areas of high habitat quality in Lake Michigan.     

Petrogeochemical aspects of the Late Cretaceous and Paleogene ignimbrite volcanism of East Sikhote-Alin

The chemical and trace-element features of the Late Cretaceous and Early Paleogene ignimbrite complexes of East Sikhote Alin are discussed. The Turonian-Campanian volcanic rocks of the Primorsky Complex compose linear structure of the Eastern Sikhote Alin volcanic belt. They are represented by crystalrich rhyolitic, rhyodacitic, and dacitic S-type plateau ignimbrites produced by fissure eruptions of acid magmas. The Maastrichtian-Paleocene volcanic rocks occur as isolated volcanic depression and caldera structures, which have no structural and spatial relations with the volcanic belt. This period is characterized by bimodal volcanism. The Samarginsky, Dorofeevsky, and Severyansky volcanic complexes are made up of basalt-andesite-dacite lavas and pyroclastic rocks, while the Levosobolevsky and Siyanovsky complexes are comprised of rhyolitic and dacitic tuffs and ignimbrites. Petrogeochemically, the felsic volcanic rocks are close to the S-type plateau ignimbrites of the Primorsky Complex. The Paleocene-Early Eocene silicic volcanics of the Bogopolsky Complex are represented by S- and A-type dacitic and rhyolitic tuffs and ignimbrites filling collapsed calderas. The eruption of A-type ferroan hyaloignimbrites occurred at the final stage of the Paleogene volcanism (Bogopolsky Complex). The magmatic rocks show well expressed mineralogical and geochemical evidence for the interaction between the crustal magmas and enriched sublithospheric mantle. It was shown that the revealed differences in the mineralogical and geochemical composition of the ignimbrite complexes are indicative of a change in the geodynamic regime of the Asian active continental margin at the Mesozoic-Cenozoic transition.     

Photogrammetric Capabilities of the Kodak DC40, DCS420 and DCS460 Digital Cameras

The aim of this study is to assess the impact of sensor size and resolution of different digital camera sensors upon the accuracy and precision of three dimensional data derived by photogrammetry. Kodak DC40, DCS420 and DCS460 digital cameras were used to produce digital images of retroreflective targets in a 4 m three dimensional test field. The image locations of the targeted points were automatically measured using an off the shelf image processing software package. Two different sub-pixel measurement approaches were examined: centre of gravity and weighted mean. From the automated sub-pixel measurement of the targeted points, results indicate that the high resolution DCS460 camera produces optimum results using either the weighted mean or centre of gravity approaches. Although this was perhaps expected, the far lower resolution DC40 camera performed better than was originally anticipated, suggesting potential for the cheaper DC40 for many applications.     

WORLD ATLAS OF THEMATIC MAPS OF DESERTIFICATION

The author describes the contents and participation of former Soviet republics in the compilation of a global atlas of desertification, published under the auspices of the United Nations. Translated by H. L. Haslett, Leamington Spa, UK, from: Izvestiya Akademii Nauk SSSR, seriya geograficheskaya, 1991, No. 6, p. 130.