An EPR study of native radiation-induced paramagnetic defects in sudoite (di–trioctahedral Al–Mg chlorite) from the alteration halo related to unconformity-type uranium deposits

Natural radiation-induced defects were identified in specimens of sudoite (Al–Mg di-trioctahedral chlorite) related to unconformity-type uranium deposits at the base of the Athabasca Group (Saskatchewan, Canada), using electron paramagnetic resonance (EPR) spectroscopy at X- and Q-band frequencies. X-band spectra indicate the presence of a main native defect, named the A_s-center, whose EPR signal is dominated by an axially distorted spectrum with apparent principal components as follows: g _// = 2,051 and g _⊥ = 2,005, and a secondary defect with apparent component g = 2,025. The study of oriented specimens shows that the main defect has its g _// component perpendicular to the (ab) plane of sudoite. The A_s-center corresponds to an electron hole located on oxygen atoms of the structure and is likely associated with Si, according to the lack of hyperfine structure. The A_s-center in sudoite has EPR parameters similar to the A-center in kaolinite and dickite, and the A_i-center in illite. The saturation behavior of EPR spectra as a function of power demonstrates that native defects of sudoite are different from those known in other clays, such as kaolinite, dickite or smectite, but are similar to those of illite. The isochronal annealing data suggest that the main defect in sudoite is stable to more than 300°C. The corresponding defects characterized in sudoite may have the potential for tracing past radionuclide migration around unconformity-type uranium deposits.     

Assessing the response of watersheds to catastrophic (logging) and possible secular (global temperature change) perturbations using sediment-chemical chronologies

Geochemical profiles of sediment cores from two oligotrophic lakes (Elk and Mullett) in northern Lower Michigan were studied to examine the response and recovery of watersheds to large-scale logging that occurred between 1850 and 1920. Specific questions addressed were: can the impact of extensive clear-cutting of forests be recognized in the sediment-chemical chronologies, can states of system stability be identified prior to the logging, and are there indications that the systems are recovering and possibly returning to a stable state? To answer these questions, elements were put into four groups as proxies for watershed runoff or export (e.g., Al, Mg), pollution (e.g., Pb, Cu), redox (e.g., Fe, As), and productivity (e.g., Ca, P). It was observed that vertical patterns of all proxies were influenced by logging and the early increases in concentration of pollution proxies were due to increased watershed export, not pollution. System stability might be recognized by relatively symmetrical vertical patterns among all of the proxies or secular changes of slowly increasing or decreasing vertical concentration trajectories. Some pre-logging trajectories were punctuated by episodes of slightly elevated concentrations that appear to be related to comparatively warmer periods during the Little Ice Age. Iron and Mn enrichments caused by increased watershed runoff might be misinterpreted as paleo-redox horizons. Results are interpreted to indicate that (1) reference conditions may be better defined as the temporal trends among proxy groups and not individual concentrations, (2) simply assuming pre-1800 conditions as a reference may not be appropriate, (3) inter-proxy group comparisons are needed to help for interpretations of intra-proxy group patterns, (4) the possible regime shift identified here might be expected for other ecosystems because of the intensity of human disturbances and secular changes, and (5) without consideration of a possible regime shift, recovery from logging is estimated to be on the order of 75–130 a, but shorter if regime shifts are considered.     

Solar shield: forecasting and mitigating space weather effects on high-voltage power transmission systems

In this paper, central elements of the Solar Shield project, launched to design and establish an experimental system capable of forecasting the space weather effects on high-voltage power transmission system, are described. It will be shown how Sun–Earth system data and models hosted at the Community Coordinated Modeling Center (CCMC) are used to generate two-level magnetohydrodynamics-based forecasts providing 1–2 day and 30–60 min lead-times. The Electric Power Research Institute (EPRI) represents the end-user, the power transmission industry, in the project. EPRI integrates the forecast products to an online display tool providing information about space weather conditions to the member power utilities. EPRI also evaluates the economic impacts of severe storms on power transmission systems. The economic analysis will quantify the economic value of the generated forecasting system. The first version of the two-level forecasting system is currently running in real-time at CCMC. An initial analysis of the system’s capabilities has been completed, and further analysis is being carried out to optimize the performance of the system. Although the initial results are encouraging, definite conclusions about system’s performance can be given only after more extensive analysis, and implementation of an automatic evaluation process using forecasted and observed geomagnetically induced currents from different nodes of the North American power transmission system. The final output of the Solar Shield will be a recommendation for an optimal forecasting system that may be transitioned into space weather operations.     

A field study (Massachusetts, USA) of the factors controlling the depth of groundwater flow systems in crystalline fractured-rock terrain

Groundwater movement and availability in crystalline and metamorphosed rocks is dominated by the secondary porosity generated through fracturing. The distributions of fractures and fracture zones determine permeable pathways and the productivity of these rocks. Controls on how these distributions vary with depth in the shallow subsurface (<300 m) and their resulting influence on groundwater flow is not well understood. The results of a subsurface study in the Nashoba and Avalon terranes of eastern Massachusetts (USA), which is a region experiencing expanded use of the fractured bedrock as a potable-supply aquifer, are presented. The study logged the distribution of fractures in 17 boreholes, identified flowing fractures, and hydraulically characterized the rock mass intersecting the boreholes. Of all fractures encountered, 2.5% are hydraulically active. Boreholes show decreasing fracture frequency up to 300 m depth, with hydraulically active fractures showing a similar trend; this restricts topographically driven flow. Borehole temperature profiles corroborate this, with minimal hydrologically altered flow observed in the profiles below 100 m. Results from this study suggest that active flow systems in these geologic settings are shallow and that fracture permeability outside of the influence of large-scale structures will follow a decreasing trend with depth.     

The next layer: Towards open pedagogy in geospatial education

Open-source software and open data are becoming increasingly popular in the teaching and learning of geographic information science. The cost savings that are derived from using free software over proprietary software are one driving factor, yet the move from “closed” to “open” represents much more than financial austerity—it signifies a broader shift in educational philosophy. This article documents the gradual transition of an introductory undergraduate course in geographic information systems from an entirely closed course to one that has become increasingly open. Having completely adopted the first three layers of open—software, data, and educational resources—the course is now turning toward the next layer: embracing the philosophy of open pedagogy.     

Recent Developments in the Analysis of the Black Mat Layer and Cosmic Impact at 12.8 ka

Recent analyses of sediment samples from “black mat” sites in South America and Europe support previous interpretations of an ET impact event that reversed the Late Glacial demise of LGM ice during the Bølling Allerød warming, resulting in a resurgence of ice termed the Younger Dryas (YD) cooling episode. The breakup or impact of a cosmic vehicle at the YD boundary coincides with the onset of a 1‐kyr long interval of glacial resurgence, one of the most studied events of the Late Pleistocene. New analytical databases reveal a corpus of data indicating that the cosmic impact was a real event, most possibly a cosmic airburst from Earth's encounter with the Taurid Complex comet or unknown asteroid, an event that led to cosmic fragments exploding interhemispherically over widely dispersed areas, including the northern Andes of Venezuela and the Alps on the Italian/French frontier. While the databases in the two areas differ somewhat, the overall interpretation is that microtextural evidence in weathering rinds and in sands of associated paleosols and glaciofluvial deposits carry undeniable attributes of melted glassy carbon and Fe spherules, planar deformation features, shock‐melted and contorted quartz, occasional transition and platinum metals, and brecciated and impacted minerals of diverse lithologies. In concert with other black mat localities in the Western USA, the Netherlands, coastal France, Syria, Central Asia, Peru, Argentina and Mexico, it appears that a widespread cosmic impact by an asteroid or comet is responsible for deposition of the black mat at the onset of the YD glacial event. Whether or not the impact caused a 1‐kyr interval of glacial climate depends upon whether or not the Earth had multiple centuries‐long episodic encounters with the Taurid Complex or asteroid remnants; impact‐related changes in microclimates sustained climatic forcing sufficient to maintain positive mass balances in the reformed ice; and/or inertia in the Atlantic thermohaline circulation system persisted for 1 kyr.     

Utilization of a multicriteria least cost path model in an aquatic environment

A critical component of maintaining biodiversity in fragmented habitats is maintaining connectivity among the usable fragments. Least cost path (LCP) analysis is a tool that can be used for predicting the ability of an organism to move from one habitat patch to another, based on geographical features of the landscape and life history traits of the organism. While this analysis has been utilized for terrestrial habitats, it is rarely applied to aquatic environments. Aquatic hypoxic conditions occur when dissolved oxygen falls below 2 mg/L. These conditions can create barriers in the water column that can either force fish to leave a habitat, or avoid that habitat altogether. Using the lower St. Johns River (LSJR) estuary in Florida, USA, as a study system, the ability of an adult silver perch, Bairdiella chrysoura, to escape a large-scale hypoxic event was modeled using a multicriteria LCP approach. Criteria-specific cost grids were constructed based upon current speed, risk of predation, and whether oxygen levels in the habitat area were normoxic (>5.5 mg/L), or hypoxic (<2.0–1.5 mg/L) as a function of water depth for the LSJR. The criteria cost grids were combined using relative weighting to produce the multicriteria cost grid used to implement the LCP analysis. Three origin and destination point locations within the LSJR study area were selected for modeling whether or not a silver perch would be able to escape a hypoxic zone. Since the LCP model will always determine a LCP from the specified origin point location, ecologically relevant swimming capacities for silver perch under normoxic and hypoxic conditions were then applied to assess the model, and to determine whether the fish would be able to reach areas unimpacted by hypoxia. The LCP model and the swimming capacity results for this study predict that under normoxic conditions, fish movement was unimpeded. During the rapidly developing hypoxic event that was modeled, the results from the LCP model indicate that the fish could move outside the hypoxic zone, but when swimming capacities were applied to the model, the silver perch could not escape. Ecologically, the results of this study suggest that silver perch would experience high mortality under a rapidly developing hypoxic event. Additionally, the results of this study indicate that a LCP model can be applied to an aquatic habitat, as long as the cost grids incorporate relevant abiotic and biotic factors.