Toxic chemicals in Canadian fish-eating birds

Cross-country comparison of DDE and PCB residue levels in cormorant, gull and tern eggs in Canada reveal that bird populations at the Great Lakes are most contaminated with those pollutants. DDE levels have been correlated with reproductive failure in Double-crested Cormorants in the Great Lakes with eggshell thinning as a major factor. Low reproductive success in Herring Gull colonies at Lake Ontario is associated with high chlorinated hydrocarbon levels in eggs. Fish-eating birds in the Wabigoon River system, northwestern Ontario, are among the most known mercury contaminated birds. It is suggested that the effects of mercury on the reproduction of fish-eating birds should be further examined there.Fish-eating birds occupy the highest levels of the food web and magnification of toxic chemicals through prey organisms in this web makes those birds vulnerable to the effects of environmental contaminants. Since fish-eating birds are present everywhere in Canada's freshwater and marine habitats and occupy various niches there, they may serve as pollution indicators in various food chains of our aquatic environment. Colonial birds are especially valuable indicators as pollution effects on total bird populations can be studied. Baseline information on fish-eating bird populations should now be collected everywhere in Canada for measuring present and future effects of environmental pollutants, as well as other man-made disturbances on their populations.     

Flow behind an attached shock wave in a radiating gas

A simple method is used to determine the curvature of an attached shock wave and the flow variable gradients behind the shock curve at the tip of a straight-edged wedge placed symmetrically in a supersonic flow of a radiating gas near the optically thin limit. The shock curvature and the flow variable gradients along the wedge at the tip are computed for a wide range of upstream flow Mach numbers and wedge angles. Several interesting results are noted; in particular, it is found that the effect of an increase in the upstream flow Mach number or the radiative flux is to enhance the shock wave curvature which, however, decreases with an increase in the specific heat ratio or the wedge angle.     

An Upper Limit on Sunspot Activity During the Maunder Minimum

We have estimated the upper and lower limits of sunspot activity, in terms of active day fraction during the Maunder minimum (1645–1710), using raw information on individual daily observations (Hoyt and Schatten, 1998). Establishing the relation between the sunspot activity and active day fraction after 1850, we evaluate the upper limit of annual group sunspot number during the deep Maunder minimum (1645–1700) which does not exceed 4. The earlier finding of a dominant 22-year periodicity during the Maunder minimum is verified and shown to be robust. Also we confirm that the start of the Maunder minimum was very abrupt.     

Phase transformations of enstatite in spherical shock waves

The analysis of available theoretical evaluations and experimental data reveals discrepancies and makes it possible to formulate the goals for the comprehensive study of the behavior of enstatite MgSiO₃ in shock isentropic waves of various scale and intensity. The paper presents the layout and results of an explosion experiment on the compression of an enstatite sphere with spherical shock waves and the subsequent recovery of the experimental material and its examination in discrete zones (along the sphere radius) that were produced by shock waves in the material. The latter were examined with the application of scanning electron microscopy, Raman spectroscopy, and X-ray diffraction analysis. The comparison of the systematic variations in the texture, chemistry, and phase composition of enstatite along the sphere radius with calculated pressure P(R, t) and temperature T(R, t) values led us to the following conclusions: enstatite starts melting on an isentrope upon pressure relief after shock wave compression at ?? _xx ?? 80 GPa and melts on the front of the spherically converging shock wave at ?? _xx ?? 160 GPa and T ?? 6300 K. Our laboratory experiments with shock waves were the world??s first in which enstatite was loaded with spherical converging shock isentropic waves and which provided evidence that shock wave-loaded MgSiO₃ shows certain morphological and mineralogical features never before detected in this mineral loaded with plane shock wave of smaller amplitude and duration. Goals are formulated for the further studying of shock wave-loaded materials, and the necessity is discussed for conducting an explosion experiment with a five to seven times greater spherical system in order to increase the duration of the shock wave loading impulse.     

Search for spatial variation in the jovian N/N ratio from Cassini/CIRS observations

We have used the spectra obtained by the Composite Infrared Spectrometer (CIRS) onboard the Cassini spacecraft to search for latitudinal variation in the ¹⁵N/¹⁴N ratio on Jupiter. We found no variations statistically significant given the observational and model uncertainties. The absence of latitudinal variations demonstrates that ¹⁵NH₃ is not fractionated in Jupiter's atmosphere, and that the measured ¹⁵N/¹⁴N represents Jupiter's global value. Our mean value for the global jovian ¹⁵N/¹⁴N ratio of (2.22±0.52)×10⁻³ agrees with previous measurements made by Fouchet et al. (2000, Icarus 143, 223-243) and Owen et al. (2001, Astrophys. J. 553, L77-L79). We argue that the jovian isotopic ¹⁵N/¹⁴N ratio must represent the solar nitrogen isotopic composition. The solar ¹⁵N/¹⁴N ratio hence significantly differs from the terrestrial value: (¹⁵N/¹⁴N)_⊕=3.68×10⁻³. This supports the proposition that terrestrial nitrogen originates from a nitrogen reservoir isolated from the main nitrogen reservoir in the proto-solar nebula. The origin and carrier of this isolated reservoir are still unknown.     

Hydrodynamical simulations of Galactic fountains – I. Evolution of single fountains

The ejection of the gas out of the disc in late-type galaxies is related to star formation and is due mainly to Type II supernovae. In this paper, we studied in detail the development of the Galactic fountains in order to understand their dynamical evolution and their influence on the redistribution of the freshly delivered metals over the disc. To this aim, we performed a number of 3D hydrodynamical radiative cooling simulations of the gas in the Milky Way where the whole Galaxy structure, the Galactic differential rotation and the supernova explosions generated by a single OB association are considered. A typical fountain powered by 100 Type II supernovae may eject material up to ∼2 kpc which than collapses back mostly in the form of dense, cold clouds and filaments. The majority of the gas lifted up by the fountains falls back on the disc remaining within a radial distance  Δ R = 0.5 kpc  from the place where the fountain originated. This localized circulation of disc gas does not influence the radial chemical gradients on large scale, as required by the chemical models of the Milky Way which reproduce the metallicity distribution without invoking large fluxes of metals. Simulations of multiple fountains fuelled by Type II supernovae of different OB associations will be presented in a companion paper.     

Measuring proton energies and fluxes using EIT (SOHO) CCD areas outside the solar disk images

An indirect proton flux measuring tool based on discrimination of the energy deposited by protons in 128 × 128 pixel EIT CCD areas outside the solar disk images is presented. Single pixel intensity events are converted into proton incident energy flux using modeled energy deposition curves for angles of incidence ±60° in four EIT spatial areas with different proton stopping power. The extracted proton flux is corrected for both the loss of one‐pixel events in the range of angles of incidence as well as for the contribution to the single pixel events resulting from scattered middle‐energy protons (low‐energy or high‐energy particles are stopped by the EIT components or pass through them, accordingly). A simple geometrical approach was found and applied to correct for a non‐unique relation between the proton‐associated CCD output signal and the incident proton energy. With this geometrical approximation four unique proton incident energy ranges were determined as 45–49, 145–154, 297–335, and 390–440 MeV. The indirect proton flux measuring tool has been tested by comparing Solar Energetic Particles (SEP) flux temporal profiles extracted from the EIT CCD frames and downloaded from the GOES database for the Bastille Day (BD) of 2000 July 14 and the more recent 2005 January 20 events. The SEP flux temporal profiles and proton spectra extracted from the EIT in the relatively narrow energy ranges between 45 and 440 MeV reported here are consistent with the related GOES profiles. The four additional EIT extracted ranges provide higher energy resolution of the SEP data. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Geological maps from the British Antarctic Survey

In a bold move the British Antarctic Survey has published the naturally fragmentary results of their ongoing geological mapping and research programme in the Antarctic Peninsula and offshore islands, plus South Georgia. The later is classified as a United Kingdom overseas territory, along with the volcanically active South Sandwich Islands just north of 60 degrees south. Beyond this latitude to the South Pole all territorial claims have been frozen by the Antarctic treaty, which built upon the International Geophysical Year of 1957 and came into force in 1961. Since then this monumental achievement, developed during the height of the cold war, has succeeded in keeping Antarctica demilitarized, including banning the disposal of nuclear waste, and untainted by mineral exploration. In 1998 this treaty was renewed for a further fifty years and extended to cover the impact of tourism. Although geological research had been conducted since the pioneering days of Shackleton, Scott and Amundsen, the original 1908 territorial claim was backed up by a continuing presence since 1943, and the Falklands Islands Dependencies Survey was renamed the British Antarctic Survey in 1962 to chime with the spirit of purely scientific research entailed by this treaty which has now expanded to a membership of nearly fifty nations.     

Comparison of cell- and vertex-centered discretization methods for flow in a two-dimensional discrete-fracture–matrix system

Simulations of flow for a discrete-fracture model in fractured porous rocks have gradually become more practical, as a consequence of increased computer power and improved simulation and characterization techniques. Discrete-fracture models can be formulated in a lower-dimensional framework, where the fractures are modeled in a lower dimension than the matrix, or in an equi-dimensional form, where the fractures and the matrix have the same dimension.